Synthesis of Quaternary-Ammonium-Lignin-Based Ionic Liquids and Comparison of Extraction Behavior of Co with 2-Ethylhexyl Phosphoric Acid Mono-2-Ethylhexyl Ester
The escalating demand for cobalt in modern industry necessitates the recycling or extraction of this resource for sustainable development. Despite the abundance of lignin in nature, its utilization remains low, highlighting the need to enhance its value-added potential. This study focuses on the syn...
Gespeichert in:
| Veröffentlicht in: | Separations 2024-04, Vol.11 (4) |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | 4 |
| container_start_page | |
| container_title | Separations |
| container_volume | 11 |
| creator | Li, Guijiang Xu, Wenze |
| description | The escalating demand for cobalt in modern industry necessitates the recycling or extraction of this resource for sustainable development. Despite the abundance of lignin in nature, its utilization remains low, highlighting the need to enhance its value-added potential. This study focuses on the synthesis of quaternary ammonium lignin (QAL) and 2-ethylhexyl phosphoric acid mono-2-ethylhexyl ester (P507) as ionic liquid (QP–IL) compounds for the extraction of metal ions. A comparison of the extraction behavior of Co(II) and Ni(II) from chloride solution between QP–IL and P507 revealed varying extraction ratios under different conditions, with QP–IL demonstrating a higher cobalt extractability than P507. Furthermore, under identical conditions, QP–IL exhibited superior Co/Ni separation performance (βCo/Ni) compared to P507. Ultimately, QP–IL proved to be more effective than P507 in separating cobalt from mixed solutions. |
| doi_str_mv | 10.3390/separations11040116 |
| format | Article |
| fullrecord | <record><control><sourceid>gale</sourceid><recordid>TN_cdi_gale_infotracacademiconefile_A793552561</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A793552561</galeid><sourcerecordid>A793552561</sourcerecordid><originalsourceid>FETCH-gale_infotracacademiconefile_A7935525613</originalsourceid><addsrcrecordid>eNqVjsFKxDAQhoMouOg-gZe8QNaksa09dktFYQVF7xLadDPSZtZMVreP45vagof1KHOY4eOf__8Zu1JypXUhr8nuTDAR0JNS8kYqlZ2wRZIUubjNdXF6dJ-zJdG7lFLlOstUsmDfL6OPzhIQx44_7020wZswinIY0MN-EBvYevBibci2_GFiDd_Axx5a4sa3vMJhigdCPxvUhxhMM3fha-vMJ2CYcYX8C6LjiaijG3tnD2PPnxzSzmGYDMsGWv6IHsUfRU1Tm0t21pme7PJ3X7DVXf1a3Yut6e0b-A7nyGlaO0CD3nYw8TIvdJomaab0vx9-ADDnbow</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Synthesis of Quaternary-Ammonium-Lignin-Based Ionic Liquids and Comparison of Extraction Behavior of Co with 2-Ethylhexyl Phosphoric Acid Mono-2-Ethylhexyl Ester</title><source>MDPI - Multidisciplinary Digital Publishing Institute</source><source>DOAJ Directory of Open Access Journals</source><source>EZB-FREE-00999 freely available EZB journals</source><creator>Li, Guijiang ; Xu, Wenze</creator><creatorcontrib>Li, Guijiang ; Xu, Wenze</creatorcontrib><description>The escalating demand for cobalt in modern industry necessitates the recycling or extraction of this resource for sustainable development. Despite the abundance of lignin in nature, its utilization remains low, highlighting the need to enhance its value-added potential. This study focuses on the synthesis of quaternary ammonium lignin (QAL) and 2-ethylhexyl phosphoric acid mono-2-ethylhexyl ester (P507) as ionic liquid (QP–IL) compounds for the extraction of metal ions. A comparison of the extraction behavior of Co(II) and Ni(II) from chloride solution between QP–IL and P507 revealed varying extraction ratios under different conditions, with QP–IL demonstrating a higher cobalt extractability than P507. Furthermore, under identical conditions, QP–IL exhibited superior Co/Ni separation performance (βCo/Ni) compared to P507. Ultimately, QP–IL proved to be more effective than P507 in separating cobalt from mixed solutions.</description><identifier>ISSN: 2297-8739</identifier><identifier>EISSN: 2297-8739</identifier><identifier>DOI: 10.3390/separations11040116</identifier><language>eng</language><publisher>MDPI AG</publisher><subject>Cobalt ; Cobalt industry ; Lignin ; Phosphates ; Phosphoric acid</subject><ispartof>Separations, 2024-04, Vol.11 (4)</ispartof><rights>COPYRIGHT 2024 MDPI AG</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,860,27901,27902</link.rule.ids></links><search><creatorcontrib>Li, Guijiang</creatorcontrib><creatorcontrib>Xu, Wenze</creatorcontrib><title>Synthesis of Quaternary-Ammonium-Lignin-Based Ionic Liquids and Comparison of Extraction Behavior of Co with 2-Ethylhexyl Phosphoric Acid Mono-2-Ethylhexyl Ester</title><title>Separations</title><description>The escalating demand for cobalt in modern industry necessitates the recycling or extraction of this resource for sustainable development. Despite the abundance of lignin in nature, its utilization