Synthesis of alkyl- and aryldiphenylphosphines via electrogenerated magnesium chloride diphenylphosphanide
A two-steps procedure allowing the formation of alkyldiphenylphosphines and aryldiphenylphosphines in good yield is described. It relies on the electrochemical preparation of magnesium chloride diphenylphosphanide and its subsequent coupling with either alkyl halides or aryl fluorides. A two-steps p...
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| Veröffentlicht in: | Journal of organometallic chemistry 2006-04, Vol.691 (9), p.1809-1813 |
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| container_end_page | 1813 |
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| container_issue | 9 |
| container_start_page | 1809 |
| container_title | Journal of organometallic chemistry |
| container_volume | 691 |
| creator | Nechab, Malek Le Gall, Erwan Troupel, Michel Nédélec, Jean-Yves |
| description | A two-steps procedure allowing the formation of alkyldiphenylphosphines and aryldiphenylphosphines in good yield is described. It relies on the electrochemical preparation of magnesium chloride diphenylphosphanide and its subsequent coupling with either alkyl halides or aryl fluorides.
A two-steps procedure allowing the formation of alkyldiphenylphosphines and aryldiphenylphosphines in good yield is described. It relies on the electrochemical preparation of magnesium chloride diphenylphosphanide and its subsequent coupling with either alkyl halides or aryl fluorides. |
| doi_str_mv | 10.1016/j.jorganchem.2006.01.001 |
| format | Article |
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A two-steps procedure allowing the formation of alkyldiphenylphosphines and aryldiphenylphosphines in good yield is described. It relies on the electrochemical preparation of magnesium chloride diphenylphosphanide and its subsequent coupling with either alkyl halides or aryl fluorides.</description><identifier>ISSN: 0022-328X</identifier><identifier>EISSN: 1872-8561</identifier><identifier>EISSN: 0022-328X</identifier><identifier>DOI: 10.1016/j.jorganchem.2006.01.001</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Alkyldiphenylphosphine ; Aryldiphenylphosphine ; Chlorodiphenylphosphine ; Diphenylphosphanide ; Electrosynthesis ; Organic halide</subject><ispartof>Journal of organometallic chemistry, 2006-04, Vol.691 (9), p.1809-1813</ispartof><rights>2006 Elsevier B.V.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c352t-f4acd3ea2439c6880a4e548f0321fa7d299bd38854762bf05e22d851fc6be0523</citedby><cites>FETCH-LOGICAL-c352t-f4acd3ea2439c6880a4e548f0321fa7d299bd38854762bf05e22d851fc6be0523</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0022328X06000313$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,776,780,881,3536,27903,27904,65309</link.rule.ids><backlink>$$Uhttps://hal.science/hal-00070948$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Nechab, Malek</creatorcontrib><creatorcontrib>Le Gall, Erwan</creatorcontrib><creatorcontrib>Troupel, Michel</creatorcontrib><creatorcontrib>Nédélec, Jean-Yves</creatorcontrib><title>Synthesis of alkyl- and aryldiphenylphosphines via electrogenerated magnesium chloride diphenylphosphanide</title><title>Journal of organometallic chemistry</title><description>A two-steps procedure allowing the formation of alkyldiphenylphosphines and aryldiphenylphosphines in good yield is described. It relies on the electrochemical preparation of magnesium chloride diphenylphosphanide and its subsequent coupling with either alkyl halides or aryl fluorides.
