Low-cost, pseudo-Halbach dipole magnets for NMR
[Display omitted] •Strong, low-homogeneity magnets constructed using low-cost materials and simple engineering.•Apply in NMR experiments where field strength is a priority over uniformity, e.g. prepolarization.•Demonstrated use of the magnet in zero-field NMR spectroscopy. We present designs for com...
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Veröffentlicht in: | Journal of magnetic resonance (1997) 2017-04, Vol.277, p.143-148 |
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container_title | Journal of magnetic resonance (1997) |
container_volume | 277 |
creator | Tayler, Michael C.D. Sakellariou, Dimitrios |
description | [Display omitted]
•Strong, low-homogeneity magnets constructed using low-cost materials and simple engineering.•Apply in NMR experiments where field strength is a priority over uniformity, e.g. prepolarization.•Demonstrated use of the magnet in zero-field NMR spectroscopy.
We present designs for compact, inexpensive and strong dipole permanent magnets aimed primarily at magnetic resonance applications where prepolarization and detection occur at different locations. Low-homogeneity magnets with a 7.5mm bore size and field up to nearly 2T are constructed using low-cost starting materials, standard workshop tools and only few hours of labor – an achievable project for a student or postdoc with spare time. As an application example we show how our magnet was used to polarize the nuclear spins in approximately 1mL of pure [13C]-methanol prior to detection of its high-resolution NMR spectrum at zero field (measurement field below 10-10T), where signals appear at multiples of the carbon-hydrogen spin-spin coupling frequency 1JCH=140.7(1)Hz. |
doi_str_mv | 10.1016/j.jmr.2017.03.001 |
format | Article |
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•Strong, low-homogeneity magnets constructed using low-cost materials and simple engineering.•Apply in NMR experiments where field strength is a priority over uniformity, e.g. prepolarization.•Demonstrated use of the magnet in zero-field NMR spectroscopy.
We present designs for compact, inexpensive and strong dipole permanent magnets aimed primarily at magnetic resonance applications where prepolarization and detection occur at different locations. Low-homogeneity magnets with a 7.5mm bore size and field up to nearly 2T are constructed using low-cost starting materials, standard workshop tools and only few hours of labor – an achievable project for a student or postdoc with spare time. As an application example we show how our magnet was used to polarize the nuclear spins in approximately 1mL of pure [13C]-methanol prior to detection of its high-resolution NMR spectrum at zero field (measurement field below 10-10T), where signals appear at multiples of the carbon-hydrogen spin-spin coupling frequency 1JCH=140.7(1)Hz.</description><identifier>ISSN: 1090-7807</identifier><identifier>EISSN: 1096-0856</identifier><identifier>DOI: 10.1016/j.jmr.2017.03.001</identifier><identifier>PMID: 28285144</identifier><language>eng</language><publisher>United States: Elsevier Inc</publisher><subject>Chemical Sciences ; Low-field NMR ; Material chemistry ; Nuclear magnetic resonance (NMR) ; Permanent magnets ; Zero-field NMR</subject><ispartof>Journal of magnetic resonance (1997), 2017-04, Vol.277, p.143-148</ispartof><rights>2017</rights><rights>Copyright © 2017. Published by Elsevier Inc.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c430t-30cdde338234e9e4a11aaf16c5829cf3ecabc7002177e1612228c5df489ac32f3</citedby><cites>FETCH-LOGICAL-c430t-30cdde338234e9e4a11aaf16c5829cf3ecabc7002177e1612228c5df489ac32f3</cites><orcidid>0000-0001-7424-5543</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jmr.2017.03.001$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,780,784,885,3548,27923,27924,45994</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28285144$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://cea.hal.science/cea-01488897$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Tayler, Michael C.D.</creatorcontrib><creatorcontrib>Sakellariou, Dimitrios</creatorcontrib><title>Low-cost, pseudo-Halbach dipole magnets for NMR</title><title>Journal of magnetic resonance (1997)</title><addtitle>J Magn Reson</addtitle><description>[Display omitted]
•Strong, low-homogeneity magnets constructed using low-cost materials and simple engineering.•Apply in NMR experiments where field strength is a priority over uniformity, e.g. prepolarization.•Demonstrated use of the magnet in zero-field NMR spectroscopy.
