Metallic Conductivity of Mechanochemically Doped Polyaniline

It was shown that the conductivity of polyaniline can be increased significantly as a result of mechanochemical doping with camphorsulfonic acid and secondary doping with m-cresol in comparison with the conductivity of the polymer synthesized by the traditional method. The obtained polymer has a nan...

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Veröffentlicht in:Theoretical and experimental chemistry 2014-09, Vol.50 (4), p.197-203
Hauptverfasser: Posudievsky, O. Yu, Kozarenko, O. A., Kotenko, I. E., Boiko, O. P., Shkavro, A. G., Koshechko, V. G., Pokhodenko, V. D.
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Sprache:eng
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Zusammenfassung:It was shown that the conductivity of polyaniline can be increased significantly as a result of mechanochemical doping with camphorsulfonic acid and secondary doping with m-cresol in comparison with the conductivity of the polymer synthesized by the traditional method. The obtained polymer has a nanofibrillar structure and is characterized by a metallic type of temperature dependence of the conductivity over a wide range of temperatures.
ISSN:0040-5760
1573-935X
DOI:10.1007/s11237-014-9373-7