Identification of Barrenwort flavonoids by high-resolution tandem mass spectrometry
Fragmentation of the main Barrenwort flavonoids—icariin, icaritin, icarisides I and II, and epimedins A and B—is studied by tandem mass spectrometry. High-resolution mass spectra of positively charged ions of these compounds are obtained under the conditions of collision-induced dissociation. Charac...
Gespeichert in:
| Veröffentlicht in: | Journal of analytical chemistry (New York, N.Y.) N.Y.), 2016-08, Vol.71 (8), p.768-776 |
|---|---|
| Hauptverfasser: | , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 776 |
|---|---|
| container_issue | 8 |
| container_start_page | 768 |
| container_title | Journal of analytical chemistry (New York, N.Y.) |
| container_volume | 71 |
| creator | Shevlyakova, O. A. Vasil’ev, K. Yu Ikhalainen, A. A. Antokhin, A. M. Taranchenko, V. F. Goncharov, V. M. Mitrofanov, D. A. Aksenov, A. V. Rodin, I. A. Shpigun, O. A. |
| description | Fragmentation of the main Barrenwort flavonoids—icariin, icaritin, icarisides I and II, and epimedins A and B—is studied by tandem mass spectrometry. High-resolution mass spectra of positively charged ions of these compounds are obtained under the conditions of collision-induced dissociation. Characteristic fragment ions are determined, which ensured the classification of unknown compounds as Barrenwort flavonoids. Epimedin C was isolated from raw plant material by preparative liquid chromatography; its structure was confirmed by
1
H and
13
C NMR spectra. |
| doi_str_mv | 10.1134/S106193481608013X |
| format | Article |
| fullrecord | <record><control><sourceid>gale_cross</sourceid><recordid>TN_cdi_gale_infotracmisc_A496346100</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A496346100</galeid><sourcerecordid>A496346100</sourcerecordid><originalsourceid>FETCH-LOGICAL-c427t-3649e5a8b362005609e2682f7a13d68f795517f34acbb4a075245ac02fcec3093</originalsourceid><addsrcrecordid>eNp90c9LwzAUB_AiCs7pH-Ct4MlDZ9KkaXOc4o_BQHAK3kqavXQZbTKSTN1_b-a8DIfkkEfe5xtIXpJcYjTCmNCbGUYMc0IrzFCFMHk_SgbbMiOY8-NYx3a27Z8mZ94vEUI80kEym8zBBK20FEFbk1qV3grnwHxaF1LViQ9rrJ77tNmkC90uMgfedusfG4SZQ5_2wvvUr0AGZ3sIbnOenCjRebj43YfJ28P9691TNn1-nNyNp5mkeRkywiiHQlQNYTlCBUMcclblqhSYzFmlSl4UuFSECtk0VKCyyGkhJMqVBEkQJ8PkandvKzqotVE2OCF77WU9ppwRyjBCUWUHVAsGnOisAaXj8Z4fHfBxxbdqeTBwvReIJsBXaMXa-3oye9m3eGels947UPXK6V64TY1RvR1k_WeQMZPvMj5a04Krl3btTPzZf0Lfnqudpw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Identification of Barrenwort flavonoids by high-resolution tandem mass spectrometry</title><source>SpringerLink Journals - AutoHoldings</source><creator>Shevlyakova, O. A. ; Vasil’ev, K. Yu ; Ikhalainen, A. A. ; Antokhin, A. M. ; Taranchenko, V. F. ; Goncharov, V. M. ; Mitrofanov, D. A. ; Aksenov, A. V. ; Rodin, I. A. ; Shpigun, O. A.</creator><creatorcontrib>Shevlyakova, O. A. ; Vasil’ev, K. Yu ; Ikhalainen, A. A. ; Antokhin, A. M. ; Taranchenko, V. F. ; Goncharov, V. M. ; Mitrofanov, D. A. ; Aksenov, A. V. ; Rodin, I. A. ; Shpigun, O. A.</creatorcontrib><description>Fragmentation of the main Barrenwort flavonoids—icariin, icaritin, icarisides I and II, and epimedins A and B—is studied by tandem mass spectrometry. High-resolution mass spectra of positively charged ions of these compounds are obtained under the conditions of collision-induced dissociation. Characteristic fragment ions are determined, which ensured the classification of unknown compounds as Barrenwort flavonoids. Epimedin C was isolated from raw plant material by preparative liquid chromatography; its structure was confirmed by
1
H and
13
