Oxidation of Aniline to Nitrobenzene Catalysed by 1-Butyl-3-methyl imidazolium phosphotungstate Hybrid Material Using m-chloroperbenzoic Acid as an Oxidant
Keggin ion based hybrid materials, [BmIm] 3 [PW 12 O 40 ], [TBA] 3 PW 12 O 40 and [BuPy] 3 PW 12 O 40 , were prepared by proton exchange with organic cations, 1-butyl-3-methyl imidazolium ion, tetrabutylammonium ion and butylpyridinium ion, respectively. The formation of hybrid materials was confirm...
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| Veröffentlicht in: | Catalysis letters 2018, Vol.148 (1), p.246-257 |
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| creator | Meenakshi, R. Shakeela, K. Kutti Rani, S. Ranga Rao, G. |
| description | Keggin ion based hybrid materials, [BmIm]
3
[PW
12
O
40
], [TBA]
3
PW
12
O
40
and [BuPy]
3
PW
12
O
40
, were prepared by proton exchange with organic cations, 1-butyl-3-methyl imidazolium ion, tetrabutylammonium ion and butylpyridinium ion, respectively. The formation of hybrid materials was confirmed by FTIR, PXRD, SEM, TG-DTA, DSC analysis. These hybrid compounds are active for oxidation of aniline using m-chloroperbenzoic acid as an oxidant. Among the three hybrid compounds, 1-butyl-3-methyl imidazolium phosphotungstate was found to be the best and efficient catalyst for selective aniline oxidation to nitrobenzene. It is a recoverable and reusable catalytic system. The redox property of the phosphotungstate cluster in the hybrid material is involved in the catalytic activity.
Graphical Abstract |
| doi_str_mv | 10.1007/s10562-017-2214-2 |
| format | Article |
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3
[PW
12
O
40
], [TBA]
3
PW
12
O
40
and [BuPy]
3
PW
12
O
40
, were prepared by proton exchange with organic cations, 1-butyl-3-methyl imidazolium ion, tetrabutylammonium ion and butylpyridinium ion, respectively. The formation of hybrid materials was confirmed by FTIR, PXRD, SEM, TG-DTA, DSC analysis. These hybrid compounds are active for oxidation of aniline using m-chloroperbenzoic acid as an oxidant. Among the three hybrid compounds, 1-butyl-3-methyl imidazolium phosphotungstate was found to be the best and efficient catalyst for selective aniline oxidation to nitrobenzene. It is a recoverable and reusable catalytic system. The redox property of the phosphotungstate cluster in the hybrid material is involved in the catalytic activity.
Graphical Abstract</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-017-2214-2</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Analysis ; Aniline ; Catalysis ; Catalysts ; Chemistry ; Chemistry and Materials Science ; Industrial Chemistry/Chemical Engineering ; Nitrobenzenes ; Organometallic Chemistry ; Oxidation-reduction reactions ; Physical Chemistry</subject><ispartof>Catalysis letters, 2018, Vol.148 (1), p.246-257</ispartof><rights>Springer Science+Business Media, LLC 2017</rights><rights>COPYRIGHT 2018 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c398t-499b63ad9edfe97df7f3d6b48cdda608d0ae22a4e69c4b07e6f3fe6012d750563</citedby><cites>FETCH-LOGICAL-c398t-499b63ad9edfe97df7f3d6b48cdda608d0ae22a4e69c4b07e6f3fe6012d750563</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10562-017-2214-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10562-017-2214-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Meenakshi, R.</creatorcontrib><creatorcontrib>Shakeela, K.</creatorcontrib><creatorcontrib>Kutti Rani, S.</creatorcontrib><creatorcontrib>Ranga Rao, G.</creatorcontrib><title>Oxidation of Aniline to Nitrobenzene Catalysed by 1-Butyl-3-methyl imidazolium phosphotungstate Hybrid Material Using m-chloroperbenzoic Acid as an Oxidant</title><title>Catalysis letters</title><addtitle>Catal Lett</addtitle><description>Keggin ion based hybrid materials, [BmIm]
3
[PW
12
O
40
], [TBA]
3
PW
12
O
40
and [BuPy]
3
PW
12
O
40
, were prepared by proton exchange with organic cations, 1-butyl-3-methyl imidazolium ion, tetrabutylammonium ion and butylpyridinium ion, respectively. The formation of hybrid materials was confirmed by FTIR, PXRD, SEM, TG-DTA, DSC analysis. These hybrid compounds are active for oxidation of aniline using m-chloroperbenzoic acid as an oxidant. Among the three hybrid compounds, 1-butyl-3-methyl imidazolium phosphotungstate was found to be the best and efficient catalyst for selective aniline oxidation to nitrobenzene. It is a recoverable and reusable catalytic system. The redox property of the phosphotungstate cluster in the hybrid material is involved in the catalytic activity.
