Crystal structure, vibrational spectra and nonlinear optical properties of new melaminium salt: 2,4,6-triamino-1,3,5-triazin-1,3-ium tartrate monohydrate

The crystals of the new melaminium salt, i.e., 2,4,6-triamino-1,3,5-triazin-1,3-ium tartrate monohydrate, C 3H 8N 6 2+·C 3H 4O 6 2−·H 2O were obtained by slow evaporation of an aqueous solution at room temperature. The compound crystallizes in noncentrosymmetric space group of monoclinic system. The...

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Veröffentlicht in:Solid state sciences 2003-03, Vol.5 (3), p.509-518
Hauptverfasser: Marchewka, M.K, Baran, J, Pietraszko, A, Haznar, A, Debrus, S, Ratajczak, H
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container_end_page 518
container_issue 3
container_start_page 509
container_title Solid state sciences
container_volume 5
creator Marchewka, M.K
Baran, J
Pietraszko, A
Haznar, A
Debrus, S
Ratajczak, H
description The crystals of the new melaminium salt, i.e., 2,4,6-triamino-1,3,5-triazin-1,3-ium tartrate monohydrate, C 3H 8N 6 2+·C 3H 4O 6 2−·H 2O were obtained by slow evaporation of an aqueous solution at room temperature. The compound crystallizes in noncentrosymmetric space group of monoclinic system. The melamine molecule occurs in di-protonated form while the tartaric acid is doubly ionized with two COO − carboxylic groups. DSC measurements do not indicate clearly on the occurrence of phase transition in the temperature region 113–293 K. Second harmonic generation efficiency d eff∼ d eff (KDP). Graphic
doi_str_mv 10.1016/S1293-2558(03)00029-3
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subjects Condensed matter: electronic structure, electrical, magnetic, and optical properties
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Fundamental areas of phenomenology (including applications)
Hydrogen bond
Infrared and raman spectra and scattering
Melamine
Nonlinear optical crystals
Optical materials
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Optics
Organic compounds
Organic compounds, polymers
Physics
Second harmonic generation
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
Tartrate
title Crystal structure, vibrational spectra and nonlinear optical properties of new melaminium salt: 2,4,6-triamino-1,3,5-triazin-1,3-ium tartrate monohydrate
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