Analysis of silyl derivatives of methylphosphonic acid esters by gas chromatography-mass spectrometry with atmospheric pressure photoionization
Using trimethylsilyl (TMS) and tert -butyldimethylsilyl (TBDMS) derivatives of methylphosphonic acid and methylphosphonic acid esters, a comparative study of two ionization methods, namely, atmospheric pressure photoionization (APPhI) and photochemical ionization (APCPhI), in gas chromatography/mass...
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| Veröffentlicht in: | Journal of analytical chemistry (New York, N.Y.) N.Y.), 2014-12, Vol.69 (14), p.1356-1360 |
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| container_title | Journal of analytical chemistry (New York, N.Y.) |
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| creator | Yashin, Yu. S. Revelsky, I. A. Tikhonova, I. N. |
| description | Using trimethylsilyl (TMS) and
tert
-butyldimethylsilyl (TBDMS) derivatives of methylphosphonic acid and methylphosphonic acid esters, a comparative study of two ionization methods, namely, atmospheric pressure photoionization (APPhI) and photochemical ionization (APCPhI), in gas chromatography/mass spectrometry has been performed. It has been shown that, in the case of APPhI, the mass spectra of TMS and TBDMS derivatives contained only peaks corresponding to [M + 73]
+
and [M + 115]
+
(or [M + Si(Me)
3
]
+
and [M + Si(
t
Bu)(Me)
2
]
+
ions, respectively, where M is the molecular mass of a respective TMS or TBDMS derivative of methylphosphonic ester). APCPhI mass spectra recorded in the presence of acetone as a reagent substance consisted of only peaks of [M + H]
+
and [M + M
A
+ H]
+
ions (M
A
is acetone molecule). The corresponding detection limits for silylated derivatives in APPhI and APCPhI were 30–125 pg and 1.1–23 pg, respectively (depending on the analyte). |
| doi_str_mv | 10.1134/S1061934814140135 |
| format | Article |
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tert
-butyldimethylsilyl (TBDMS) derivatives of methylphosphonic acid and methylphosphonic acid esters, a comparative study of two ionization methods, namely, atmospheric pressure photoionization (APPhI) and photochemical ionization (APCPhI), in gas chromatography/mass spectrometry has been performed. It has been shown that, in the case of APPhI, the mass spectra of TMS and TBDMS derivatives contained only peaks corresponding to [M + 73]
+
and [M + 115]
+
(or [M + Si(Me)
3
]
+
and [M + Si(
t
Bu)(Me)
2
]
+
ions, respectively, where M is the molecular mass of a respective TMS or TBDMS derivative of methylphosphonic ester). APCPhI mass spectra recorded in the presence of acetone as a reagent substance consisted of only peaks of [M + H]
+
and [M + M
A
+ H]
+
ions (M
A
is acetone molecule). The corresponding detection limits for silylated derivatives in APPhI and APCPhI were 30–125 pg and 1.1–23 pg, respectively (depending on the analyte).</description><identifier>ISSN: 1061-9348</identifier><identifier>EISSN: 1608-3199</identifier><identifier>DOI: 10.1134/S1061934814140135</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Analytical Chemistry ; Atmospheric pressure ; Chemical properties ; Chemistry ; Chemistry and Materials Science ; Esters ; Gas chromatography ; Identification and classification ; Mass spectrometry ; Methods ; Photoionization</subject><ispartof>Journal of analytical chemistry (New York, N.Y.), 2014-12, Vol.69 (14), p.1356-1360</ispartof><rights>Pleiades Publishing, Ltd. 2014</rights><rights>COPYRIGHT 2014 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c427t-4fe12b86f2dcc4622e73dcb693724bea1954ce8ecbe6ac566fd67812e3b09ab23</citedby><cites>FETCH-LOGICAL-c427t-4fe12b86f2dcc4622e73dcb693724bea1954ce8ecbe6ac566fd67812e3b09ab23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1061934814140135$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1061934814140135$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,781,785,27926,27927,41490,42559,51321</link.rule.ids></links><search><creatorcontrib>Yashin, Yu. S.</creatorcontrib><creatorcontrib>Revelsky, I. A.</creatorcontrib><creatorcontrib>Tikhonova, I. N.</creatorcontrib><title>Analysis of silyl derivatives of methylphosphonic acid esters by gas chromatography-mass spectrometry with atmospheric pressure photoionization</title><title>Journal of analytical chemistry (New York, N.Y.)</title><addtitle>J Anal Chem</addtitle><description>Using trimethylsilyl (TMS) and
tert
-butyldimethylsilyl (TBDMS) derivatives of methylphosphonic acid and methylphosphonic acid esters, a comparative study of two ionization methods, namely, atmospheric pressure photoionization (APPhI) and photochemical ionization (APCPhI), in gas chromatography/mass spectrometry has been performed. It has been shown that, in the case of APPhI, the mass spectra of TMS and TBDMS derivatives contained only peaks corresponding to [M + 73]
+
and [M + 115]
+
(or [M + Si(Me)
3
]
+
and [M + Si(
t
Bu)(Me)
2
]
+
