Insights into the Behaviors of the Catalytic Combustion of Propane over Spinel Catalysts
The behaviors of C 3 H 8 catalytic combustion were investigated over spinel AB 2 O 4 (AB 2 O 4 prepared by co-precipitation method) with two transition metal (A and B are both transition metal elements) and single transition metal (A is transition metal element). Results showed that the spinel AFe 2...
Gespeichert in:
| Veröffentlicht in: | Catalysis letters 2020-12, Vol.150 (12), p.3617-3625 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 3625 |
|---|---|
| container_issue | 12 |
| container_start_page | 3617 |
| container_title | Catalysis letters |
| container_volume | 150 |
| creator | Gao, Yang Wang, Sheng Lv, Lirong Li, Deyi Yue, Xu Wang, Shudong |
| description | The behaviors of C
3
H
8
catalytic combustion were investigated over spinel AB
2
O
4
(AB
2
O
4
prepared by co-precipitation method) with two transition metal (A and B are both transition metal elements) and single transition metal (A is transition metal element). Results showed that the spinel AFe
2
O
4
(A = Ni, Cu) owned superior catalytic activities than the spinel AAl
2
O
4
(A = Ni, Cu). In combination with XRD, SEM, Raman, XPS and H
2
-TPR, it could be deduced that higher activity was dependent on abundant surface oxygen vacancy and adsorbed oxygen species. The oxygen activation was enhanced by the doping of another transition metal in B sites of AB
2
O
4
. As a result, the catalytic performance was promoted. Among as-prepared catalysts, NiFe
2
O
4
owned more superior activity and hydrothermal stability for C
3
H
8
combustion than noble metal catalyst. It is expected to be applicable in the removal of VOCs.
Graphic Abstract
Due to the B-site transition metal doping, the surface oxygen activation behavior of the spinel catalyst can be modulated, which makes AFe
2
O
4
have a higher propane catalytic activity than AAl
2
O
4
. |
| doi_str_mv | 10.1007/s10562-020-03239-3 |
| format | Article |
| fullrecord | <record><control><sourceid>gale_cross</sourceid><recordid>TN_cdi_gale_infotracacademiconefile_A638924265</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A638924265</galeid><sourcerecordid>A638924265</sourcerecordid><originalsourceid>FETCH-LOGICAL-c401t-5fff0f8650737cffc5b13a0564dd0ef5ba7b230d4d2f5956386470e4f20066623</originalsourceid><addsrcrecordid>eNp9kE1PwyAYgBujiXP6Bzz16qH6AqWsx9n4sWSJxmmyG6EtbCwdLMAW9-9l6y67GA6Ql-ch4UmSewSPCIA9eQS0wBlgyIBgUmbkIhkgynA2YuX8Mp4BoYwwPL9ObrxfAUDJUDlI5hPj9WIZfKpNsGlYyvRZLsVOW-dTq46DSgTR7YNu0squ660P2prD3aezG2FkanfSpbONNrI7sT742-RKic7Lu9M-TH5eX76r92z68TapxtOsyQGFjCqlQI0KCoywRqmG1oiI-Jm8bUEqWgtWYwJt3mJFS1qQUZEzkLnCAEVRYDJMHvt3F6KTXBtlgxNNXK1c68YaqXScj6NY4hwXNAoPZ0JkgvwNC7H1nk9mX-cs7tnGWe-dVHzj9Fq4PUfAD-F5H57H8PwYnpMokV7yETYL6fjKbp2JEf6z_gD89YVu</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Insights into the Behaviors of the Catalytic Combustion of Propane over Spinel Catalysts</title><source>SpringerLink Journals</source><creator>Gao, Yang ; Wang, Sheng ; Lv, Lirong ; Li, Deyi ; Yue, Xu ; Wang, Shudong</creator><creatorcontrib>Gao, Yang ; Wang, Sheng ; Lv, Lirong ; Li, Deyi ; Yue, Xu ; Wang, Shudong</creatorcontrib><description>The behaviors of C
3
H
8
catalytic combustion were investigated over spinel AB
2
O
4
(AB
2
O
4
prepared by co-precipitation method) with two transition metal (A and B are both transition metal elements) and single transition metal (A is transition metal element). Results showed that the spinel AFe
2
O
4
(A = Ni, Cu) owned superior catalytic activities than the spinel AAl
2
O
4
(A = Ni, Cu). In combination with XRD, SEM, Raman, XPS and H
2
-TPR, it could be deduced that higher activity was dependent on abundant surface oxygen vacancy and adsorbed oxygen species. The oxygen activation was enhanced by the doping of another transition metal in B sites of AB
2
O
4
. As a result, the catalytic performance was promoted. Among as-prepared catalysts, NiFe
2
O
4
owned more superior activity and hydrothermal stability for C
3
H
8
combustion than noble metal catalyst. It is expected to be applicable in the removal of VOCs.
