Interlayer charge transfer in supported and suspended MoS.sub.2/Graphene/MoS.sub.2 vertical heterostructures

In this letter, we report on the optical and structural properties of supported and suspended MoS.sub.2 /Graphene/MoS.sub.2 vertical heterostructures using Raman and photoluminescence (PL) spectroscopies. Vertical heterostructures (VH) are formed by multiple wet transfers on micro-sized holes in SiO...

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Veröffentlicht in:PloS one 2023-07, Vol.18 (7), p.e0283834
Hauptverfasser: Rocha Robledo, Ana K, Flores Salazar, Mario, Muñiz Martínez, Bárbara A, Torres-Rosales, Ángel A, Lara-Alfaro, Héctor F, Del Pozo-Zamudio, Osvaldo, Cerda-Méndez, Edgar A, Jiménez-Sandoval, Sergio, De Luna Bugallo, Andres
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container_title PloS one
container_volume 18
creator Rocha Robledo, Ana K
Flores Salazar, Mario
Muñiz Martínez, Bárbara A
Torres-Rosales, Ángel A
Lara-Alfaro, Héctor F
Del Pozo-Zamudio, Osvaldo
Cerda-Méndez, Edgar A
Jiménez-Sandoval, Sergio
De Luna Bugallo, Andres
description In this letter, we report on the optical and structural properties of supported and suspended MoS.sub.2 /Graphene/MoS.sub.2 vertical heterostructures using Raman and photoluminescence (PL) spectroscopies. Vertical heterostructures (VH) are formed by multiple wet transfers on micro-sized holes in SiO.sub.2 /Si substrates, resulting in VH with different configurations. The strong interlayer coupling is confirmed by Raman spectroscopy. Additionally, we observe an enhancement of the PL emission in the three-layer VH (either support or suspended) compared with bare MoS.sub.2 or MoS.sub.2 /Graphene. This suggests the formation of a spatial type-II band alignment assisted by the graphene layer and thus, the operation of the VH as a n++/metal/n junction.
doi_str_mv 10.1371/journal.pone.0283834
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subjects Analysis
Comparative analysis
Evaluation
Graphene
Photoluminescence
Properties
Raman spectroscopy
title Interlayer charge transfer in supported and suspended MoS.sub.2/Graphene/MoS.sub.2 vertical heterostructures
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