C NMR spectra.</description><identifier>ISSN: 1061-9348</identifier><identifier>EISSN: 1608-3199</identifier><identifier>DOI: 10.1134/S106193481608013X</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Analytical Chemistry ; Chemical properties ; Chemistry ; Chemistry and Materials Science ; Flavonoids ; Mass spectrometry ; Methods</subject><ispartof>Journal of analytical chemistry (New York, N.Y.), 2016-08, Vol.71 (8), p.768-776</ispartof><rights>Pleiades Publishing, Ltd. 2016</rights><rights>COPYRIGHT 2016 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c427t-3649e5a8b362005609e2682f7a13d68f795517f34acbb4a075245ac02fcec3093</citedby><cites>FETCH-LOGICAL-c427t-3649e5a8b362005609e2682f7a13d68f795517f34acbb4a075245ac02fcec3093</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S106193481608013X$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S106193481608013X$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27922,27923,41486,42555,51317</link.rule.ids></links><search><creatorcontrib>Shevlyakova, O. A.</creatorcontrib><creatorcontrib>Vasil’ev, K. Yu</creatorcontrib><creatorcontrib>Ikhalainen, A. A.</creatorcontrib><creatorcontrib>Antokhin, A. M.</creatorcontrib><creatorcontrib>Taranchenko, V. F.</creatorcontrib><creatorcontrib>Goncharov, V. M.</creatorcontrib><creatorcontrib>Mitrofanov, D. A.</creatorcontrib><creatorcontrib>Aksenov, A. V.</creatorcontrib><creatorcontrib>Rodin, I. A.</creatorcontrib><creatorcontrib>Shpigun, O. A.</creatorcontrib><title>Identification of Barrenwort flavonoids by high-resolution tandem mass spectrometry</title><title>Journal of analytical chemistry (New York, N.Y.)</title><addtitle>J Anal Chem</addtitle><description>Fragmentation of the main Barrenwort flavonoids—icariin, icaritin, icarisides I and II, and epimedins A and B—is studied by tandem mass spectrometry. High-resolution mass spectra of positively charged ions of these compounds are obtained under the conditions of collision-induced dissociation. Characteristic fragment ions are determined, which ensured the classification of unknown compounds as Barrenwort flavonoids. Epimedin C was isolated from raw plant material by preparative liquid chromatography; its structure was confirmed by
1
H and
13
C NMR spectra.</description><subject>Analytical Chemistry</subject><subject>Chemical properties</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Flavonoids</subject><subject>Mass spectrometry</subject><subject>Methods</subject><issn>1061-9348</issn><issn>1608-3199</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp90c9LwzAUB_AiCs7pH-Ct4MlDZ9KkaXOc4o_BQHAK3kqavXQZbTKSTN1_b-a8DIfkkEfe5xtIXpJcYjTCmNCbGUYMc0IrzFCFMHk_SgbbMiOY8-NYx3a27Z8mZ94vEUI80kEym8zBBK20FEFbk1qV3grnwHxaF1LViQ9rrJ77tNmkC90uMgfedusfG4SZQ5_2wvvUr0AGZ3sIbnOenCjRebj43YfJ28P9691TNn1-nNyNp5mkeRkywiiHQlQNYTlCBUMcclblqhSYzFmlSl4UuFSECtk0VKCyyGkhJMqVBEkQJ8PkandvKzqotVE2OCF77WU9ppwRyjBCUWUHVAsGnOisAaXj8Z4fHfBxxbdqeTBwvReIJsBXaMXa-3oye9m3eGels947UPXK6V64TY1RvR1k_WeQMZPvMj5a04Krl3btTPzZf0Lfnqudpw</recordid><startdate>20160801</startdate><enddate>20160801</enddate><creator>Shevlyakova, O. A.</creator><creator>Vasil’ev, K. Yu</creator><creator>Ikhalainen, A. A.</creator><creator>Antokhin, A. M.</creator><creator>Taranchenko, V. F.</creator><creator>Goncharov, V. M.</creator><creator>Mitrofanov, D. A.</creator><creator>Aksenov, A. V.</creator><creator>Rodin, I. A.</creator><creator>Shpigun, O. A.</creator><general>Pleiades Publishing</general><general>Springer</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope></search><sort><creationdate>20160801</creationdate><title>Identification of Barrenwort flavonoids by high-resolution tandem mass spectrometry</title><author>Shevlyakova, O. A. ; Vasil’ev, K. Yu ; Ikhalainen, A. A. ; Antokhin, A. M. ; Taranchenko, V. F. ; Goncharov, V. M. ; Mitrofanov, D. A. ; Aksenov, A. V. ; Rodin, I. A. ; Shpigun, O. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c427t-3649e5a8b362005609e2682f7a13d68f795517f34acbb4a075245ac02fcec3093</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Analytical Chemistry</topic><topic>Chemical properties</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Flavonoids</topic><topic>Mass spectrometry</topic><topic>Methods</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shevlyakova, O. A.</creatorcontrib><creatorcontrib>Vasil’ev, K. Yu</creatorcontrib><creatorcontrib>Ikhalainen, A. A.</creatorcontrib><creatorcontrib>Antokhin, A. M.</creatorcontrib><creatorcontrib>Taranchenko, V. F.</creatorcontrib><creatorcontrib>Goncharov, V. M.</creatorcontrib><creatorcontrib>Mitrofanov, D. A.</creatorcontrib><creatorcontrib>Aksenov, A. V.</creatorcontrib><creatorcontrib>Rodin, I. A.</creatorcontrib><creatorcontrib>Shpigun, O. A.</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><jtitle>Journal of analytical chemistry (New York, N.Y.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shevlyakova, O. A.</au><au>Vasil’ev, K. Yu</au><au>Ikhalainen, A. A.</au><au>Antokhin, A. M.</au><au>Taranchenko, V. F.</au><au>Goncharov, V. M.</au><au>Mitrofanov, D. A.</au><au>Aksenov, A. V.</au><au>Rodin, I. A.</au><au>Shpigun, O. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Identification of Barrenwort flavonoids by high-resolution tandem mass spectrometry</atitle><jtitle>Journal of analytical chemistry (New York, N.Y.)</jtitle><stitle>J Anal Chem</stitle><date>2016-08-01</date><risdate>2016</risdate><volume>71</volume><issue>8</issue><spage>768</spage><epage>776</epage><pages>768-776</pages><issn>1061-9348</issn><eissn>1608-3199</eissn><abstract>Fragmentation of the main Barrenwort flavonoids—icariin, icaritin, icarisides I and II, and epimedins A and B—is studied by tandem mass spectrometry. High-resolution mass spectra of positively charged ions of these compounds are obtained under the conditions of collision-induced dissociation. Characteristic fragment ions are determined, which ensured the classification of unknown compounds as Barrenwort flavonoids. Epimedin C was isolated from raw plant material by preparative liquid chromatography; its structure was confirmed by
1
H and
13
C NMR spectra.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S106193481608013X</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1061-9348 |
| ispartof | Journal of analytical chemistry (New York, N.Y.), 2016-08, Vol.71 (8), p.768-776 |
| issn | 1061-9348 1608-3199 |
| language | eng |
| recordid | cdi_gale_infotracmisc_A496346100 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Analytical Chemistry Chemical properties Chemistry Chemistry and Materials Science Flavonoids Mass spectrometry Methods |
| title | Identification of Barrenwort flavonoids by high-resolution tandem mass spectrometry |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-10T09%3A16%3A53IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Identification%20of%20Barrenwort%20flavonoids%20by%20high-resolution%20tandem%20mass%20spectrometry&rft.jtitle=Journal%20of%20analytical%20chemistry%20(New%20York,%20N.Y.)&rft.au=Shevlyakova,%20O.%20A.&rft.date=2016-08-01&rft.volume=71&rft.issue=8&rft.spage=768&rft.epage=776&rft.pages=768-776&rft.issn=1061-9348&rft.eissn=1608-3199&rft_id=info:doi/10.1134/S106193481608013X&rft_dat=%3Cgale_cross%3EA496346100%3C/gale_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rft_galeid=A496346100&rfr_iscdi=true |