Graphic Abstract
Due to the B-site transition metal doping, the surface oxygen activation behavior of the spinel catalyst can be modulated, which makes AFe
2
O
4
have a higher propane catalytic activity than AAl
2
O
4
.</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-020-03239-3</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Catalysis ; Catalysts ; Chemistry ; Chemistry and Materials Science ; Combustion ; Industrial Chemistry/Chemical Engineering ; Organometallic Chemistry ; Physical Chemistry ; Propane ; Spinel group ; Transition metal compounds</subject><ispartof>Catalysis letters, 2020-12, Vol.150 (12), p.3617-3625</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2020</rights><rights>COPYRIGHT 2020 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c401t-5fff0f8650737cffc5b13a0564dd0ef5ba7b230d4d2f5956386470e4f20066623</citedby><cites>FETCH-LOGICAL-c401t-5fff0f8650737cffc5b13a0564dd0ef5ba7b230d4d2f5956386470e4f20066623</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10562-020-03239-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10562-020-03239-3$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Gao, Yang</creatorcontrib><creatorcontrib>Wang, Sheng</creatorcontrib><creatorcontrib>Lv, Lirong</creatorcontrib><creatorcontrib>Li, Deyi</creatorcontrib><creatorcontrib>Yue, Xu</creatorcontrib><creatorcontrib>Wang, Shudong</creatorcontrib><title>Insights into the Behaviors of the Catalytic Combustion of Propane over Spinel Catalysts</title><title>Catalysis letters</title><addtitle>Catal Lett</addtitle><description>The behaviors of C
3
H
8
catalytic combustion were investigated over spinel AB
2
O
4
(AB
2
O
4
prepared by co-precipitation method) with two transition metal (A and B are both transition metal elements) and single transition metal (A is transition metal element). Results showed that the spinel AFe
2
O
4
(A = Ni, Cu) owned superior catalytic activities than the spinel AAl
2
O
4
(A = Ni, Cu). In combination with XRD, SEM, Raman, XPS and H
2
-TPR, it could be deduced that higher activity was dependent on abundant surface oxygen vacancy and adsorbed oxygen species. The oxygen activation was enhanced by the doping of another transition metal in B sites of AB
2
O
4
. As a result, the catalytic performance was promoted. Among as-prepared catalysts, NiFe
2
O
4
owned more superior activity and hydrothermal stability for C
3
H
8
combustion than noble metal catalyst. It is expected to be applicable in the removal of VOCs.