ions, respectively, where M is the molecular mass of a respective TMS or TBDMS derivative of methylphosphonic ester). APCPhI mass spectra recorded in the presence of acetone as a reagent substance consisted of only peaks of [M + H]
+
and [M + M
A
+ H]
+
ions (M
A
is acetone molecule). The corresponding detection limits for silylated derivatives in APPhI and APCPhI were 30–125 pg and 1.1–23 pg, respectively (depending on the analyte).</description><subject>Analytical Chemistry</subject><subject>Atmospheric pressure</subject><subject>Chemical properties</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Esters</subject><subject>Gas chromatography</subject><subject>Identification and classification</subject><subject>Mass spectrometry</subject><subject>Methods</subject><subject>Photoionization</subject><issn>1061-9348</issn><issn>1608-3199</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp9ksFO3DAQhqOqlaC0D8DNUk89BGzH6yTHFaIFCQkJ6DmaOJPEKIkjjxeavgSvjJftZcUKWZatme__fPAkyangZ0Jk6vxecC3KTBVCCcVFtvqUHAvNizQTZfk53mM73faPkq9Ej5zzshD6OHlZTzAsZIm5lpEdloE16O0TBPuEb8URQ78Mc-8o7skaBsY2DCmgJ1YvrANipvduhOA6D3O_pCMQMZrRhFjG4Bf2bEPPIIxbSdQbNnsk2nhkURqcjeJ_8Uk3fUu-tDAQfv9_niR_fl0-XFylN7e_ry_WN6lRMg-palHIutCtbIxRWkrMs8bUusxyqWoEUa6UwQJNjRrMSuu20XkhJGY1L6GW2UnyY-ftYMDKTq0LHsxoyVRrxfOSq6iKVHqA6nBCD4ObsLWxvMefHeDjanC05mDg514gMgH_hg42RNX1_d0-K3as8Y7IY1vN3o7gl0rwajsE1bshiBm5y1Bkpw599eg2Pn45fRB6Bdw3ts4</recordid><startdate>20141230</startdate><enddate>20141230</enddate><creator>Yashin, Yu. S.</creator><creator>Revelsky, I. A.</creator><creator>Tikhonova, I. N.</creator><general>Pleiades Publishing</general><general>Springer</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope></search><sort><creationdate>20141230</creationdate><title>Analysis of silyl derivatives of methylphosphonic acid esters by gas chromatography-mass spectrometry with atmospheric pressure photoionization</title><author>Yashin, Yu. S. ; Revelsky, I. A. ; Tikhonova, I. N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c427t-4fe12b86f2dcc4622e73dcb693724bea1954ce8ecbe6ac566fd67812e3b09ab23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Analytical Chemistry</topic><topic>Atmospheric pressure</topic><topic>Chemical properties</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Esters</topic><topic>Gas chromatography</topic><topic>Identification and classification</topic><topic>Mass spectrometry</topic><topic>Methods</topic><topic>Photoionization</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yashin, Yu. S.</creatorcontrib><creatorcontrib>Revelsky, I. A.</creatorcontrib><creatorcontrib>Tikhonova, I. N.</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><jtitle>Journal of analytical chemistry (New York, N.Y.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yashin, Yu. S.</au><au>Revelsky, I. A.</au><au>Tikhonova, I. N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Analysis of silyl derivatives of methylphosphonic acid esters by gas chromatography-mass spectrometry with atmospheric pressure photoionization</atitle><jtitle>Journal of analytical chemistry (New York, N.Y.)</jtitle><stitle>J Anal Chem</stitle><date>2014-12-30</date><risdate>2014</risdate><volume>69</volume><issue>14</issue><spage>1356</spage><epage>1360</epage><pages>1356-1360</pages><issn>1061-9348</issn><eissn>1608-3199</eissn><abstract>Using trimethylsilyl (TMS) and
tert
-butyldimethylsilyl (TBDMS) derivatives of methylphosphonic acid and methylphosphonic acid esters, a comparative study of two ionization methods, namely, atmospheric pressure photoionization (APPhI) and photochemical ionization (APCPhI), in gas chromatography/mass spectrometry has been performed. It has been shown that, in the case of APPhI, the mass spectra of TMS and TBDMS derivatives contained only peaks corresponding to [M + 73]
+
and [M + 115]
+
(or [M + Si(Me)
3
]
+
and [M + Si(
t
Bu)(Me)
2
]
+
ions, respectively, where M is the molecular mass of a respective TMS or TBDMS derivative of methylphosphonic ester). APCPhI mass spectra recorded in the presence of acetone as a reagent substance consisted of only peaks of [M + H]
+
and [M + M
A
+ H]
+
ions (M
A
is acetone molecule). The corresponding detection limits for silylated derivatives in APPhI and APCPhI were 30–125 pg and 1.1–23 pg, respectively (depending on the analyte).</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1061934814140135</doi><tpages>5</tpages></addata></record> |
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| issn | 1061-9348 1608-3199 |
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| subjects | Analytical Chemistry Atmospheric pressure Chemical properties Chemistry Chemistry and Materials Science Esters Gas chromatography Identification and classification Mass spectrometry Methods Photoionization |
| title | Analysis of silyl derivatives of methylphosphonic acid esters by gas chromatography-mass spectrometry with atmospheric pressure photoionization |
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