Thermodynamic study of the uranium–vanadium system
Temperatures of solid/liquid transitions and vanadium thermodynamic activity data are measured in the U–V system to improve the thermodynamic description of the U–V and C–U–V systems. Binary alloys are synthesized from the pure metals in a high vacuum furnace. With that apparatus, both liquidus temp...
Gespeichert in:
| Veröffentlicht in: | The Journal of chemical thermodynamics 2011-03, Vol.43 (3), p.458-466 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 466 |
|---|---|
| container_issue | 3 |
| container_start_page | 458 |
| container_title | The Journal of chemical thermodynamics |
| container_volume | 43 |
| creator | Berche, A. Alpettaz, T. Chatain, S. Blanc, C. Gossé, S. Guéneau, C. |
| description | Temperatures of solid/liquid transitions and vanadium thermodynamic activity data are measured in the U–V system to improve the thermodynamic description of the U–V and C–U–V systems. Binary alloys are synthesized from the pure metals in a high vacuum furnace. With that apparatus, both liquidus temperatures and vanadium activities are measured for each sample. During the experiments, the temperature of the samples is monitored with an optical pyrometer. In parallel, the activity of vanadium referred to pure vanadium is measured for
x
V
=
0.18, 0.40 and 0.62 in the (1850 to 2090)
K temperature range using high temperature mass spectrometry coupled to a multiple Knudsen cell system. The quenched microstructure of the alloys is analysed by electron microscopy. These new data together with the few ones from the literature are finally used to obtain a consistent set of thermodynamic parameters for the U–V system using the Calphad method. |
| doi_str_mv | 10.1016/j.jct.2010.10.023 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_cea_04509296v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0021961410003344</els_id><sourcerecordid>1671279846</sourcerecordid><originalsourceid>FETCH-LOGICAL-c394t-9807494f91549efc1d667bb53d3786a76ad00d5163f1f10effd74cc3d2ca7a503</originalsourceid><addsrcrecordid>eNp9kMtKAzEUQIMoWKsf4G42gi6m3jvJZBpcleILCm50HWIeNGUemswUuvMf_EO_xNSWLl3lwbnnwiHkEmGCgPx2NVnpflLA33sCBT0iIwTBc8oLfkxGAAXmgiM7JWcxrgBAUAEjwl6XNjSd2bSq8TqL_WA2WeeyfmmzIajWD83P1_datcqkaxY3sbfNOTlxqo72Yn-OydvD_ev8KV-8PD7PZ4tcU8H6XEyhYoI5gSUT1mk0nFfv7yU1tJpyVXFlAEyJnDp0CNY5UzGtqSm0qlQJdExudt6lquVH8I0KG9kpL59mC6mtksBKEIXga0zs9Y79CN3nYGMvGx-1rWvV2m6IEnmFRSWmjCcUd6gOXYzBuoMbQW5rypVMNeW25vYr1UwzV3u9ilrVLqXRPh4GCzpFwWDrvttxNnVZextk1N622hofbHKazv-z5RcWj4lC</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1671279846</pqid></control><display><type>article</type><title>Thermodynamic study of the uranium–vanadium system</title><source>ScienceDirect Journals (5 years ago - present)</source><creator>Berche, A. ; Alpettaz, T. ; Chatain, S. ; Blanc, C. ; Gossé, S. ; Guéneau, C.</creator><creatorcontrib>Berche, A. ; Alpettaz, T. ; Chatain, S. ; Blanc, C. ; Gossé, S. ; Guéneau, C.</creatorcontrib><description>Temperatures of solid/liquid transitions and vanadium thermodynamic activity data are measured in the U–V system to improve the thermodynamic description of the U–V and C–U–V systems. Binary alloys are synthesized from the pure metals in a high vacuum furnace. With that apparatus, both liquidus temperatures and vanadium activities are measured for each sample. During the experiments, the temperature of the samples is monitored with an optical pyrometer. In parallel, the activity of vanadium referred to pure vanadium is measured for
x
V
=
0.18, 0.40 and 0.62 in the (1850 to 2090)
K temperature range using high temperature mass spectrometry coupled to a multiple Knudsen cell system. The quenched microstructure of the alloys is analysed by electron microscopy. These new data together with the few ones from the literature are finally used to obtain a consistent set of thermodynamic parameters for the U–V system using the Calphad method.