Stability of Hydrogen Fluoride Under Water-Gas-Reaction Conditions
The prime objective of the investigation was to prove the stability of hydrogen fluoride under water-gas-reaction conditions. Calculations of the thermodynamically equilibrium composition of substances in the system of elements C–H–F–O were conducted, and it has been shown that with excess carbon an...
Gespeichert in:
| Veröffentlicht in: | Journal of engineering physics and thermophysics 2019-07, Vol.92 (4), p.889-898 |
|---|---|
| Hauptverfasser: | , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 898 |
|---|---|
| container_issue | 4 |
| container_start_page | 889 |
| container_title | Journal of engineering physics and thermophysics |
| container_volume | 92 |
| creator | Kapustin, V. V. Pashkevich, D. S. Talalov, V. A. Mukhortov, D. A. Alekseev, Yu. I. Petrov, V. B. Kambur, P. S. Kambur, M. P. Voznyuk, O. N. |
| description | The prime objective of the investigation was to prove the stability of hydrogen fluoride under water-gas-reaction conditions. Calculations of the thermodynamically equilibrium composition of substances in the system of elements C–H–F–O were conducted, and it has been shown that with excess carbon and at a temperature of 1000 to 2000 K, the basic components of the mixture are carbon mono- and dioxide, hydrogen, methane, and hydrogen fluoride, and carbon fluorides and oxyfluorides are absent. At a temperature above 1300 K, the thermodynamically equilibrium mixture consists of carbon monoxide, hydrogen, and hydrogen fluoride. Calculation results have been confirmed by laboratory experiments in which the only fluorine-containing substance, i.e., hydrogen fluoride, was found as part of the products of interaction of water and carbon in the presence of hydrogen fluoride at a temperature of the order of 1500 K. The obtained results can become a basis for the technology of obtaining anhydrous hydrogen fluoride from its aqueous solutions, including the azeotropic one, by high-temperature interaction of the steam and carbon at |
| doi_str_mv | 10.1007/s10891-019-02000-x |
| format | Article |
| fullrecord | <record><control><sourceid>gale_cross</sourceid><recordid>TN_cdi_gale_infotracacademiconefile_A601764486</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A601764486</galeid><sourcerecordid>A601764486</sourcerecordid><originalsourceid>FETCH-LOGICAL-c315t-6868a99f213361f52d58d708a5841ad510508de95c24144c2c4cc6b935780bcd3</originalsourceid><addsrcrecordid>eNp9kD1PAjEYgC9GExH9A063OhTb68f1RiQCJiQmINGtKW3vUgKtaUsC_97iubCYDn3TPs87PEXxiOAIQVg_RwR5gwBEDYAVhBAcr4oBojUGvEZf13mGrMrfFb0t7mLcZqThBA-Kl1WSG7uz6VT6tpyfdPCdceV0d_DBalOunTah_JTJBDCTESyNVMl6V0680_Y8xfvippW7aB7-7mGxnr5-TOZg8T57m4wXQGFEE2Cccdk0bYUwZqillaZc15BLygmSmiJIIdemoaoiiBBVKaIU2zSY1hxulMbDYtTv7eTOCOtan4JU-Wizt8o709r8PmYQ1YwQzrLwdCFkJplj6uQhRvG2Wl6yVc-q4GMMphXfwe5lOAkExTmx6BOLnFj8JhbHLOFeihl2nQli6w_B5Qj_WT8VTX0q</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Stability of Hydrogen Fluoride Under Water-Gas-Reaction Conditions</title><source>Springer Nature - Complete Springer Journals</source><creator>Kapustin, V. V. ; Pashkevich, D. S. ; Talalov, V. A. ; Mukhortov, D. A. ; Alekseev, Yu. I. ; Petrov, V. B. ; Kambur, P. S. ; Kambur, M. P. ; Voznyuk, O. N.</creator><creatorcontrib>Kapustin, V. V. ; Pashkevich, D. S. ; Talalov, V. A. ; Mukhortov, D. A. ; Alekseev, Yu. I. ; Petrov, V. B. ; Kambur, P. S. ; Kambur, M. P. ; Voznyuk, O. N.</creatorcontrib><description>The prime objective of the investigation was to prove the stability of hydrogen fluoride under water-gas-reaction conditions. Calculations of the thermodynamically equilibrium composition of substances in the system of elements C–H–F–O were conducted, and it has been shown that with excess carbon and at a temperature of 1000 to 2000 K, the basic components of the mixture are carbon mono- and dioxide, hydrogen, methane, and hydrogen fluoride, and carbon fluorides and oxyfluorides are absent. At a temperature above 1300 K, the thermodynamically equilibrium mixture consists of carbon monoxide, hydrogen, and hydrogen fluoride. Calculation results have been confirmed by laboratory experiments in which the only fluorine-containing substance, i.e., hydrogen fluoride, was found as