We present designs for compact, inexpensive and strong dipole permanent magnets aimed primarily at magnetic resonance applications where prepolarization and detection occur at different locations. Low-homogeneity magnets with a 7.5mm bore size and field up to nearly 2T are constructed using low-cost starting materials, standard workshop tools and only few hours of labor – an achievable project for a student or postdoc with spare time. As an application example we show how our magnet was used to polarize the nuclear spins in approximately 1mL of pure [13C]-methanol prior to detection of its high-resolution NMR spectrum at zero field (measurement field below 10-10T), where signals appear at multiples of the carbon-hydrogen spin-spin coupling frequency 1JCH=140.7(1)Hz.</description><subject>Chemical Sciences</subject><subject>Low-field NMR</subject><subject>Material chemistry</subject><subject>Nuclear magnetic resonance (NMR)</subject><subject>Permanent magnets</subject><subject>Zero-field NMR</subject><issn>1090-7807</issn><issn>1096-0856</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp9kD9PwzAQRy0E4v8HYEEZQSLpne3EjpgQAopUQEIwW65zgVRJXewUxLcnpcDIdDe83xseY0cIGQIWo1k260LGAVUGIgPADbaLUBYp6LzY_P4hVRrUDtuLcTYAmCvYZjtcc52jlLtsNPEfqfOxP0sWkZaVT8e2nVr3mlTNwreUdPZlTn1Mah-S-7vHA7ZV2zbS4c_dZ8_XV0-X43TycHN7eTFJnRTQpwJcVZEQmgtJJUmLaG2Nhcs1L10tyNmpUwAclSIskHOuXV7VUpfWCV6LfXa69r7a1ixC09nwabxtzPhiYhxZAyi11qV6x4E9WbOL4N-WFHvTNdFR29o5-WU0qFWhUeayHFBcoy74GAPVf24Es2pqZmZoalZNDQgzJBs2xz_65bSj6m_xG3EAztcADUHeGwomuobmjqomkOtN5Zt_9F8WBYP-</recordid><startdate>20170401</startdate><enddate>20170401</enddate><creator>Tayler, Michael C.D.</creator><creator>Sakellariou, Dimitrios</creator><general>Elsevier Inc</general><general>Elsevier</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0001-7424-5543</orcidid></search><sort><creationdate>20170401</creationdate><title>Low-cost, pseudo-Halbach dipole magnets for NMR</title><author>Tayler, Michael C.D. ; Sakellariou, Dimitrios</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c430t-30cdde338234e9e4a11aaf16c5829cf3ecabc7002177e1612228c5df489ac32f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Chemical Sciences</topic><topic>Low-field NMR</topic><topic>Material chemistry</topic><topic>Nuclear magnetic resonance (NMR)</topic><topic>Permanent magnets</topic><topic>Zero-field NMR</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tayler, Michael C.D.</creatorcontrib><creatorcontrib>Sakellariou, Dimitrios</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of magnetic resonance (1997)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tayler, Michael C.D.</au><au>Sakellariou, Dimitrios</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Low-cost, pseudo-Halbach dipole magnets for NMR</atitle><jtitle>Journal of magnetic resonance (1997)</jtitle><addtitle>J Magn Reson</addtitle><date>2017-04-01</date><risdate>2017</risdate><volume>277</volume><spage>143</spage><epage>148</epage><pages>143-148</pages><issn>1090-7807</issn><eissn>1096-0856</eissn><abstract>[Display omitted]
•Strong, low-homogeneity magnets constructed using low-cost materials and simple engineering.•Apply in NMR experiments where field strength is a priority over uniformity, e.g. prepolarization.•Demonstrated use of the magnet in zero-field NMR spectroscopy.
We present designs for compact, inexpensive and strong dipole permanent magnets aimed primarily at magnetic resonance applications where prepolarization and detection occur at different locations. Low-homogeneity magnets with a 7.5mm bore size and field up to nearly 2T are constructed using low-cost starting materials, standard workshop tools and only few hours of labor – an achievable project for a student or postdoc with spare time. As an application example we show how our magnet was used to polarize the nuclear spins in approximately 1mL of pure [13C]-methanol prior to detection of its high-resolution NMR spectrum at zero field (measurement field below 10-10T), where signals appear at multiples of the carbon-hydrogen spin-spin coupling frequency 1JCH=140.7(1)Hz.</abstract><cop>United States</cop><pub>Elsevier Inc</pub><pmid>28285144</pmid><doi>10.1016/j.jmr.2017.03.001</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0001-7424-5543</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | Chemical Sciences Low-field NMR Material chemistry Nuclear magnetic resonance (NMR) Permanent magnets Zero-field NMR |
title | Low-cost, pseudo-Halbach dipole magnets for NMR |
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