Nickel-tungsten sulfide polyaromatic hydrocarbon hydrogenation nanocatalysts prepared in an ionic liquid
Nickel-tungsten sulfide nanocatalysts for the hydrogenation of aromatic hydrocarbons (HCs) have been prepared by the in situ decomposition of nickel thiotungstate precursors in an ionic liquid (IL) using the [BMPip] 2 Ni(WS 4 ) 2 nickel thiotungstate complex as a precursor and the thermally stable I...
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| Veröffentlicht in: | Petroleum chemistry 2015, Vol.55 (1), p.38-44 |
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| container_title | Petroleum chemistry |
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| creator | Sizova, I. A. Serdyukov, S. I. Maksimov, A. L. Sinikova, N. A. |
| description | Nickel-tungsten sulfide nanocatalysts for the hydrogenation of aromatic hydrocarbons (HCs) have been prepared by the in situ decomposition of nickel thiotungstate precursors in an ionic liquid (IL) using the [BMPip]
2
Ni(WS
4
)
2
nickel thiotungstate complex as a precursor and the thermally stable IL 1-butyl-1-methylpiperidinium trifluoromethanesulfonate BMPipCF
3
SO
3
as a solvent for the precursor. The Ni-W-S particles in situ synthesized in the IL have been characterized by X-ray photoelectron spectroscopy and TEM. It has been shown that the particles are 0.5-nm-wide nanoplates associated in agglomerates with a diameter of 100–150 nm. Catalytic activity has been studied using the example of naphthalene hydrogenation in various solvents in a batch reactor at a temperature of 350°C and a pressure of 5.0 MPa. It has been shown that the IL can be used for the selective hydrogenation of aromatic HCs in a mixture with olefins. |
| doi_str_mv | 10.1134/S0965544115010120 |
| format | Article |
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2
Ni(WS
4
)
2
nickel thiotungstate complex as a precursor and the thermally stable IL 1-butyl-1-methylpiperidinium trifluoromethanesulfonate BMPipCF
3
SO
3
as a solvent for the precursor. The Ni-W-S particles in situ synthesized in the IL have been characterized by X-ray photoelectron spectroscopy and TEM. It has been shown that the particles are 0.5-nm-wide nanoplates associated in agglomerates with a diameter of 100–150 nm. Catalytic activity has been studied using the example of naphthalene hydrogenation in various solvents in a batch reactor at a temperature of 350°C and a pressure of 5.0 MPa. It has been shown that the IL can be used for the selective hydrogenation of aromatic HCs in a mixture with olefins.</description><identifier>ISSN: 0965-5441</identifier><identifier>EISSN: 1555-6239</identifier><identifier>DOI: 10.1134/S0965544115010120</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Catalysis ; Chemistry ; Chemistry and Materials Science ; Hydrogenation ; Industrial Chemistry/Chemical Engineering ; Nickel ; Somatotropin ; Sulfides ; Tungsten ; Tungsten compounds</subject><ispartof>Petroleum chemistry, 2015, Vol.55 (1), p.38-44</ispartof><rights>Pleiades Publishing, Ltd. 2015</rights><rights>COPYRIGHT 2015 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c355t-74a7727c68edad24345b4e0a76630a3f6535259cc4a540e5dcf058414fe0ae983</citedby><cites>FETCH-LOGICAL-c355t-74a7727c68edad24345b4e0a76630a3f6535259cc4a540e5dcf058414fe0ae983</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0965544115010120$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0965544115010120$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Sizova, I. A.</creatorcontrib><creatorcontrib>Serdyukov, S. I.</creatorcontrib><creatorcontrib>Maksimov, A. L.</creatorcontrib><creatorcontrib>Sinikova, N. A.</creatorcontrib><title>Nickel-tungsten sulfide polyaromatic hydrocarbon hydrogenation nanocatalysts prepared in an ionic liquid</title><title>Petroleum chemistry</title><addtitle>Pet. Chem</addtitle><description>Nickel-tungsten sulfide nanocatalysts for the hydrogenation of aromatic hydrocarbons (HCs) have been prepared by the in situ decomposition of nickel thiotungstate precursors in an ionic liquid (IL) using the [BMPip]
2
Ni(WS
4
)
2
nickel thiotungstate complex as a precursor and the thermally stable IL 1-butyl-1-methylpiperidinium trifluoromethanesulfonate BMPipCF
3
SO
3
