Kinetic evidence for five-coordination in AlOH[.sup.2+] ion

Trivalent aluminum ions are important in natural bodies of water, but the structure of their coordination shell is a complex unsolved problem. In strong acid (pH < 3.0), [Al.sup.III] exists almost entirely as the octahedra[ Al[([H.sub.2]O).sub.6.sup.3+] ion, whereas in basic conditions (pH > 7...

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Veröffentlicht in:	Science (American Association for the Advancement of Science) 2005-06, Vol.308 (5727), p.1450
Hauptverfasser:	Swaddle, Thomas W, Rosenqvist, Jorgen, Yu, Ping, Bylaska, Eric, Phillips, Brian L, Casey, William H
Format:	Artikel
Sprache:	eng
Schlagworte:	Aluminum compounds Analysis
Online-Zugang:	Volltext
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