part of the products of interaction of water and carbon in the presence of hydrogen fluoride at a temperature of the order of 1500 K. The obtained results can become a basis for the technology of obtaining anhydrous hydrogen fluoride from its aqueous solutions, including the azeotropic one, by high-temperature interaction of the steam and carbon at</description><identifier>ISSN: 1062-0125</identifier><identifier>EISSN: 1573-871X</identifier><identifier>DOI: 10.1007/s10891-019-02000-x</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Classical Mechanics ; Complex Systems ; Engineering ; Engineering Thermodynamics ; Heat and Mass Transfer ; Industrial Chemistry/Chemical Engineering ; Thermodynamics</subject><ispartof>Journal of engineering physics and thermophysics, 2019-07, Vol.92 (4), p.889-898</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019</rights><rights>COPYRIGHT 2019 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c315t-6868a99f213361f52d58d708a5841ad510508de95c24144c2c4cc6b935780bcd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10891-019-02000-x$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10891-019-02000-x$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Kapustin, V. V.</creatorcontrib><creatorcontrib>Pashkevich, D. S.</creatorcontrib><creatorcontrib>Talalov, V. A.</creatorcontrib><creatorcontrib>Mukhortov, D. A.</creatorcontrib><creatorcontrib>Alekseev, Yu. I.</creatorcontrib><creatorcontrib>Petrov, V. B.</creatorcontrib><creatorcontrib>Kambur, P. S.</creatorcontrib><creatorcontrib>Kambur, M. P.</creatorcontrib><creatorcontrib>Voznyuk, O. N.</creatorcontrib><title>Stability of Hydrogen Fluoride Under Water-Gas-Reaction Conditions</title><title>Journal of engineering physics and thermophysics</title><addtitle>J Eng Phys Thermophy</addtitle><description>The prime objective of the investigation was to prove the stability of hydrogen fluoride under water-gas-reaction conditions. Calculations of the thermodynamically equilibrium composition of substances in the system of elements C–H–F–O were conducted, and it has been shown that with excess carbon and at a temperature of 1000 to 2000 K, the basic components of the mixture are carbon mono- and dioxide, hydrogen, methane, and hydrogen fluoride, and carbon fluorides and oxyfluorides are absent. At a temperature above 1300 K, the thermodynamically equilibrium mixture consists of carbon monoxide, hydrogen, and hydrogen fluoride. Calculation results have been confirmed by laboratory experiments in which the only fluorine-containing substance, i.e., hydrogen fluoride, was found as part of the products of interaction of water and carbon in the presence of hydrogen fluoride at a temperature of the order of 1500 K. The obtained results can become a basis for the technology of obtaining anhydrous hydrogen fluoride from its aqueous solutions, including the azeotropic one, by high-temperature interaction of the steam and carbon at</description><subject>Classical Mechanics</subject><subject>Complex Systems</subject><subject>Engineering</subject><subject>Engineering Thermodynamics</subject><subject>Heat and Mass Transfer</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Thermodynamics</subject><issn>1062-0125</issn><issn>1573-871X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kD1PAjEYgC9GExH9A063OhTb68f1RiQCJiQmINGtKW3vUgKtaUsC_97iubCYDn3TPs87PEXxiOAIQVg_RwR5gwBEDYAVhBAcr4oBojUGvEZf13mGrMrfFb0t7mLcZqThBA-Kl1WSG7uz6VT6tpyfdPCdceV0d_DBalOunTah_JTJBDCTESyNVMl6V0680_Y8xfvippW7aB7-7mGxnr5-TOZg8T57m4wXQGFEE2Cccdk0bYUwZqillaZc15BLygmSmiJIIdemoaoiiBBVKaIU2zSY1hxulMbDYtTv7eTOCOtan4JU-Wizt8o709r8PmYQ1YwQzrLwdCFkJplj6uQhRvG2Wl6yVc-q4GMMphXfwe5lOAkExTmx6BOLnFj8JhbHLOFeihl2nQli6w_B5Qj_WT8VTX0q</recordid><startdate>20190701</startdate><enddate>20190701</enddate><creator>Kapustin, V. V.</creator><creator>Pashkevich, D. S.</creator><creator>Talalov, V. A.</creator><creator>Mukhortov, D. A.</creator><creator>Alekseev, Yu. I.</creator><creator>Petrov, V. B.</creator><creator>Kambur, P. S.</creator><creator>Kambur, M. P.</creator><creator>Voznyuk, O. N.