Synthesis and Evaluation of LaBaCo[sub.2−x]MoIx/IO[sub.5+δ] Cathode for Intermediate-Temperature Solid Oxide Fuel Cells
LaBaCo[sub.2−x] MoxO[sub.5+δ] (LBCMx, x = 0–0.08) cathodes synthesized by a sol-gel method were evaluated for intermediate-temperature solid oxide fuel cells. The limit of the solid solubility of Mo in LBCMx was lower than 0.08. As the content of Mo increased gradually from 0 to 0.06, the thermal ex...
Gespeichert in:
| Veröffentlicht in: | Materials 2022-08, Vol.15 (17) |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | 17 |
| container_start_page | |
| container_title | Materials |
| container_volume | 15 |
| creator | He, Shoucheng Zhang, Lanqing Cai, Jiantao Wu, Xingyu Sun, Hanxi Du, Tao |
| description | LaBaCo[sub.2−x] MoxO[sub.5+δ] (LBCMx, x = 0–0.08) cathodes synthesized by a sol-gel method were evaluated for intermediate-temperature solid oxide fuel cells. The limit of the solid solubility of Mo in LBCMx was lower than 0.08. As the content of Mo increased gradually from 0 to 0.06, the thermal expansion coefficient decreased from 20.87 × 10[sup.−6] K[sup.−1] to 18.47 × 10[sup.−6] K[sup.−1] . The introduction of Mo could increase the conductivity of LBCMx, which varied from 464 S cm[sup.−1] to 621 S cm[sup.−1] at 800 °C. The polarization resistance of the optimal cathode LBCM0.04 in air at 800 °C was 0.036 Ω cm[sup.2] , reduced by a factor of 1.67 when compared with the undoped Mo cathode. The corresponding maximum power density of a single cell based on a YSZ electrolyte improved from 165 mW cm[sup.−2] to 248 mW cm[sup.−2] at 800 °C. |
| doi_str_mv | 10.3390/ma15175858 |
| format | Article |
| fullrecord | <record><control><sourceid>gale</sourceid><recordid>TN_cdi_gale_infotracacademiconefile_A745743115</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A745743115</galeid><sourcerecordid>A745743115</sourcerecordid><originalsourceid>FETCH-gale_infotracacademiconefile_A7457431153</originalsourceid><addsrcrecordid>eNqVi0FOwzAURC0EEhXthhN4j5LGdUziJUStiATqot2hCn3qb2rk2Ch2UOAErHsWzsEhOAkRYtEtM4sZPc0Qcs6ylHOZTRtgghWiFOURGTEpLxMm8_z4oJ-SSQjP2SDOWTmTI_K-enNxh8EECk7R-SvYDqLxjnpNb-EaKn8fusd09v2x7zd3vu6n9fKXiIuvzw2tIO68Qqp9S2sXsW1QGYiYrLF5wRZi1yJdeWsUXfZmGC46tLRCa8OYnGiwASd_eUbSxXxd3SRPYPHBOO1jC9vBChuz9Q61GfhVkYsi54wJ_u_DD2xcXRc</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Synthesis and Evaluation of LaBaCo[sub.2−x]MoIx/IO[sub.5+δ] Cathode for Intermediate-Temperature Solid Oxide Fuel Cells</title><source>PubMed Central Open Access</source><source>MDPI - Multidisciplinary Digital Publishing Institute</source><source>EZB-FREE-00999 freely available EZB journals</source><source>PubMed Central</source><source>Free Full-Text Journals in Chemistry</source><creator>He, Shoucheng ; Zhang, Lanqing ; Cai, Jiantao ; Wu, Xingyu ; Sun, Hanxi ; Du, Tao</creator><creatorcontrib>He, Shoucheng ; Zhang, Lanqing ; Cai, Jiantao ; Wu, Xingyu ; Sun, Hanxi ; Du, Tao</creatorcontrib><description>LaBaCo[sub.2−x] MoxO[sub.5+δ] (LBCMx, x = 0–0.08) cathodes synthesized by a sol-gel method were evaluated for intermediate-temperature solid oxide fuel cells. The limit of the solid solubility of Mo in LBCMx was lower than 0.08. As the content of Mo increased gradually from 0 to 0.06, the thermal expansion coefficient decreased from 20.87 × 10[sup.−6] K[sup.−1] to 18.47 × 10[sup.−6] K[sup.−1] . The introduction of Mo could increase the conductivity of LBCMx, which varied from 464 S cm[sup.