GLOBAL ANALYSIS OF 24 ROVIBRATIONAL BANDS OF THE OCTAD OF THE [sup.76]Ge[H.sub.4] MOLECULE

GLOBAL ANALYSIS OF 24 ROVIBRATIONAL BANDS OF THE OCTAD OF THE [sup.76]Ge[H.sub.4] MOLECULE

A global fitting method has been developed for spherical top molecules. The octad of the GeH4 molecule comprising 24 interacting states has been investigated. By solving the inverse spectroscopic problem, positions of the band centers and rotational and resonant parameters are calculated. A total of...

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Veröffentlicht in:Russian physics journal 2021-03, Vol.63 (11), p.1937
Hauptverfasser: Raspopova, N.I, Gromova, O.V, Bekhtereva, E.S, Koshelev, M.A, Sennikov, P.G
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container_issue 11
container_start_page 1937
container_title Russian physics journal
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creator Raspopova, N.I
Gromova, O.V
Bekhtereva, E.S
Koshelev, M.A
Sennikov, P.G
description A global fitting method has been developed for spherical top molecules. The octad of the GeH4 molecule comprising 24 interacting states has been investigated. By solving the inverse spectroscopic problem, positions of the band centers and rotational and resonant parameters are calculated. A total of 70 variable parameters allow 1184 initial experimental rovibrational energies to be reproduced with a standard deviation of 1.2 x [10.sup.-3] [cm.sup.-1]. Keywords: Germane molecule, global analysis, spectroscopic parameters.
doi_str_mv 10.1007/s11182-021-02254-0
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title GLOBAL ANALYSIS OF 24 ROVIBRATIONAL BANDS OF THE OCTAD OF THE [sup.76]Ge[H.sub.4] MOLECULE
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