Synthesis and Transport and Ionophoric Properties of [alpha],[omega]-Diphosphorylated Azapodands: XII. Membrane Transport of Organic Acids by Diphosphorylated Diamines and Diazapodands

Synthesis and Transport and Ionophoric Properties of [alpha],[omega]-Diphosphorylated Azapodands: XII. Membrane Transport of Organic Acids by Diphosphorylated Diamines and Diazapodands

Membrane transport of mono- and polyfunctional carboxylic acids mediated by phosphorylated diamines has been studied. The structure of complexes transferred through the membrane has been discussed; in some cases, a relation has been found between the efficiency of membrane transport of organic acid...

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Veröffentlicht in:Russian journal of general chemistry 2019-12, Vol.89 (12), p.2424
Hauptverfasser: Davletshina, N.V, Nasyrov, I.R, Khabibullina, A.R, Davletshin, R.R, Gaynullin, A.Z, Cherkasov, R.A
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container_issue 12
container_start_page 2424
container_title Russian journal of general chemistry
container_volume 89
creator Davletshina, N.V
Nasyrov, I.R
Khabibullina, A.R
Davletshin, R.R
Gaynullin, A.Z
Cherkasov, R.A
description Membrane transport of mono- and polyfunctional carboxylic acids mediated by phosphorylated diamines has been studied. The structure of complexes transferred through the membrane has been discussed; in some cases, a relation has been found between the efficiency of membrane transport of organic acid substrates and the structure of membrane carriers and their complexes with the acids. A correlation between the transmembrane flow and shift of some characteristic IR absorption bands (as well as change of their intensity) of the substrate-carrier complexes in comparison to the corresponding substrates and carriers has been estimated. Keywords: diphosphorylated diamines, azapodands, membrane extraction, aminophosphoryl carrier DOI: 10.1134/S1070363219120168
doi_str_mv 10.1134/S1070363219120168
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Organic acids
title Synthesis and Transport and Ionophoric Properties of [alpha],[omega]-Diphosphorylated Azapodands: XII. Membrane Transport of Organic Acids by Diphosphorylated Diamines and Diazapodands
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