</description><identifier>ISSN: 0021-9614</identifier><identifier>EISSN: 1096-3626</identifier><identifier>DOI: 10.1016/j.jct.2010.10.023</identifier><identifier>CODEN: JCTDAF</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Alloys ; Calphad ; Chemical Sciences ; Chemical thermodynamics ; Chemistry ; Computer simulation ; Exact sciences and technology ; Furnaces ; General and physical chemistry ; High temperature mass spectrometry ; Liquids ; Material chemistry ; Mathematical models ; Metals and alloys ; Phase transformations ; Quenching (cooling) ; Thermal analysis ; Thermodynamic properties ; Thermodynamics ; Uranium ; Vanadium</subject><ispartof>The Journal of chemical thermodynamics, 2011-03, Vol.43 (3), p.458-466</ispartof><rights>2010 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c394t-9807494f91549efc1d667bb53d3786a76ad00d5163f1f10effd74cc3d2ca7a503</citedby><cites>FETCH-LOGICAL-c394t-9807494f91549efc1d667bb53d3786a76ad00d5163f1f10effd74cc3d2ca7a503</cites><orcidid>0000-0001-7300-9004</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jct.2010.10.023$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,780,784,885,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23819406$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://cea.hal.science/cea-04509296$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Berche, A.</creatorcontrib><creatorcontrib>Alpettaz, T.</creatorcontrib><creatorcontrib>Chatain, S.</creatorcontrib><creatorcontrib>Blanc, C.</creatorcontrib><creatorcontrib>Gossé, S.</creatorcontrib><creatorcontrib>Guéneau, C.</creatorcontrib><title>Thermodynamic study of the uranium–vanadium system</title><title>The Journal of chemical thermodynamics</title><description>Temperatures of solid/liquid transitions and vanadium thermodynamic activity data are measured in the U–V system to improve the thermodynamic description of the U–V and C–U–V systems. Binary alloys are synthesized from the pure metals in a high vacuum furnace. With that apparatus, both liquidus temperatures and vanadium activities are measured for each sample. During the experiments, the temperature of the samples is monitored with an optical pyrometer. In parallel, the activity of vanadium referred to pure vanadium is measured for
x
V
=
0.18, 0.40 and 0.62 in the (1850 to 2090)
K temperature range using high temperature mass spectrometry coupled to a multiple Knudsen cell system. The quenched microstructure of the alloys is analysed by electron microscopy. These new data together with the few ones from the literature are finally used to obtain a consistent set of thermodynamic parameters for the U–V system using the Calphad method.</description><subject>Alloys</subject><subject>Calphad</subject><subject>Chemical Sciences</subject><subject>Chemical thermodynamics</subject><subject>Chemistry</subject><subject>Computer simulation</subject><subject>Exact sciences and technology</subject><subject>Furnaces</subject><subject>General and physical chemistry</subject><subject>High temperature mass spectrometry</subject><subject>Liquids</subject><subject>Material chemistry</subject><subject>Mathematical models</subject><subject>Metals and alloys</subject><subject>Phase transformations</subject><subject>Quenching (cooling)</subject><subject>Thermal analysis</subject><subject>Thermodynamic properties</subject><subject>Thermodynamics</subject><subject>Uranium</subject><subject>Vanadium</subject><issn>0021-9614</issn><issn>1096-3626</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9kMtKAzEUQIMoWKsf4G42gi6m3jvJZBpcleILCm50HWIeNGUemswUuvMf_EO_xNSWLl3lwbnnwiHkEmGCgPx2NVnpflLA33sCBT0iIwTBc8oLfkxGAAXmgiM7JWcxrgBAUAEjwl6XNjSd2bSq8TqL_WA2WeeyfmmzIajWD83P1_datcqkaxY3sbfNOTlxqo72Yn-OydvD_ev8KV-8PD7PZ4tcU8H6XEyhYoI5gSUT1mk0nFfv7yU1tJpyVXFlAEyJnDp0CNY5UzGtqSm0qlQJdExudt6lquVH8I0KG9kpL59mC6mtksBKEIXga0zs9Y79CN3nYGMvGx-1rWvV2m6IEnmFRSWmjCcUd6gOXYzBuoMbQW5rypVMNeW25vYr1UwzV3u9ilrVLqXRPh4GCzpFwWDrvttxNnVZextk1N622hofbHKazv-z5RcWj4lC</recordid><startdate>20110301</startdate><enddate>20110301</enddate><creator>Berche, A.</creator><creator>Alpettaz, T.</creator><creator>Chatain, S.</creator><creator>Blanc, C.</creator><creator>Gossé, S.</creator><creator>Guéneau, C.