Novel Luminescent Probe Based on a Terbium(III) Complex for Hemoglobin Determination
We have studied the spectral luminescent properties of Tb(III) and Eu(III) complexes with a number of novel derivatives of oxoquinoline-3-carboxylic acid amides (L 1 –L 5 ). We have observed quenching of the luminescence of 1:1 Tb(III)–L 1–5 complexes by hemoglobin (Hb), which is explained by resona...
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| Veröffentlicht in: | Journal of applied spectroscopy 2014-09, Vol.81 (4), p.672-677 |
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| container_title | Journal of applied spectroscopy |
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| creator | Yegorova, A. V. Leonenko, I. I. Aleksandrova, D. I. Scrypynets, Yu. V. Antonovich, V. P. Ukrainets, I. V. |
| description | We have studied the spectral luminescent properties of Tb(III) and Eu(III) complexes with a number of novel derivatives of oxoquinoline-3-carboxylic acid amides (L
1
–L
5
). We have observed quenching of the luminescence of 1:1 Tb(III)–L
1–5
complexes by hemoglobin (Hb), which is explained by resonance energy transfer of electronic excitation from the donor (Tb(III)–L
1–5
) to the acceptor (Hb). Using the novel luminescent probe Tb(III)–L
1
, we have developed a method for determining Hb in human blood. The calibration Stern–Volmer plot is linear in the Hb concentration range 0.6–36.0 μg/mL, detection limit 0.2 μg/mL (3·10
–9
mol/L). |
| doi_str_mv | 10.1007/s10812-014-9988-4 |
| format | Article |
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1
–L
5
). We have observed quenching of the luminescence of 1:1 Tb(III)–L
1–5
complexes by hemoglobin (Hb), which is explained by resonance energy transfer of electronic excitation from the donor (Tb(III)–L
1–5
) to the acceptor (Hb). Using the novel luminescent probe Tb(III)–L
1
, we have developed a method for determining Hb in human blood. The calibration Stern–Volmer plot is linear in the Hb concentration range 0.6–36.0 μg/mL, detection limit 0.2 μg/mL (3·10
–9
mol/L).</description><identifier>ISSN: 0021-9037</identifier><identifier>EISSN: 1573-8647</identifier><identifier>DOI: 10.1007/s10812-014-9988-4</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Analytical Chemistry ; Atomic/Molecular Structure and Spectra ; Hemoglobin ; Investigations ; Physics ; Physics and Astronomy ; Rare earth metals</subject><ispartof>Journal of applied spectroscopy, 2014-09, Vol.81 (4), p.672-677</ispartof><rights>Springer Science+Business Media New York 2014</rights><rights>COPYRIGHT 2014 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c389t-b5ddd61f5b614a52a94809dcfb21c8b5dd81c1bc2dc1373de7f41d5c7a6051cf3</citedby><cites>FETCH-LOGICAL-c389t-b5ddd61f5b614a52a94809dcfb21c8b5dd81c1bc2dc1373de7f41d5c7a6051cf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10812-014-9988-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10812-014-9988-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Yegorova, A. V.</creatorcontrib><creatorcontrib>Leonenko, I. I.</creatorcontrib><creatorcontrib>Aleksandrova, D. I.</creatorcontrib><creatorcontrib>Scrypynets, Yu. V.</creatorcontrib><creatorcontrib>Antonovich, V. P.</creatorcontrib><creatorcontrib>Ukrainets, I. V.</creatorcontrib><title>Novel Luminescent Probe Based on a Terbium(III) Complex for Hemoglobin Determination</title><title>Journal of applied spectroscopy</title><addtitle>J Appl Spectrosc</addtitle><description>We have studied the spectral luminescent properties of Tb(III) and Eu(III) complexes with a number of novel derivatives of oxoquinoline-3-carboxylic acid amides (L
1
–L
5
). We have observed quenching of the luminescence of 1:1 Tb(III)–L
1–5
complexes by hemoglobin (Hb), which is explained by resonance energy transfer of electronic excitation from the donor (Tb(III)–L
1–5
) to the acceptor (Hb). Using the novel luminescent probe Tb(III)–L
1
, we have developed a method for determining Hb in human blood. The calibration Stern–Volmer plot is linear in the Hb concentration range 0.6–36.0 μg/mL, detection limit 0.2 μg/mL (3·10
–9
