Green synthesis of ZnCo.sub.2O.sub.4 nanoparticles by Aloe albiflora extract and its application as catalyst on the thermal decomposition of ammonium perchlorate
ZnCo.sub.2O.sub.4 nanoparticles were prepared by green method using Aloe albiflora extract solution and characterized by Fourier transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy, and the result showed that the average particle size was
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| Veröffentlicht in: | Journal of thermal analysis and calorimetry 2017-12, Vol.130 (3), p.1327 |
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| container_issue | 3 |
| container_start_page | 1327 |
| container_title | Journal of thermal analysis and calorimetry |
| container_volume | 130 |
| creator | Juibari, Nafise Modanlou Eslami, Abbas |
| description | ZnCo.sub.2O.sub.4 nanoparticles were prepared by green method using Aloe albiflora extract solution and characterized by Fourier transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy, and the result showed that the average particle size was |
| doi_str_mv | 10.1007/s10973-017-6613-9 |
| format | Article |
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The effect of the ZnCo.sub.2O.sub.4 nanoparticles on thermal decomposition of ammonium perchlorate (AP) was enhancing the evolved heat from 400 to 1505 J g.sup.-1 and a decrease of decomposition temperature from 420 to 310 °C. The kinetic parameters of thermal decomposition of both pure AP and catalyzed sample have been calculated by Kissinger method, and the results showed that the values of pre-exponential factor and activation energy of thermal decomposition of catalyzed sample increased with respect to that of pure AP. However, the calculated rate constant was higher in presence of ZnCo.sub.2O.sub.4 nanoparticles.</description><identifier>ISSN: 1388-6150</identifier><identifier>DOI: 10.1007/s10973-017-6613-9</identifier><language>eng</language><publisher>Springer</publisher><subject>Diffraction ; Infrared spectroscopy ; Nanoparticles ; X-rays</subject><ispartof>Journal of thermal analysis and calorimetry, 2017-12, Vol.130 (3), p.1327</ispartof><rights>COPYRIGHT 2017 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Juibari, Nafise Modanlou</creatorcontrib><creatorcontrib>Eslami, Abbas</creatorcontrib><title>Green synthesis of ZnCo.sub.2O.sub.4 nanoparticles by Aloe albiflora extract and its application as catalyst on the thermal decomposition of ammonium perchlorate</title><title>Journal of thermal analysis and calorimetry</title><description>ZnCo.sub.2O.sub.4 nanoparticles were prepared by green method using Aloe albiflora extract solution and characterized by Fourier transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy, and the result showed that the average particle size was <30 nm. The effect of the ZnCo.sub.2O.sub.4 nanoparticles on thermal decomposition of ammonium perchlorate (AP) was enhancing the evolved heat from 400 to 1505 J g.sup.-1 and a decrease of decomposition temperature from 420 to 310 °C. The kinetic parameters of thermal decomposition of both pure AP and catalyzed sample have been calculated by Kissinger method, and the results showed that the values of pre-exponential factor and activation energy of thermal decomposition of catalyzed sample increased with respect to that of pure AP. However, the calculated rate constant was higher in presence of ZnCo.sub.2O.sub.4 nanoparticles.</description><subject>Diffraction</subject><subject>Infrared spectroscopy</subject><subject>Nanoparticles</subject><subject>X-rays</subject><issn>1388-6150</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNpVUE1LAzEQ3YOC9eMHeMvVw65JdpM0x1K0FgoF7clLmc0mbSSbLJsU7M_xn5pWD8owvJnhvRnmFcU9wRXBWDxGgqWoS0xEyTmpS3lRTEg9nZacMHxVXMf4gTGWEpNJ8bUYtfYoHn3a62gjCga9-3mo4qGt6PoMDfLgwwBjssrpiNojmrmgEbjWGhdGQPozjaASAt8hmyKCYXBWQbLBI4goV-COMaHc5jOnHHtwqNMq9EOI9kzMl6Hvg7eHHg16VPvT6qRvi0sDLuq7X7wpNs9Pm_lLuVovlvPZqtyJmpZS8KZpeCsw6YwBTiVueaclY4oJ1ireAFZCthxrrPC0UZSaLnvQKEVl3er6pqh-1u7A6a31JpxeytHp3qrgtbF5PmOk4UxQRrPg4Z8gc1L2YQeHGLfLt9e_3G_Yvn7v</recordid><startdate>20171201</startdate><enddate>20171201</enddate><creator>Juibari, Nafise Modanlou</creator><creator>Eslami, Abbas</creator><general>Springer</general><scope>ISR</scope></search><sort><creationdate>20171201</creationdate><title>Green synthesis of ZnCo.sub.2O.sub.4 nanoparticles by Aloe albiflora extract and its application as catalyst on the thermal decomposition of ammonium perchlorate</title><author>Juibari, Nafise Modanlou ; Eslami, Abbas</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-g732-9764446b701dffa6290b6de955c575bc64a0c79b60e0c084c22fd0994cc293be3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Diffraction</topic><topic>Infrared spectroscopy</topic><topic>Nanoparticles</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Juibari, Nafise Modanlou</creatorcontrib><creatorcontrib>Eslami, Abbas</creatorcontrib><collection>Gale In Context: Science</collection><jtitle>Journal of thermal analysis and calorimetry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Juibari, Nafise Modanlou</au><au>Eslami, Abbas</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Green synthesis of ZnCo.sub.2O.sub.4 nanoparticles by Aloe albiflora extract and its application as catalyst on the thermal decomposition of ammonium perchlorate</atitle><jtitle>Journal of thermal analysis and calorimetry</jtitle><date>2017-12-01</date><risdate>2017</risdate><volume>130</volume><issue>3</issue><spage>1327</spage><pages>1327-</pages><issn>1388-6150</issn><abstract>ZnCo.sub.2O.sub.4 nanoparticles were prepared by green method using Aloe albiflora extract solution and characterized by Fourier transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy, and the result showed that the average particle size was <30 nm. The effect of the ZnCo.sub.2O.sub.4 nanoparticles on thermal decomposition of ammonium perchlorate (AP) was enhancing the evolved heat from 400 to 1505 J g.sup.-1 and a decrease of decomposition temperature from 420 to 310 °C. The kinetic parameters of thermal decomposition of both pure AP and catalyzed sample have been calculated by Kissinger method, and the results showed that the values of pre-exponential factor and activation energy of thermal decomposition of catalyzed sample increased with respect to that of pure AP. However, the calculated rate constant was higher in presence of ZnCo.sub.2O.sub.4 nanoparticles.</abstract><pub>Springer</pub><doi>10.1007/s10973-017-6613-9</doi><tpages>7</tpages></addata></record> |
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| issn | 1388-6150 |
| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Diffraction Infrared spectroscopy Nanoparticles X-rays |
| title | Green synthesis of ZnCo.sub.2O.sub.4 nanoparticles by Aloe albiflora extract and its application as catalyst on the thermal decomposition of ammonium perchlorate |
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