Preparation, characterization, and determination of mechanical and thermal stability of natural zeolite-based foamed geopolymers

[Display omitted] •Foamed geopolymers were prepared for the first time by the alkaline activation of Ecuadorian natural zeolite.•Different amounts of Al powder and H2O2 (30% water solution) were used as foaming agents.•The compressive strength results met Ecuadorian technical standards NTE INEN 643...

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Veröffentlicht in:Construction & building materials 2018-05, Vol.172, p.448-456
Hauptverfasser: Lynch, José Luis Villalba, Baykara, Haci, Cornejo, Mauricio, Soriano, Guillermo, Ulloa, Néstor A.
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container_end_page 456
container_issue
container_start_page 448
container_title Construction & building materials
container_volume 172
creator Lynch, José Luis Villalba
Baykara, Haci
Cornejo, Mauricio
Soriano, Guillermo
Ulloa, Néstor A.
description [Display omitted] •Foamed geopolymers were prepared for the first time by the alkaline activation of Ecuadorian natural zeolite.•Different amounts of Al powder and H2O2 (30% water solution) were used as foaming agents.•The compressive strength results met Ecuadorian technical standards NTE INEN 643 and NTE INEN 638.•Potential isolation materials were prepared for construction industry. This study is the first attempt to evaluate the effect of two foaming agents, aluminum powder and hydrogen peroxide (30 wt% water solution) on zeolite-based geopolymers and their possible use as building material according to Ecuadorian technical standards. These foamed geopolymers were prepared by alkali activation of an Ecuadorian natural zeolitic tuff and by alkali activation using NaOH (10 M), Ca(OH)2 and Na4Si5O12, with the use of two different foaming agents mentioned. In the case of aluminum powder, the experimental range was between 0.05 and 0.25 wt%; on the other hand, the percentages of hydrogen peroxide ranged from 0.5 to 4.0%. For characterization of the foamed geopolymer samples, quantitative X-ray diffraction (QXRD), thermogravimetric (TGA), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM) techniques were used. The results of both foaming agents in zeolite-based geopolymers met Ecuadorian technical standards NTE INEN 643 and NTE INEN 638; nevertheless, the use of aluminum powder as foaming agent exhibited a better pore size distribution, suggesting a better performance. On the basis of these results, foamed geopolymers are suitable construction materials for the application of manufactured for masonry wall in houses.
doi_str_mv 10.1016/j.conbuildmat.2018.03.253
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This study is the first attempt to evaluate the effect of two foaming agents, aluminum powder and hydrogen peroxide (30 wt% water solution) on zeolite-based geopolymers and their possible use as building material according to Ecuadorian technical standards. These foamed geopolymers were prepared by alkali activation of an Ecuadorian natural zeolitic tuff and by alkali activation using NaOH (10 M), Ca(OH)2 and Na4Si5O12, with the use of two different foaming agents mentioned. In the case of aluminum powder, the experimental range was between 0.05 and 0.25 wt%; on the other hand, the percentages of hydrogen peroxide ranged from 0.5 to 4.0%. For characterization of the foamed geopolymer samples, quantitative X-ray diffraction (QXRD), thermogravimetric (TGA), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM) techniques were used. The results of both foaming agents in zeolite-based geopolymers met Ecuadorian technical standards NTE INEN 643 and NTE INEN 638; nevertheless, the use of aluminum powder as foaming agent exhibited a better pore size distribution, suggesting a better performance. 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This study is the first attempt to evaluate the effect of two foaming agents, aluminum powder and hydrogen peroxide (30 wt% water solution) on zeolite-based geopolymers and their possible use as building material according to Ecuadorian technical standards. These foamed geopolymers were prepared by alkali activation of an Ecuadorian natural zeolitic tuff and by alkali activation using NaOH (10 M), Ca(OH)2 and Na4Si5O12, with the use of two different foaming agents mentioned. In the case of aluminum powder, the experimental range was between 0.05 and 0.25 wt%; on the other hand, the percentages of hydrogen peroxide ranged from 0.5 to 4.0%. For characterization of the foamed geopolymer samples, quantitative X-ray diffraction (QXRD), thermogravimetric (TGA), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM) techniques were used. 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source ScienceDirect Journals (5 years ago - present)
subjects Aluminum powder
Analysis
Chemical properties
Concretes
Ecuadorian natural zeolite
Foamed geopolymer
Hydrogen peroxide
Mechanical properties
Potential Isolation materials
Thermal properties
Volcanic rocks
Zeolites
title Preparation, characterization, and determination of mechanical and thermal stability of natural zeolite-based foamed geopolymers
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