Excited State Pathways Leading to Formation of Adenine Dimers

The reaction intermediate in the path leading to UV-induced formation of adenine dimers AA and AA* is identified for the first time quantum mechanically, using PCM/TD-DFT calculations on (dA)2 (dA: 2′deoxyadenosine). In parallel, its fingerprint is detected in the absorption spectra recorded on the...

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Veröffentlicht in:	The journal of physical chemistry letters 2016-06, Vol.7 (11), p.2020-2023
Hauptverfasser:	Banyasz, Akos, Martinez-Fernandez, Lara, Ketola, Tiia-Maaria, Muñoz-Losa, Aurora, Esposito, Luciana, Markovitsi, Dimitra, Improta, Roberto
Format:	Artikel
Sprache:	eng
Schlagworte:	Adenine - chemistry Chemical Sciences Dimerization or physical chemistry Quantum Theory Theoretical and Ultraviolet Rays
Online-Zugang:	Volltext
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