Phosphine–Stibine and Phosphine–Stiborane Iperi/I-Substituted Donor–Acceptor Complexes
Two novel Sb(III) and Sb(V) peri-substituted acenaphthene phosphorus−antimony compounds were prepared. The Sb(III) compound, 1, was prepared via reacting the organolithium precursor with dichloro(p-tolyl)Stibine, and 2 was prepared by the chlorination of 1. Both 1 and 2 were characterized by multinu...
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| Veröffentlicht in: | MolBank 2023-05, Vol.2023 (2) |
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| creator | Bergsch, Jan U Slawin, Alexandra M. Z Kilian, Petr Chalmers, Brian A |
| description | Two novel Sb(III) and Sb(V) peri-substituted acenaphthene phosphorus−antimony compounds were prepared. The Sb(III) compound, 1, was prepared via reacting the organolithium precursor with dichloro(p-tolyl)Stibine, and 2 was prepared by the chlorination of 1. Both 1 and 2 were characterized by multinuclear ([sup.1] H, [sup.13] C and [sup.31] P) NMR spectroscopy, and their molecular structures resolved by single-crystal X-ray diffraction. Both compounds show a dative P−Sb interaction with the antimony being the acceptor group in both cases owing to its Lewis acidity. |
| doi_str_mv | 10.3390/M1653 |
| format | Article |
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Both compounds show a dative P−Sb interaction with the antimony being the acceptor group in both cases owing to its Lewis acidity.</description><subject>Analysis</subject><subject>Chemical synthesis</subject><subject>Diffraction</subject><subject>Electron donor-acceptor complexes</subject><subject>Identification and classification</subject><subject>Methods</subject><subject>Nuclear magnetic resonance spectroscopy</subject><subject>Structure</subject><subject>X-rays</subject><issn>1422-8599</issn><issn>1422-8599</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNpjYOA1NNAzNrY00Pc1NDM1ZmLgNDQxMtK1MLW0ZEFiczBwFRdnGRiYGBoZG3AyxARk5BcXZGTmpT5qmBxckpkEZCkk5qUooIvnFyUCZTwLUosy9T11g0uTiksyS0pLUlMUXPLz8ouAqhyTk1MLSvKLFJzzcwtyUitSi3kYWNMSc4pTeaE0N4Oem2uIs4duemJOanxmXlp-SVFiMhCmpOZmJufnpaZlAsUdzU0tjC3NDIzMjUnWAABIoFMp</recordid><startdate>20230501</startdate><enddate>20230501</enddate><creator>Bergsch, Jan U</creator><creator>Slawin, Alexandra M. 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Z ; Kilian, Petr ; Chalmers, Brian A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-gale_infotracacademiconefile_A7583960273</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Analysis</topic><topic>Chemical synthesis</topic><topic>Diffraction</topic><topic>Electron donor-acceptor complexes</topic><topic>Identification and classification</topic><topic>Methods</topic><topic>Nuclear magnetic resonance spectroscopy</topic><topic>Structure</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bergsch, Jan U</creatorcontrib><creatorcontrib>Slawin, Alexandra M. Z</creatorcontrib><creatorcontrib>Kilian, Petr</creatorcontrib><creatorcontrib>Chalmers, Brian A</creatorcontrib><jtitle>MolBank</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bergsch, Jan U</au><au>Slawin, Alexandra M. Z</au><au>Kilian, Petr</au><au>Chalmers, Brian A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Phosphine–Stibine and Phosphine–Stiborane Iperi/I-Substituted Donor–Acceptor Complexes</atitle><jtitle>MolBank</jtitle><date>2023-05-01</date><risdate>2023</risdate><volume>2023</volume><issue>2</issue><issn>1422-8599</issn><eissn>1422-8599</eissn><abstract>Two novel Sb(III) and Sb(V) peri-substituted acenaphthene phosphorus−antimony compounds were prepared. The Sb(III) compound, 1, was prepared via reacting the organolithium precursor with dichloro(p-tolyl)Stibine, and 2 was prepared by the chlorination of 1. Both 1 and 2 were characterized by multinuclear ([sup.1] H, [sup.13] C and [sup.31] P) NMR spectroscopy, and their molecular structures resolved by single-crystal X-ray diffraction. Both compounds show a dative P−Sb interaction with the antimony being the acceptor group in both cases owing to its Lewis acidity.</abstract><pub>MDPI AG</pub><doi>10.3390/M1653</doi></addata></record> |
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| source | MDPI - Multidisciplinary Digital Publishing Institute; DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals |
| subjects | Analysis Chemical synthesis Diffraction Electron donor-acceptor complexes Identification and classification Methods Nuclear magnetic resonance spectroscopy Structure X-rays |
| title | Phosphine–Stibine and Phosphine–Stiborane Iperi/I-Substituted Donor–Acceptor Complexes |
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