Lead-Free FACsSnI[sub.3] Based Perovskite Solar Cell: Designing Hole and Electron Transport Layer

In recent years, lead-based perovskites solar cells have demonstrated excellent power-conversion efficiency. Despite their remarkable progress, the commercialization of lead-based perovskites is hampered by lead toxicity concerns. The recently discovered non-toxic FACsSnI[sub.3] perovskite has the potential to replace lead-based perovskites in solar cell applications. Since the perovskite material FACsSnI[sub.3] (FA[sub.0.85] Cs[sub.0.15] SnI[sub.3] ) is relatively new, there is a lack of information, particularly regarding the design features required for electron and hole-transport layers for efficient photovoltaic responses. The important variables, such as electron affinity, energy band gap, film thickness, and doping density of both electron and hole-transport layers, were simulated and modeled separately and iteratively in this study to achieve the most efficient photovoltaic response. Finally, the absorber layer thickness of FACsSnI[sub.3] perovskite is tuned to achieve a maximum power-conversion efficiency of slightly more than 24%. We hope that the findings of this study will serve as a strong guideline for future research and the design of lead-free perovskite solar cells for efficient photovoltaic responses.