On the Mechanism of Detonation Combustion of Nanostructured Silicon with a Solid-Phase Oxidant

The physical mechanism of detonation combustion of nanostructured silicon with a solid-phase oxidant at a velocity of the combustion front of 1000–3000 m/s has been proposed. Thermodynamic characteristics of combustion of model solid-phase mixtures “silicon–ammonium perchlorate” with different equiv...

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Veröffentlicht in:Journal of engineering physics and thermophysics 2020-11, Vol.93 (6), p.1439-1448
Hauptverfasser: Krivosheyev, P. N., Mironov, V. N., Penyazkov, O. G., Futko, S. I.
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container_issue 6
container_start_page 1439
container_title Journal of engineering physics and thermophysics
container_volume 93
creator Krivosheyev, P. N.
Mironov, V. N.
Penyazkov, O. G.
Futko, S. I.
description The physical mechanism of detonation combustion of nanostructured silicon with a solid-phase oxidant at a velocity of the combustion front of 1000–3000 m/s has been proposed. Thermodynamic characteristics of combustion of model solid-phase mixtures “silicon–ammonium perchlorate” with different equivalent ratios of their components have been calculated at different pressures. It has been established that a characteristic feature of detonation combustion of nanostructured silicon with a solid-phase oxidant is the stationary velocity of motion of the detonation front with a significant defect (10–15%) with respect to the Chapman–Jouguet detonation velocity. The detonation (supersonic) and subsonic regimes of combustion of nanostructured silicon with a solid-phase oxidant have been determined.
doi_str_mv 10.1007/s10891-020-02249-7
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subjects Analysis
Classical Mechanics
Combustion
Complex Systems
Engineering
Engineering Thermodynamics
Heat and Mass Transfer
Heat and Mass Transfer in Combustion Processes
Industrial Chemistry/Chemical Engineering
Silicon
Thermodynamics
title On the Mechanism of Detonation Combustion of Nanostructured Silicon with a Solid-Phase Oxidant
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