Chiral Induction in Quinoline-Derived Oligoamide Foldamers: Assignment of Helical Handedness and Role of Steric Effects

Chiral groups attached to the end of quinoline-derived oligoamide foldamers give rise to chiral helical induction in solution. Using various chiral groups, diastereomeric excesses ranging from 9% to 83% could be measured by NMR and circular dichroism. Despite these relatively weak values and the fac...

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Veröffentlicht in:	Journal of the American Chemical Society 2005-09, Vol.127 (37), p.12943-12951
Hauptverfasser:	Dolain, Christel, Jiang, Hua, Léger, Jean-Michel, Guionneau, Philippe, Huc, Ivan
Format:	Artikel
Sprache:	eng
Schlagworte:	Amides - chemistry Applied sciences Chemical Sciences Circular Dichroism Crystallography, X-Ray Exact sciences and technology Magnetic Resonance Spectroscopy Material chemistry Models, Molecular Molecular Structure Organic polymers Physicochemistry of polymers Properties and characterization Quinolines - chemistry Stereoisomerism Structure, morphology and analysis
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