Graphical Abstract</description><subject>Analysis</subject><subject>Aniline</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Nitrobenzenes</subject><subject>Organometallic Chemistry</subject><subject>Oxidation-reduction reactions</subject><subject>Physical Chemistry</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp9kc9q3DAQxk1poWmSB-hN1x6U6o_XWh23S9sEkgbSBHITsjXyKsjSIskQ51X6stVme8mlCKEZ8f1mhvma5jMlF5QQ8TVTsuoYJlRgxmiL2bvmhK4Ew2shH9_XmFCKuWCPH5tPOT8RQqSg8qT5c_vsjC4uBhQt2gTnXQBUIvrlSoo9hBeo-VYX7ZcMBvULovjbXBaPOZ6g7BaP3FRLvETv5gntdzHXW-Yw5qILoMulT86gmxonpz16yC6MaMLDzscU95AOPaIb0GaoMp2RDuh1plDOmg9W-wzn_97T5uHH9_vtJb6-_Xm13Vzjgct1wa2Ufce1kWAsSGGssNx0fbsejNEdWRuigTHdQieHticCOsstdIQyI1Z1a_y0uTjWHbUH5YKNJemhHgOTG2IA6-r_ZsVY13IqeAW-vAGqpsBzGfWcs7r6ffdWS4_aIcWcE1i1T27SaVGUqIN16midqtapg3WKVYYdmVy1YYSknuKcQt3Bf6C_gcqfDg</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Meenakshi, R.</creator><creator>Shakeela, K.</creator><creator>Kutti Rani, S.</creator><creator>Ranga Rao, G.</creator><general>Springer US</general><general>Springer</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope></search><sort><creationdate>2018</creationdate><title>Oxidation of Aniline to Nitrobenzene Catalysed by 1-Butyl-3-methyl imidazolium phosphotungstate Hybrid Material Using m-chloroperbenzoic Acid as an Oxidant</title><author>Meenakshi, R. ; Shakeela, K. ; Kutti Rani, S. ; Ranga Rao, G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c398t-499b63ad9edfe97df7f3d6b48cdda608d0ae22a4e69c4b07e6f3fe6012d750563</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Analysis</topic><topic>Aniline</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Nitrobenzenes</topic><topic>Organometallic Chemistry</topic><topic>Oxidation-reduction reactions</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Meenakshi, R.</creatorcontrib><creatorcontrib>Shakeela, K.</creatorcontrib><creatorcontrib>Kutti Rani, S.</creatorcontrib><creatorcontrib>Ranga Rao, G.</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Meenakshi, R.</au><au>Shakeela, K.</au><au>Kutti Rani, S.</au><au>Ranga Rao, G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Oxidation of Aniline to Nitrobenzene Catalysed by 1-Butyl-3-methyl imidazolium phosphotungstate Hybrid Material Using m-chloroperbenzoic Acid as an Oxidant</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2018</date><risdate>2018</risdate><volume>148</volume><issue>1</issue><spage>246</spage><epage>257</epage><pages>246-257</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>Keggin ion based hybrid materials, [BmIm]
3
[PW
12
O
40
], [TBA]
3
PW
12
O
40
and [BuPy]
3
PW
12
O
40
, were prepared by proton exchange with organic cations, 1-butyl-3-methyl imidazolium ion, tetrabutylammonium ion and butylpyridinium ion, respectively. The formation of hybrid materials was confirmed by FTIR, PXRD, SEM, TG-DTA, DSC analysis. These hybrid compounds are active for oxidation of aniline using m-chloroperbenzoic acid as an oxidant. Among the three hybrid compounds, 1-butyl-3-methyl imidazolium phosphotungstate was found to be the best and efficient catalyst for selective aniline oxidation to nitrobenzene. It is a recoverable and reusable catalytic system. The redox property of the phosphotungstate cluster in the hybrid material is involved in the catalytic activity.
Graphical Abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10562-017-2214-2</doi><tpages>12</tpages></addata></record> |
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| language | eng |
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| subjects | Analysis Aniline Catalysis Catalysts Chemistry Chemistry and Materials Science Industrial Chemistry/Chemical Engineering Nitrobenzenes Organometallic Chemistry Oxidation-reduction reactions Physical Chemistry |
| title | Oxidation of Aniline to Nitrobenzene Catalysed by 1-Butyl-3-methyl imidazolium phosphotungstate Hybrid Material Using m-chloroperbenzoic Acid as an Oxidant |
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