</creator><general>Springer US</general><general>Springer</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope></search><sort><creationdate>20190701</creationdate><title>Stability of Hydrogen Fluoride Under Water-Gas-Reaction Conditions</title><author>Kapustin, V. V. ; Pashkevich, D. S. ; Talalov, V. A. ; Mukhortov, D. A. ; Alekseev, Yu. I. ; Petrov, V. B. ; Kambur, P. S. ; Kambur, M. P. ; Voznyuk, O. N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c315t-6868a99f213361f52d58d708a5841ad510508de95c24144c2c4cc6b935780bcd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Classical Mechanics</topic><topic>Complex Systems</topic><topic>Engineering</topic><topic>Engineering Thermodynamics</topic><topic>Heat and Mass Transfer</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Thermodynamics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kapustin, V. V.</creatorcontrib><creatorcontrib>Pashkevich, D. S.</creatorcontrib><creatorcontrib>Talalov, V. A.</creatorcontrib><creatorcontrib>Mukhortov, D. A.</creatorcontrib><creatorcontrib>Alekseev, Yu. I.</creatorcontrib><creatorcontrib>Petrov, V. B.</creatorcontrib><creatorcontrib>Kambur, P. S.</creatorcontrib><creatorcontrib>Kambur, M. P.</creatorcontrib><creatorcontrib>Voznyuk, O. N.</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><jtitle>Journal of engineering physics and thermophysics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kapustin, V. V.</au><au>Pashkevich, D. S.</au><au>Talalov, V. A.</au><au>Mukhortov, D. A.</au><au>Alekseev, Yu. I.</au><au>Petrov, V. B.</au><au>Kambur, P. S.</au><au>Kambur, M. P.</au><au>Voznyuk, O. N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Stability of Hydrogen Fluoride Under Water-Gas-Reaction Conditions</atitle><jtitle>Journal of engineering physics and thermophysics</jtitle><stitle>J Eng Phys Thermophy</stitle><date>2019-07-01</date><risdate>2019</risdate><volume>92</volume><issue>4</issue><spage>889</spage><epage>898</epage><pages>889-898</pages><issn>1062-0125</issn><eissn>1573-871X</eissn><abstract>The prime objective of the investigation was to prove the stability of hydrogen fluoride under water-gas-reaction conditions. Calculations of the thermodynamically equilibrium composition of substances in the system of elements C–H–F–O were conducted, and it has been shown that with excess carbon and at a temperature of 1000 to 2000 K, the basic components of the mixture are carbon mono- and dioxide, hydrogen, methane, and hydrogen fluoride, and carbon fluorides and oxyfluorides are absent. At a temperature above 1300 K, the thermodynamically equilibrium mixture consists of carbon monoxide, hydrogen, and hydrogen fluoride. Calculation results have been confirmed by laboratory experiments in which the only fluorine-containing substance, i.e., hydrogen fluoride, was found as part of the products of interaction of water and carbon in the presence of hydrogen fluoride at a temperature of the order of 1500 K. The obtained results can become a basis for the technology of obtaining anhydrous hydrogen fluoride from its aqueous solutions, including the azeotropic one, by high-temperature interaction of the steam and carbon at</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10891-019-02000-x</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1062-0125 |
| ispartof | Journal of engineering physics and thermophysics, 2019-07, Vol.92 (4), p.889-898 |
| issn | 1062-0125 1573-871X |
| language | eng |
| recordid | cdi_gale_infotracacademiconefile_A601764486 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Classical Mechanics Complex Systems Engineering Engineering Thermodynamics Heat and Mass Transfer Industrial Chemistry/Chemical Engineering Thermodynamics |
| title | Stability of Hydrogen Fluoride Under Water-Gas-Reaction Conditions |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-31T21%3A40%3A37IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Stability%20of%20Hydrogen%20Fluoride%20Under%20Water-Gas-Reaction%20Conditions&rft.jtitle=Journal%20of%20engineering%20physics%20and%20thermophysics&rft.au=Kapustin,%20V.%20V.&rft.date=2019-07-01&rft.volume=92&rft.issue=4&rft.spage=889&rft.epage=898&rft.pages=889-898&rft.issn=1062-0125&rft.eissn=1573-871X&rft_id=info:doi/10.1007/s10891-019-02000-x&rft_dat=%3Cgale_cross%3EA601764486%3C/gale_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rft_galeid=A601764486&rfr_iscdi=true |