Transition State Spectroscopy of the Photoinduced Ca + CH3F Reaction. 1. A Cluster Isolated Chemical Reaction Study

Transition State Spectroscopy of the Photoinduced Ca + CH3F Reaction. 1. A Cluster Isolated Chemical Reaction Study

The “cluster isolated chemical reactions” technique is used to examine the dynamics of the photoinduced reaction producing electronically excited CaF when 1:1 Ca·CH3F complexes are deposited at the surface of large argon clusters. This technique ensures quantitatively that 1:1 complexes are actually...

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Veröffentlicht in:The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2005-10, Vol.109 (42), p.9494-9498
Hauptverfasser: Gaveau, M.-A, Gloaguen, E, Fournier, P.-R, Mestdagh, J.-M
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container_issue 42
container_start_page 9494
container_title The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory
container_volume 109
creator Gaveau, M.-A
Gloaguen, E
Fournier, P.-R
Mestdagh, J.-M
description The “cluster isolated chemical reactions” technique is used to examine the dynamics of the photoinduced reaction producing electronically excited CaF when 1:1 Ca·CH3F complexes are deposited at the surface of large argon clusters. This technique ensures quantitatively that 1:1 complexes are actually at the origin of the observed signals. The reaction is monitored by observing the CaF chemiluminescence while scanning the photoexcitation laser. The resulting action spectrum contains information about the absorption bands of the complex, filtered by the dynamics of the reaction. The observations suggest a profound alteration of the calcium electronic structure and a control of the reaction by the CF stretch in CH3F.
doi_str_mv 10.1021/jp053128h
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title Transition State Spectroscopy of the Photoinduced Ca + CH3F Reaction. 1. A Cluster Isolated Chemical Reaction Study
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