−1] to 621 S cm[sup.−1] at 800 °C. The polarization resistance of the optimal cathode LBCM0.04 in air at 800 °C was 0.036 Ω cm[sup.2] , reduced by a factor of 1.67 when compared with the undoped Mo cathode. The corresponding maximum power density of a single cell based on a YSZ electrolyte improved from 165 mW cm[sup.−2] to 248 mW cm[sup.−2] at 800 °C.</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>DOI: 10.3390/ma15175858</identifier><language>eng</language><publisher>MDPI AG</publisher><subject>Barium compounds ; Cathodes ; Chemical properties ; Chemical synthesis ; Equipment and supplies ; Fuel cells ; Lanthanum ; Materials ; Methods ; Molybdenum compounds ; Production processes</subject><ispartof>Materials, 2022-08, Vol.15 (17)</ispartof><rights>COPYRIGHT 2022 MDPI AG</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>He, Shoucheng</creatorcontrib><creatorcontrib>Zhang, Lanqing</creatorcontrib><creatorcontrib>Cai, Jiantao</creatorcontrib><creatorcontrib>Wu, Xingyu</creatorcontrib><creatorcontrib>Sun, Hanxi</creatorcontrib><creatorcontrib>Du, Tao</creatorcontrib><title>Synthesis and Evaluation of LaBaCo[sub.2−x]MoIx/IO[sub.5+δ] Cathode for Intermediate-Temperature Solid Oxide Fuel Cells</title><title>Materials</title><description>LaBaCo[sub.2−x] MoxO[sub.5+δ] (LBCMx, x = 0–0.08) cathodes synthesized by a sol-gel method were evaluated for intermediate-temperature solid oxide fuel cells. The limit of the solid solubility of Mo in LBCMx was lower than 0.08. As the content of Mo increased gradually from 0 to 0.06, the thermal expansion coefficient decreased from 20.87 × 10[sup.−6] K[sup.−1] to 18.47 × 10[sup.−6] K[sup.−1] . The introduction of Mo could increase the conductivity of LBCMx, which varied from 464 S cm[sup.−1] to 621 S cm[sup.−1] at 800 °C. The polarization resistance of the optimal cathode LBCM0.04 in air at 800 °C was 0.036 Ω cm[sup.2] , reduced by a factor of 1.67 when compared with the undoped Mo cathode. The corresponding maximum power density of a single cell based on a YSZ electrolyte improved from 165 mW cm[sup.−2] to 248 mW cm[sup.−2] at 800 °C.</description><subject>Barium compounds</subject><subject>Cathodes</subject><subject>Chemical properties</subject><subject>Chemical synthesis</subject><subject>Equipment and supplies</subject><subject>Fuel cells</subject><subject>Lanthanum</subject><subject>Materials</subject><subject>Methods</subject><subject>Molybdenum compounds</subject><subject>Production processes</subject><issn>1996-1944</issn><issn>1996-1944</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqVi0FOwzAURC0EEhXthhN4j5LGdUziJUStiATqot2hCn3qb2rk2Ch2UOAErHsWzsEhOAkRYtEtM4sZPc0Qcs6ylHOZTRtgghWiFOURGTEpLxMm8_z4oJ-SSQjP2SDOWTmTI_K-enNxh8EECk7R-SvYDqLxjnpNb-EaKn8fusd09v2x7zd3vu6n9fKXiIuvzw2tIO68Qqp9S2sXsW1QGYiYrLF5wRZi1yJdeWsUXfZmGC46tLRCa8OYnGiwASd_eUbSxXxd3SRPYPHBOO1jC9vBChuz9Q61GfhVkYsi54wJ_u_DD2xcXRc</recordid><startdate>20220801</startdate><enddate>20220801</enddate><creator>He, Shoucheng</creator><creator>Zhang, Lanqing</creator><creator>Cai, Jiantao</creator><creator>Wu, Xingyu</creator><creator>Sun, Hanxi</creator><creator>Du, Tao</creator><general>MDPI AG</general><scope/></search><sort><creationdate>20220801</creationdate><title>Synthesis and Evaluation of LaBaCo[sub.2−x]MoIx/IO[sub.5+δ] Cathode for Intermediate-Temperature Solid Oxide Fuel Cells</title><author>He, Shoucheng ; Zhang, Lanqing ; Cai, Jiantao ; Wu, Xingyu ; Sun, Hanxi ; Du, Tao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-gale_infotracacademiconefile_A7457431153</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Barium compounds</topic><topic>Cathodes</topic><topic>Chemical properties</topic><topic>Chemical synthesis</topic><topic>Equipment and supplies</topic><topic>Fuel cells</topic><topic>Lanthanum</topic><topic>Materials</topic><topic>Methods</topic><topic>Molybdenum compounds</topic><topic>Production processes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>He, Shoucheng</creatorcontrib><creatorcontrib>Zhang, Lanqing</creatorcontrib><creatorcontrib>Cai, Jiantao</creatorcontrib><creatorcontrib>Wu, Xingyu</creatorcontrib><creatorcontrib>Sun, Hanxi</creatorcontrib><creatorcontrib>Du, Tao</creatorcontrib><jtitle>Materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>He, Shoucheng</au><au>Zhang, Lanqing</au><au>Cai, Jiantao</au><au>Wu, Xingyu</au><au>Sun, Hanxi</au><au>Du, Tao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Evaluation of LaBaCo[sub.2−x]MoIx/IO[sub.5+δ] Cathode for Intermediate-Temperature Solid Oxide Fuel Cells</atitle><jtitle>Materials</jtitle><date>2022-08-01</date><risdate>2022</risdate><volume>15</volume><issue>17</issue><issn>1996-1944</issn><eissn>1996-1944</eissn><abstract>LaBaCo[sub.2−x] MoxO[sub.5+δ] (LBCMx, x = 0–0.08) cathodes synthesized by a sol-gel method were evaluated for intermediate-temperature solid oxide fuel cells. The limit of the solid solubility of Mo in LBCMx was lower than 0.08. As the content of Mo increased gradually from 0 to 0.06, the thermal expansion coefficient decreased from 20.87 × 10[sup.−6] K[sup.−1] to 18.47 × 10[sup.−6] K[sup.−1] . The introduction of Mo could increase the conductivity of LBCMx, which varied from 464 S cm[sup.−1] to 621 S cm[sup.−1] at 800 °C. The polarization resistance of the optimal cathode LBCM0.04 in air at 800 °C was 0.036 Ω cm[sup.2] , reduced by a factor of 1.67 when compared with the undoped Mo cathode. The corresponding maximum power density of a single cell based on a YSZ electrolyte improved from 165 mW cm[sup.−2] to 248 mW cm[sup.−2] at 800 °C.</abstract><pub>MDPI AG</pub><doi>10.3390/ma15175858</doi></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1996-1944 |
| ispartof | Materials, 2022-08, Vol.15 (17) |
| issn | 1996-1944 1996-1944 |
| language | eng |
| recordid | cdi_gale_infotracacademiconefile_A745743115 |
| source | PubMed Central Open Access; MDPI - Multidisciplinary Digital Publishing Institute; EZB-FREE-00999 freely available EZB journals; PubMed Central; Free Full-Text Journals in Chemistry |
| subjects | Barium compounds Cathodes Chemical properties Chemical synthesis Equipment and supplies Fuel cells Lanthanum Materials Methods Molybdenum compounds Production processes |
| title | Synthesis and Evaluation of LaBaCo[sub.2−x]MoIx/IO[sub.5+δ] Cathode for Intermediate-Temperature Solid Oxide Fuel Cells |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-22T06%3A33%3A52IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20Evaluation%20of%20LaBaCo%5Bsub.2%E2%88%92x%5DMoIx/IO%5Bsub.5+%CE%B4%5D%20Cathode%20for%20Intermediate-Temperature%20Solid%20Oxide%20Fuel%20Cells&rft.jtitle=Materials&rft.au=He,%20Shoucheng&rft.date=2022-08-01&rft.volume=15&rft.issue=17&rft.issn=1996-1944&rft.eissn=1996-1944&rft_id=info:doi/10.3390/ma15175858&rft_dat=%3Cgale%3EA745743115%3C/gale%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rft_galeid=A745743115&rfr_iscdi=true |