Spontaneous unipolarity and anomalies of the dielectric and piezoelectric properties and electrical conductivity of initially heavily doped polydomain LiNb[O.sub.3]: Zn crystals

A significant spontaneous unipolarity in initially polydomain LiNb[O.sub.3]:Zn crystals doped in the range of "threshold" impurity concentrations (~4.5-4.7 mol %) has been revealed from high-temperature measurements and after high-temperature annealing under short circuit conditions. The e...

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Veröffentlicht in:Physics of the solid state 2015-08, p.1541
Hauptverfasser: Palatnikov, M.N, Sandler, V.A, Sidorov, N.V, Makarova, O.V, Biryukova, I.V, Efremov, I.N, Ivanenko, D.V
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container_title Physics of the solid state
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creator Palatnikov, M.N
Sandler, V.A
Sidorov, N.V
Makarova, O.V
Biryukova, I.V
Efremov, I.N
Ivanenko, D.V
description A significant spontaneous unipolarity in initially polydomain LiNb[O.sub.3]:Zn crystals doped in the range of "threshold" impurity concentrations (~4.5-4.7 mol %) has been revealed from high-temperature measurements and after high-temperature annealing under short circuit conditions. The effect of strong increase in the spontaneous unipolarity is accompanied by a pronounced low-frequency dielectric dispersion and abrupt anomalies in the temperature dependences of the electrical conductivity and dielectric permittivity. The piezoelectric coefficient [d.sub.333] increases to nearly maximum values available in the reference literature for nominally pure single-domain LiNb[O.sub.3] crystals.
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subjects Annealing
Electric properties
Electrical conductivity
Lithium niobate
Zinc
title Spontaneous unipolarity and anomalies of the dielectric and piezoelectric properties and electrical conductivity of initially heavily doped polydomain LiNb[O.sub.3]: Zn crystals
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