Graphic Abstract
Due to the B-site transition metal doping, the surface oxygen activation behavior of the spinel catalyst can be modulated, which makes AFe
2
O
4
have a higher propane catalytic activity than AAl
2
O
4
.</description><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Combustion</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Organometallic Chemistry</subject><subject>Physical Chemistry</subject><subject>Propane</subject><subject>Spinel group</subject><subject>Transition metal compounds</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kE1PwyAYgBujiXP6Bzz16qH6AqWsx9n4sWSJxmmyG6EtbCwdLMAW9-9l6y67GA6Ql-ch4UmSewSPCIA9eQS0wBlgyIBgUmbkIhkgynA2YuX8Mp4BoYwwPL9ObrxfAUDJUDlI5hPj9WIZfKpNsGlYyvRZLsVOW-dTq46DSgTR7YNu0squ660P2prD3aezG2FkanfSpbONNrI7sT742-RKic7Lu9M-TH5eX76r92z68TapxtOsyQGFjCqlQI0KCoywRqmG1oiI-Jm8bUEqWgtWYwJt3mJFS1qQUZEzkLnCAEVRYDJMHvt3F6KTXBtlgxNNXK1c68YaqXScj6NY4hwXNAoPZ0JkgvwNC7H1nk9mX-cs7tnGWe-dVHzj9Fq4PUfAD-F5H57H8PwYnpMokV7yETYL6fjKbp2JEf6z_gD89YVu</recordid><startdate>20201201</startdate><enddate>20201201</enddate><creator>Gao, Yang</creator><creator>Wang, Sheng</creator><creator>Lv, Lirong</creator><creator>Li, Deyi</creator><creator>Yue, Xu</creator><creator>Wang, Shudong</creator><general>Springer US</general><general>Springer</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope></search><sort><creationdate>20201201</creationdate><title>Insights into the Behaviors of the Catalytic Combustion of Propane over Spinel Catalysts</title><author>Gao, Yang ; Wang, Sheng ; Lv, Lirong ; Li, Deyi ; Yue, Xu ; Wang, Shudong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c401t-5fff0f8650737cffc5b13a0564dd0ef5ba7b230d4d2f5956386470e4f20066623</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Combustion</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Organometallic Chemistry</topic><topic>Physical Chemistry</topic><topic>Propane</topic><topic>Spinel group</topic><topic>Transition metal compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gao, Yang</creatorcontrib><creatorcontrib>Wang, Sheng</creatorcontrib><creatorcontrib>Lv, Lirong</creatorcontrib><creatorcontrib>Li, Deyi</creatorcontrib><creatorcontrib>Yue, Xu</creatorcontrib><creatorcontrib>Wang, Shudong</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gao, Yang</au><au>Wang, Sheng</au><au>Lv, Lirong</au><au>Li, Deyi</au><au>Yue, Xu</au><au>Wang, Shudong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Insights into the Behaviors of the Catalytic Combustion of Propane over Spinel Catalysts</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2020-12-01</date><risdate>2020</risdate><volume>150</volume><issue>12</issue><spage>3617</spage><epage>3625</epage><pages>3617-3625</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>The behaviors of C
3
H
8
catalytic combustion were investigated over spinel AB
2
O
4
(AB
2
O
4
prepared by co-precipitation method) with two transition metal (A and B are both transition metal elements) and single transition metal (A is transition metal element). Results showed that the spinel AFe
2
O
4
(A = Ni, Cu) owned superior catalytic activities than the spinel AAl
2
O
4
(A = Ni, Cu). In combination with XRD, SEM, Raman, XPS and H
2
-TPR, it could be deduced that higher activity was dependent on abundant surface oxygen vacancy and adsorbed oxygen species. The oxygen activation was enhanced by the doping of another transition metal in B sites of AB
2
O
4
. As a result, the catalytic performance was promoted. Among as-prepared catalysts, NiFe
2
O
4
owned more superior activity and hydrothermal stability for C
3
H
8
combustion than noble metal catalyst. It is expected to be applicable in the removal of VOCs.
Graphic Abstract
Due to the B-site transition metal doping, the surface oxygen activation behavior of the spinel catalyst can be modulated, which makes AFe
2
O
4
have a higher propane catalytic activity than AAl
2
O
4
.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10562-020-03239-3</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1011-372X |
| ispartof | Catalysis letters, 2020-12, Vol.150 (12), p.3617-3625 |
| issn | 1011-372X 1572-879X |
| language | eng |
| recordid | cdi_gale_infotracacademiconefile_A638924265 |
| source | SpringerLink Journals |
| subjects | Catalysis Catalysts Chemistry Chemistry and Materials Science Combustion Industrial Chemistry/Chemical Engineering Organometallic Chemistry Physical Chemistry Propane Spinel group Transition metal compounds |
| title | Insights into the Behaviors of the Catalytic Combustion of Propane over Spinel Catalysts |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-08T01%3A37%3A21IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Insights%20into%20the%20Behaviors%20of%20the%20Catalytic%20Combustion%20of%20Propane%20over%20Spinel%20Catalysts&rft.jtitle=Catalysis%20letters&rft.au=Gao,%20Yang&rft.date=2020-12-01&rft.volume=150&rft.issue=12&rft.spage=3617&rft.epage=3625&rft.pages=3617-3625&rft.issn=1011-372X&rft.eissn=1572-879X&rft_id=info:doi/10.1007/s10562-020-03239-3&rft_dat=%3Cgale_cross%3EA638924265%3C/gale_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rft_galeid=A638924265&rfr_iscdi=true |