Macromolecular coupling in seconds of triazolinedione end-functionalized polymers prepared by RAFT polymerization

The ultrafast and additive-free triazolinedione-click reaction with electron rich (di)enes is a powerful method for the ultrafast ligation of polymer segments. A versatile method is described for the introduction of dickable TAD end groups in various polymer segments, using reversible addition-fragm...

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Hauptverfasser:	Vandewalle, Stef, Billiet, Stijn, Driessen, Frank, Du Prez, Filip
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Sprache:	eng
Schlagworte:	BLOCK-COPOLYMERS Chemistry CLICK-CHEMISTRY ELECTROPHILIC AROMATIC-SUBSTITUTION FRAGMENTATION CHAIN TRANSFER HYPERBRANCHED POLYMERS METHACRYLATE SCIENCE TERMINAL ALKYNES THIOLACTONE CHEMISTRY
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creator	Vandewalle, Stef Billiet, Stijn Driessen, Frank Du Prez, Filip
description	The ultrafast and additive-free triazolinedione-click reaction with electron rich (di)enes is a powerful method for the ultrafast ligation of polymer segments. A versatile method is described for the introduction of dickable TAD end groups in various polymer segments, using reversible addition-fragmentation chain transfer polymerization. These triazolinedione-functionalized prepolymers were subsequently used for macromolecular functionalization with a low molecular weight diene and block copolymer synthesis of different types within seconds, at ambient conditions, through the coupling with diene-functionalized polymers such as poly(ethylene glycol) and poly(isobornyl acrylate).
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source	Ghent University Academic Bibliography; American Chemical Society Journals
subjects	BLOCK-COPOLYMERS Chemistry CLICK-CHEMISTRY ELECTROPHILIC AROMATIC-SUBSTITUTION FRAGMENTATION CHAIN TRANSFER HYPERBRANCHED POLYMERS METHACRYLATE SCIENCE TERMINAL ALKYNES THIOLACTONE CHEMISTRY
title	Macromolecular coupling in seconds of triazolinedione end-functionalized polymers prepared by RAFT polymerization
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