Photodimerization of prop-2-en-1-one in the Crystalline Solid State

(E)-3-(2,6-difluorophenyl)-1-(4-methoxyphenyl)prop-2-en-1-one (1) was synthesized and characterized by [sup.1] H and [sup.13] C NMR, mass spectrometry, and single-crystal X-ray diffraction. Photolysis (λ[sub.irr] = 300 nm) of chalcone 1 in the crystalline solid state resulted in the stereospecific f...

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Veröffentlicht in:	MolBank 2023-03, Vol.2023 (2)
Hauptverfasser:	de Paula, Adriano Farias, Cesarin-Sobrinho, Dari, Netto-Ferreira, José Carlos
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Sprache:	eng
Schlagworte:	Chemical synthesis Heterocyclic compounds Identification and classification Mass spectrometry Methods Nuclear magnetic resonance spectroscopy Structure
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creator	de Paula, Adriano Farias Cesarin-Sobrinho, Dari Netto-Ferreira, José Carlos
description	(E)-3-(2,6-difluorophenyl)-1-(4-methoxyphenyl)prop-2-en-1-one (1) was synthesized and characterized by [sup.1] H and [sup.13] C NMR, mass spectrometry, and single-crystal X-ray diffraction. Photolysis (λ[sub.irr] = 300 nm) of chalcone 1 in the crystalline solid state resulted in the stereospecific formation of the syn-head-to-head photodimer (β-truxinic).
doi_str_mv	10.3390/M1609
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subjects	Chemical synthesis Heterocyclic compounds Identification and classification Mass spectrometry Methods Nuclear magnetic resonance spectroscopy Structure
title	Photodimerization of prop-2-en-1-one in the Crystalline Solid State
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