mol/L).</description><subject>Analytical Chemistry</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Hemoglobin</subject><subject>Investigations</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Rare earth metals</subject><issn>0021-9037</issn><issn>1573-8647</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp9kU1LAzEQhoMoWD9-gLeAFz2sZvYze6z1a6GoaD2HbDIpKbuJJFvRf--WeimIzGFg5nnmMC8hZ8CugLHqOgLjkCYM8qSuOU_yPTKBosoSXubVPpkwlkJSs6w6JEcxrhhjNU_ZhCye_Cd2dL7urcOo0A30JfgW6Y2MqKl3VNIFhtau-4umaS7pzPcfHX5R4wN9xN4vO99aR29xwDDekIP17oQcGNlFPP3tx-T9_m4xe0zmzw_NbDpPVMbrIWkLrXUJpmhLyGWRyjrnrNbKtCkovtlyUNCqVCvIqkxjZXLQhapkyQpQJjsm59u7S9mhsM74IUjV26jENOMFK2te5SN19Qc1lsbeKu_Q2HG-I1zuCCMz4NewlOsYRfP2usvCllXBxxjQiI9gexm-BTCxSUZskxFjMmKTjNg46daJI-uWGMTKr4MbP_WP9APk9I8f</recordid><startdate>20140901</startdate><enddate>20140901</enddate><creator>Yegorova, A. V.</creator><creator>Leonenko, I. I.</creator><creator>Aleksandrova, D. I.</creator><creator>Scrypynets, Yu. V.</creator><creator>Antonovich, V. P.</creator><creator>Ukrainets, I. V.</creator><general>Springer US</general><general>Springer</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope></search><sort><creationdate>20140901</creationdate><title>Novel Luminescent Probe Based on a Terbium(III) Complex for Hemoglobin Determination</title><author>Yegorova, A. V. ; Leonenko, I. I. ; Aleksandrova, D. I. ; Scrypynets, Yu. V. ; Antonovich, V. P. ; Ukrainets, I. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c389t-b5ddd61f5b614a52a94809dcfb21c8b5dd81c1bc2dc1373de7f41d5c7a6051cf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Analytical Chemistry</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Hemoglobin</topic><topic>Investigations</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Rare earth metals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yegorova, A. V.</creatorcontrib><creatorcontrib>Leonenko, I. I.</creatorcontrib><creatorcontrib>Aleksandrova, D. I.</creatorcontrib><creatorcontrib>Scrypynets, Yu. V.</creatorcontrib><creatorcontrib>Antonovich, V. P.</creatorcontrib><creatorcontrib>Ukrainets, I. V.</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><jtitle>Journal of applied spectroscopy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yegorova, A. V.</au><au>Leonenko, I. I.</au><au>Aleksandrova, D. I.</au><au>Scrypynets, Yu. V.</au><au>Antonovich, V. P.</au><au>Ukrainets, I. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Novel Luminescent Probe Based on a Terbium(III) Complex for Hemoglobin Determination</atitle><jtitle>Journal of applied spectroscopy</jtitle><stitle>J Appl Spectrosc</stitle><date>2014-09-01</date><risdate>2014</risdate><volume>81</volume><issue>4</issue><spage>672</spage><epage>677</epage><pages>672-677</pages><issn>0021-9037</issn><eissn>1573-8647</eissn><abstract>We have studied the spectral luminescent properties of Tb(III) and Eu(III) complexes with a number of novel derivatives of oxoquinoline-3-carboxylic acid amides (L
1
–L
5
). We have observed quenching of the luminescence of 1:1 Tb(III)–L
1–5
complexes by hemoglobin (Hb), which is explained by resonance energy transfer of electronic excitation from the donor (Tb(III)–L
1–5
) to the acceptor (Hb). Using the novel luminescent probe Tb(III)–L
1
, we have developed a method for determining Hb in human blood. The calibration Stern–Volmer plot is linear in the Hb concentration range 0.6–36.0 μg/mL, detection limit 0.2 μg/mL (3·10
–9
mol/L).</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s10812-014-9988-4</doi><tpages>6</tpages></addata></record> |
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| ispartof | Journal of applied spectroscopy, 2014-09, Vol.81 (4), p.672-677 |
| issn | 0021-9037 1573-8647 |
| language | eng |
| recordid | cdi_gale_infotracmisc_A385069874 |
| source | SpringerNature Journals |
| subjects | Analytical Chemistry Atomic/Molecular Structure and Spectra Hemoglobin Investigations Physics Physics and Astronomy Rare earth metals |
| title | Novel Luminescent Probe Based on a Terbium(III) Complex for Hemoglobin Determination |
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