remains low, highlighting the need to enhance its value-added potential. This study focuses on the synthesis of quaternary ammonium lignin (QAL) and 2-ethylhexyl phosphoric acid mono-2-ethylhexyl ester (P507) as ionic liquid (QP–IL) compounds for the extraction of metal ions. A comparison of the extraction behavior of Co(II) and Ni(II) from chloride solution between QP–IL and P507 revealed varying extraction ratios under different conditions, with QP–IL demonstrating a higher cobalt extractability than P507. Furthermore, under identical conditions, QP–IL exhibited superior Co/Ni separation performance (βCo/Ni) compared to P507. Ultimately, QP–IL proved to be more effective than P507 in separating cobalt from mixed solutions.</description><subject>Cobalt</subject><subject>Cobalt industry</subject><subject>Lignin</subject><subject>Phosphates</subject><subject>Phosphoric acid</subject><issn>2297-8739</issn><issn>2297-8739</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqVjsFKxDAQhoMouOg-gZe8QNaksa09dktFYQVF7xLadDPSZtZMVreP45vagof1KHOY4eOf__8Zu1JypXUhr8nuTDAR0JNS8kYqlZ2wRZIUubjNdXF6dJ-zJdG7lFLlOstUsmDfL6OPzhIQx44_7020wZswinIY0MN-EBvYevBibci2_GFiDd_Axx5a4sa3vMJhigdCPxvUhxhMM3fha-vMJ2CYcYX8C6LjiaijG3tnD2PPnxzSzmGYDMsGWv6IHsUfRU1Tm0t21pme7PJ3X7DVXf1a3Yut6e0b-A7nyGlaO0CD3nYw8TIvdJomaab0vx9-ADDnbow</recordid><startdate>20240401</startdate><enddate>20240401</enddate><creator>Li, Guijiang</creator><creator>Xu, Wenze</creator><general>MDPI AG</general><scope/></search><sort><creationdate>20240401</creationdate><title>Synthesis of Quaternary-Ammonium-Lignin-Based Ionic Liquids and Comparison of Extraction Behavior of Co with 2-Ethylhexyl Phosphoric Acid Mono-2-Ethylhexyl Ester</title><author>Li, Guijiang ; Xu, Wenze</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-gale_infotracacademiconefile_A7935525613</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Cobalt</topic><topic>Cobalt industry</topic><topic>Lignin</topic><topic>Phosphates</topic><topic>Phosphoric acid</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Guijiang</creatorcontrib><creatorcontrib>Xu, Wenze</creatorcontrib><jtitle>Separations</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Guijiang</au><au>Xu, Wenze</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of Quaternary-Ammonium-Lignin-Based Ionic Liquids and Comparison of Extraction Behavior of Co with 2-Ethylhexyl Phosphoric Acid Mono-2-Ethylhexyl Ester</atitle><jtitle>Separations</jtitle><date>2024-04-01</date><risdate>2024</risdate><volume>11</volume><issue>4</issue><issn>2297-8739</issn><eissn>2297-8739</eissn><abstract>The escalating demand for cobalt in modern industry necessitates the recycling or extraction of this resource for sustainable development. Despite the abundance of lignin in nature, its utilization remains low, highlighting the need to enhance its value-added potential. This study focuses on the synthesis of quaternary ammonium lignin (QAL) and 2-ethylhexyl phosphoric acid mono-2-ethylhexyl ester (P507) as ionic liquid (QP–IL) compounds for the extraction of metal ions. A comparison of the extraction behavior of Co(II) and Ni(II) from chloride solution between QP–IL and P507 revealed varying extraction ratios under different conditions, with QP–IL demonstrating a higher cobalt extractability than P507. Furthermore, under identical conditions, QP–IL exhibited superior Co/Ni separation performance (βCo/Ni) compared to P507. Ultimately, QP–IL proved to be more effective than P507 in separating cobalt from mixed solutions.</abstract><pub>MDPI AG</pub><doi>10.3390/separations11040116</doi></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2297-8739 |
| ispartof | Separations, 2024-04, Vol.11 (4) |
| issn | 2297-8739 2297-8739 |
| language | eng |
| recordid | cdi_gale_infotracacademiconefile_A793552561 |
| source | MDPI - Multidisciplinary Digital Publishing Institute; DOAJ Directory of Open Access Journals; EZB-FREE-00999 freely available EZB journals |
| subjects | Cobalt Cobalt industry Lignin Phosphates Phosphoric acid |
| title | Synthesis of Quaternary-Ammonium-Lignin-Based Ionic Liquids and Comparison of Extraction Behavior of Co with 2-Ethylhexyl Phosphoric Acid Mono-2-Ethylhexyl Ester |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-09T11%3A10%3A31IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20of%20Quaternary-Ammonium-Lignin-Based%20Ionic%20Liquids%20and%20Comparison%20of%20Extraction%20Behavior%20of%20Co%20with%202-Ethylhexyl%20Phosphoric%20Acid%20Mono-2-Ethylhexyl%20Ester&rft.jtitle=Separations&rft.au=Li,%20Guijiang&rft.date=2024-04-01&rft.volume=11&rft.issue=4&rft.issn=2297-8739&rft.eissn=2297-8739&rft_id=info:doi/10.3390/separations11040116&rft_dat=%3Cgale%3EA793552561%3C/gale%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rft_galeid=A793552561&rfr_iscdi=true |