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0001-7300-9004</orcidid></search><sort><creationdate>20110301</creationdate><title>Thermodynamic study of the uranium–vanadium system</title><author>Berche, A. ; Alpettaz, T. ; Chatain, S. ; Blanc, C. ; Gossé, S. ; Guéneau, C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c394t-9807494f91549efc1d667bb53d3786a76ad00d5163f1f10effd74cc3d2ca7a503</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Alloys</topic><topic>Calphad</topic><topic>Chemical Sciences</topic><topic>Chemical thermodynamics</topic><topic>Chemistry</topic><topic>Computer simulation</topic><topic>Exact sciences and technology</topic><topic>Furnaces</topic><topic>General and physical chemistry</topic><topic>High temperature mass spectrometry</topic><topic>Liquids</topic><topic>Material chemistry</topic><topic>Mathematical models</topic><topic>Metals and alloys</topic><topic>Phase transformations</topic><topic>Quenching (cooling)</topic><topic>Thermal analysis</topic><topic>Thermodynamic properties</topic><topic>Thermodynamics</topic><topic>Uranium</topic><topic>Vanadium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Berche, A.</creatorcontrib><creatorcontrib>Alpettaz, T.</creatorcontrib><creatorcontrib>Chatain, S.</creatorcontrib><creatorcontrib>Blanc, C.</creatorcontrib><creatorcontrib>Gossé, S.</creatorcontrib><creatorcontrib>Guéneau, C.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>The Journal of chemical thermodynamics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Berche, A.</au><au>Alpettaz, T.</au><au>Chatain, S.</au><au>Blanc, C.</au><au>Gossé, S.</au><au>Guéneau, C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermodynamic study of the uranium–vanadium system</atitle><jtitle>The Journal of chemical thermodynamics</jtitle><date>2011-03-01</date><risdate>2011</risdate><volume>43</volume><issue>3</issue><spage>458</spage><epage>466</epage><pages>458-466</pages><issn>0021-9614</issn><eissn>1096-3626</eissn><coden>JCTDAF</coden><abstract>Temperatures of solid/liquid transitions and vanadium thermodynamic activity data are measured in the U–V system to improve the thermodynamic description of the U–V and C–U–V systems. Binary alloys are synthesized from the pure metals in a high vacuum furnace. With that apparatus, both liquidus temperatures and vanadium activities are measured for each sample. During the experiments, the temperature of the samples is monitored with an optical pyrometer. In parallel, the activity of vanadium referred to pure vanadium is measured for
x
V
=
0.18, 0.40 and 0.62 in the (1850 to 2090)
K temperature range using high temperature mass spectrometry coupled to a multiple Knudsen cell system. The quenched microstructure of the alloys is analysed by electron microscopy. These new data together with the few ones from the literature are finally used to obtain a consistent set of thermodynamic parameters for the U–V system using the Calphad method.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.jct.2010.10.023</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0001-7300-9004</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-9614 |
| ispartof | The Journal of chemical thermodynamics, 2011-03, Vol.43 (3), p.458-466 |
| issn | 0021-9614 1096-3626 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_cea_04509296v1 |
| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Alloys Calphad Chemical Sciences Chemical thermodynamics Chemistry Computer simulation Exact sciences and technology Furnaces General and physical chemistry High temperature mass spectrometry Liquids Material chemistry Mathematical models Metals and alloys Phase transformations Quenching (cooling) Thermal analysis Thermodynamic properties Thermodynamics Uranium Vanadium |
| title | Thermodynamic study of the uranium–vanadium system |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-08T01%3A05%3A44IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_hal_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Thermodynamic%20study%20of%20the%20uranium%E2%80%93vanadium%20system&rft.jtitle=The%20Journal%20of%20chemical%20thermodynamics&rft.au=Berche,%20A.&rft.date=2011-03-01&rft.volume=43&rft.issue=3&rft.spage=458&rft.epage=466&rft.pages=458-466&rft.issn=0021-9614&rft.eissn=1096-3626&rft.coden=JCTDAF&rft_id=info:doi/10.1016/j.jct.2010.10.023&rft_dat=%3Cproquest_hal_p%3E1671279846%3C/proquest_hal_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1671279846&rft_id=info:pmid/&rft_els_id=S0021961410003344&rfr_iscdi=true |