A 3D Multilevel Heterostructure Containing 2D Vertically Aligned MoS[sub.2] Nanosheets and 1D Sandwich C-MoS[sub.2]-C Nanotubes to Enhance the Storage of Li[sup.+] Ions

To overcome the disadvantages of the MoS[sub.2] anode for LIBs in terms of low intrinsic conductivity, poor mechanical stability, and adverse reaction with electrolytes, a 3D multilevel heterostructure (VANS-MoS[sub.2]-CNTs) has been successfully prepared by a simple hydrothermal method followed by thermal treatment. VANS-MoS[sub.2]-CNTs are made up of 2D vertically aligned MoS[sub.2] nanosheets (VANS) and 1D sandwich C-MoS[sub.2]-C nanotubes (CNTs). The sandwich-like nanotube is the core part, which is made up of the MoS[sub.2] nanotube covered by carbon layers on both side surfaces. Due to the special heterostructure, VANS-MoS[sub.2]-CNTs have good conductivity, high structured stability, and excellent Li[sup.+]/electron transport, resulting in high discharge capacity (1587 mAh/g at a current density of 0.1 A/g), excellent rate capacity (1330 and 730 mAh/g at current densities of 0.1 and 2 A/g, respectively), and good cyclic stability (1270 mAh/g at 0.1 A/g after 100 cycles).