Atom transfer radical polymerization (ATRP) initiated by aryl diazonium salts: a new route for surface modification of multiwalled carbon nanotubes by tethered polymer chains
We report for the first time on grafting of poly( n-methyl methacrylate), (PMMA), and polystyrene (PS) brushes by ATRP from the surface of aligned multiwalled carbon nanotubes (MWCNT) which were electrochemically treated with brominated aryl groups based on diazonium salts. The polymer brushes forme...
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| Veröffentlicht in: | Colloids and surfaces. A, Physicochemical and engineering aspects Physicochemical and engineering aspects, 2006-09, Vol.287 (1), p.217-221 |
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| container_title | Colloids and surfaces. A, Physicochemical and engineering aspects |
| container_volume | 287 |
| creator | Matrab, Tarik Chancolon, Jérôme L’hermite, Martine Mayne Rouzaud, Jean-Noël Deniau, Guy Boudou, Jean-Paul Chehimi, Mohamed M. Delamar, Michel |
| description | We report for the first time on grafting of poly(
n-methyl methacrylate), (PMMA), and polystyrene (PS) brushes by ATRP from the surface of aligned multiwalled carbon nanotubes (MWCNT) which were electrochemically treated with brominated aryl groups based on diazonium salts. The polymer brushes formed amorphous coatings, as evidenced by high-resolution transmission electron microscopy, by comparison to the nanotube structure. X-ray photoelectron spectroscopy (XPS) analysis confirmed the presence of PS and PMMA by their characteristic C1s and valence band features. Well-aligned MWCNT network allowed us to sheath individual MWCNTs with polymer brushes while keeping the initial MWCNT alignment structure. This method opens up new avenues for the elaboration of polymer/NT hybrids. |
| doi_str_mv | 10.1016/j.colsurfa.2006.05.028 |
| format | Article |
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n-methyl methacrylate), (PMMA), and polystyrene (PS) brushes by ATRP from the surface of aligned multiwalled carbon nanotubes (MWCNT) which were electrochemically treated with brominated aryl groups based on diazonium salts. The polymer brushes formed amorphous coatings, as evidenced by high-resolution transmission electron microscopy, by comparison to the nanotube structure. X-ray photoelectron spectroscopy (XPS) analysis confirmed the presence of PS and PMMA by their characteristic C1s and valence band features. Well-aligned MWCNT network allowed us to sheath individual MWCNTs with polymer brushes while keeping the initial MWCNT alignment structure. This method opens up new avenues for the elaboration of polymer/NT hybrids.</description><subject>Atom transfer radical polymerization (ATRP)</subject><subject>Carbon nanotubes</subject><subject>Chemical Sciences</subject><subject>Chemistry</subject><subject>Diazonium salts</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Material chemistry</subject><issn>0927-7757</issn><issn>1873-4359</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNqFkc1u1DAUhSMEEkPhFZA3SLBIcOxxnLBiVEFbaSQQKmvrxj-aO3Like20mj4Uz4inU2DJypJ9zvG596uqty1tWtp2H_eNDj4t0UHDKO0aKhrK-mfVqu0lr9dcDM-rFR2YrKUU8mX1KqU9pXQt5LCqfm1ymEiOMCdnI4lgUIMnh-CPk434ABnDTN5vbn98_0BwxoyQrSHjkUA8emIQHsKMy0QS-Jw-ESCzvScxLNkSFyJ57KUtmYJBV6If44Ij0-Iz3oP3JUxDHMvtDHPIy2jTKT3bvLOxPD41IXoHOKfX1QsHPtk3T-dF9fPrl9vL63r77ermcrOt9Zr1uXbj0FHhJFChmeFS9toY4awZ1qCp7gxlth8k7yRfa9ZDkeoeGB8YEx0HwS-q-py7A68OEacyrQqA6nqzVSMGO-mgKG1F13F51xZ9d9brGFKK1v01tVSdKKm9-kNJnSgpKlShVIzvzsYDpLJ4V0BoTP_cfeHU81Ohz2edLVPfoY0qabSztgaj1VmZgP_76jeQcrAf</recordid><startdate>20060915</startdate><enddate>20060915</enddate><creator>Matrab, Tarik</creator><creator>Chancolon, Jérôme</creator><creator>L’hermite, Martine Mayne</creator><creator>Rouzaud, Jean-Noël</creator><creator>Deniau, Guy</creator><creator>Boudou, Jean-Paul</creator><creator>Chehimi, Mohamed M.</creator><creator>Delamar, Michel</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0002-6098-983X</orcidid></search><sort><creationdate>20060915</creationdate><title>Atom transfer radical polymerization (ATRP) initiated by aryl diazonium salts: a new route for surface modification of multiwalled carbon nanotubes by tethered polymer chains</title><author>Matrab, Tarik ; Chancolon, Jérôme ; L’hermite, Martine Mayne ; Rouzaud, Jean-Noël ; Deniau, Guy ; Boudou, Jean-Paul ; Chehimi, Mohamed M. ; Delamar, Michel</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c428t-fb9605f7a05c2d3778cdd5fed94ac0c6d02e89736734c28a5f7c8a23922563a53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Atom transfer radical polymerization (ATRP)</topic><topic>Carbon nanotubes</topic><topic>Chemical Sciences</topic><topic>Chemistry</topic><topic>Diazonium salts</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Material chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Matrab, Tarik</creatorcontrib><creatorcontrib>Chancolon, Jérôme</creatorcontrib><creatorcontrib>L’hermite, Martine Mayne</creatorcontrib><creatorcontrib>Rouzaud, Jean-Noël</creatorcontrib><creatorcontrib>Deniau, Guy</creatorcontrib><creatorcontrib>Boudou, Jean-Paul</creatorcontrib><creatorcontrib>Chehimi, Mohamed M.</creatorcontrib><creatorcontrib>Delamar, Michel</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Colloids and surfaces. A, Physicochemical and engineering aspects</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Matrab, Tarik</au><au>Chancolon, Jérôme</au><au>L’hermite, Martine Mayne</au><au>Rouzaud, Jean-Noël</au><au>Deniau, Guy</au><au>Boudou, Jean-Paul</au><au>Chehimi, Mohamed M.</au><au>Delamar, Michel</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Atom transfer radical polymerization (ATRP) initiated by aryl diazonium salts: a new route for surface modification of multiwalled carbon nanotubes by tethered polymer chains</atitle><jtitle>Colloids and surfaces. A, Physicochemical and engineering aspects</jtitle><date>2006-09-15</date><risdate>2006</risdate><volume>287</volume><issue>1</issue><spage>217</spage><epage>221</epage><pages>217-221</pages><issn>0927-7757</issn><eissn>1873-4359</eissn><abstract>We report for the first time on grafting of poly(
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| identifier | ISSN: 0927-7757 |
| ispartof | Colloids and surfaces. A, Physicochemical and engineering aspects, 2006-09, Vol.287 (1), p.217-221 |
| issn | 0927-7757 1873-4359 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_bioemco_00156637v1 |
| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Atom transfer radical polymerization (ATRP) Carbon nanotubes Chemical Sciences Chemistry Diazonium salts Exact sciences and technology General and physical chemistry Material chemistry |
| title | Atom transfer radical polymerization (ATRP) initiated by aryl diazonium salts: a new route for surface modification of multiwalled carbon nanotubes by tethered polymer chains |
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