as a solvent for the precursor. The Ni-W-S particles in situ synthesized in the IL have been characterized by X-ray photoelectron spectroscopy and TEM. It has been shown that the particles are 0.5-nm-wide nanoplates associated in agglomerates with a diameter of 100–150 nm. Catalytic activity has been studied using the example of naphthalene hydrogenation in various solvents in a batch reactor at a temperature of 350°C and a pressure of 5.0 MPa. It has been shown that the IL can be used for the selective hydrogenation of aromatic HCs in a mixture with olefins.</description><subject>Catalysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Hydrogenation</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Nickel</subject><subject>Somatotropin</subject><subject>Sulfides</subject><subject>Tungsten</subject><subject>Tungsten compounds</subject><issn>0965-5441</issn><issn>1555-6239</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9kclOwzAQhi0EEqXwANwicU6xY0-WY1WxSRUcgHPkekldEjvYySFvj6twQSDkg5f_-yzNDELXBK8Ioez2FVc5AGOEACaYZPgELQgApHlGq1O0OMbpMT9HFyEcMCYFYXSB9s9GfKg2HUbbhEHZJIytNlIlvWsn7l3HByOS_SS9E9zvnJ3PjbIxiDfLbQwG3k5hCEnvVc-9komxCbdJBKLcms_RyEt0pnkb1NX3vkTv93dvm8d0-_LwtFlvU0EBhrRgvCiyQuSlklxmjDLYMYV5kecUc6pzoJBBJQTjwLACKTSGkhGmI6Sqki7Rzfxvw1tVG6vd4LnoTBD1muECsjK2KFKrP6i4pOqMcFZpE99_CGQWhHcheKXr3puO-6kmuD5OoP41gehksxMiaxvl64MbvY3V_yN9AZaTiI0</recordid><startdate>2015</startdate><enddate>2015</enddate><creator>Sizova, I. A.</creator><creator>Serdyukov, S. I.</creator><creator>Maksimov, A. L.</creator><creator>Sinikova, N. A.</creator><general>Pleiades Publishing</general><general>Springer</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2015</creationdate><title>Nickel-tungsten sulfide polyaromatic hydrocarbon hydrogenation nanocatalysts prepared in an ionic liquid</title><author>Sizova, I. A. ; Serdyukov, S. I. ; Maksimov, A. L. ; Sinikova, N. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c355t-74a7727c68edad24345b4e0a76630a3f6535259cc4a540e5dcf058414fe0ae983</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Catalysis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Hydrogenation</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Nickel</topic><topic>Somatotropin</topic><topic>Sulfides</topic><topic>Tungsten</topic><topic>Tungsten compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sizova, I. A.</creatorcontrib><creatorcontrib>Serdyukov, S. I.</creatorcontrib><creatorcontrib>Maksimov, A. L.</creatorcontrib><creatorcontrib>Sinikova, N. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Petroleum chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sizova, I. A.</au><au>Serdyukov, S. I.</au><au>Maksimov, A. L.</au><au>Sinikova, N. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nickel-tungsten sulfide polyaromatic hydrocarbon hydrogenation nanocatalysts prepared in an ionic liquid</atitle><jtitle>Petroleum chemistry</jtitle><stitle>Pet. Chem</stitle><date>2015</date><risdate>2015</risdate><volume>55</volume><issue>1</issue><spage>38</spage><epage>44</epage><pages>38-44</pages><issn>0965-5441</issn><eissn>1555-6239</eissn><abstract>Nickel-tungsten sulfide nanocatalysts for the hydrogenation of aromatic hydrocarbons (HCs) have been prepared by the in situ decomposition of nickel thiotungstate precursors in an ionic liquid (IL) using the [BMPip]
2
Ni(WS
4
)
2
nickel thiotungstate complex as a precursor and the thermally stable IL 1-butyl-1-methylpiperidinium trifluoromethanesulfonate BMPipCF
3
SO
3
as a solvent for the precursor. The Ni-W-S particles in situ synthesized in the IL have been characterized by X-ray photoelectron spectroscopy and TEM. It has been shown that the particles are 0.5-nm-wide nanoplates associated in agglomerates with a diameter of 100–150 nm. Catalytic activity has been studied using the example of naphthalene hydrogenation in various solvents in a batch reactor at a temperature of 350°C and a pressure of 5.0 MPa. It has been shown that the IL can be used for the selective hydrogenation of aromatic HCs in a mixture with olefins.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0965544115010120</doi><tpages>7</tpages></addata></record> |
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| language | eng |
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| source | SpringerLink Journals; EBSCOhost Business Source Complete |
| subjects | Catalysis Chemistry Chemistry and Materials Science Hydrogenation Industrial Chemistry/Chemical Engineering Nickel Somatotropin Sulfides Tungsten Tungsten compounds |
| title | Nickel-tungsten sulfide polyaromatic hydrocarbon hydrogenation nanocatalysts prepared in an ionic liquid |
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