A two-steps procedure allowing the formation of alkyldiphenylphosphines and aryldiphenylphosphines in good yield is described. It relies on the electrochemical preparation of magnesium chloride diphenylphosphanide and its subsequent coupling with either alkyl halides or aryl fluorides.</description><subject>Alkyldiphenylphosphine</subject><subject>Aryldiphenylphosphine</subject><subject>Chlorodiphenylphosphine</subject><subject>Diphenylphosphanide</subject><subject>Electrosynthesis</subject><subject>Organic halide</subject><issn>0022-328X</issn><issn>1872-8561</issn><issn>0022-328X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNqFkEtLxDAUhYMoOI7-h2xdtN6kr3Q5ijrCgAsV3IVMcjtNTR8kdWD-vS0jiitXF84958D5CKEMYgYsv2nipvc71eka25gD5DGwGICdkAUTBY9ElrNTsgDgPEq4eD8nFyE0MDkSEAvSvBy6scZgA-0rqtzHwUVUdYYqf3DGDjV2BzfUfRhq22Gge6soOtSj73fYoVcjGtqq3fSzny3Vteu9NUj_RlU3aZfkrFIu4NX3XZK3h_vXu3W0eX58ulttIp1kfIyqVGmToOJpUupcCFApZqmoIOGsUoXhZbk1iRBZWuR8W0GGnBuRsUrnW4SMJ0tyfeytlZODt-00RfbKyvVqI2dtGl9AmYo9m7zi6NW-D8Fj9RNgIGe-spG_fOXMVwKTM70luT1Gcdqyt-hl0BY7jcb6iY80vf2_5AuW_IvQ</recordid><startdate>20060415</startdate><enddate>20060415</enddate><creator>Nechab, Malek</creator><creator>Le Gall, Erwan</creator><creator>Troupel, Michel</creator><creator>Nédélec, Jean-Yves</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope></search><sort><creationdate>20060415</creationdate><title>Synthesis of alkyl- and aryldiphenylphosphines via electrogenerated magnesium chloride diphenylphosphanide</title><author>Nechab, Malek ; Le Gall, Erwan ; Troupel, Michel ; Nédélec, Jean-Yves</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c352t-f4acd3ea2439c6880a4e548f0321fa7d299bd38854762bf05e22d851fc6be0523</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Alkyldiphenylphosphine</topic><topic>Aryldiphenylphosphine</topic><topic>Chlorodiphenylphosphine</topic><topic>Diphenylphosphanide</topic><topic>Electrosynthesis</topic><topic>Organic halide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nechab, Malek</creatorcontrib><creatorcontrib>Le Gall, Erwan</creatorcontrib><creatorcontrib>Troupel, Michel</creatorcontrib><creatorcontrib>Nédélec, Jean-Yves</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of organometallic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nechab, Malek</au><au>Le Gall, Erwan</au><au>Troupel, Michel</au><au>Nédélec, Jean-Yves</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of alkyl- and aryldiphenylphosphines via electrogenerated magnesium chloride diphenylphosphanide</atitle><jtitle>Journal of organometallic chemistry</jtitle><date>2006-04-15</date><risdate>2006</risdate><volume>691</volume><issue>9</issue><spage>1809</spage><epage>1813</epage><pages>1809-1813</pages><issn>0022-328X</issn><eissn>1872-8561</eissn><eissn>0022-328X</eissn><abstract>A two-steps procedure allowing the formation of alkyldiphenylphosphines and aryldiphenylphosphines in good yield is described. It relies on the electrochemical preparation of magnesium chloride diphenylphosphanide and its subsequent coupling with either alkyl halides or aryl fluorides.
A two-steps procedure allowing the formation of alkyldiphenylphosphines and aryldiphenylphosphines in good yield is described. It relies on the electrochemical preparation of magnesium chloride diphenylphosphanide and its subsequent coupling with either alkyl halides or aryl fluorides.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.jorganchem.2006.01.001</doi><tpages>5</tpages></addata></record> |
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| ispartof | Journal of organometallic chemistry, 2006-04, Vol.691 (9), p.1809-1813 |
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| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Alkyldiphenylphosphine Aryldiphenylphosphine Chlorodiphenylphosphine Diphenylphosphanide Electrosynthesis Organic halide |
| title | Synthesis of alkyl- and aryldiphenylphosphines via electrogenerated magnesium chloride diphenylphosphanide |
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