X-ray photoelectron and mossbauer spectroscopy studies of the valence state of transition metal ions in [Co.sub.1-x][Fe.sub.x][Cr.sub.2][O.sub.4] ceramics
The valence state of transition metal ions in the [Co.sub.1-x][Fe.sub.x][Cr.sub.2][O.sub.4] (x = 0.1, 0.2, 0.5) system has been investigated using X-ray photoelectron and Mossbauer spectroscopy. It has been shown that, in this system, there are [Fe.sup.2+] and [Fe.sup.3+] ions. The relative [Fe.sup....
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| Veröffentlicht in: | Physics of the solid state 2016-01, Vol.58 (1), p.108 |
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| creator | Kochur, A.G Guglev, K.A Kozakov, A.T Kubrin, S.P Nikolskii, A.V Torgashev, V.I |
| description | The valence state of transition metal ions in the [Co.sub.1-x][Fe.sub.x][Cr.sub.2][O.sub.4] (x = 0.1, 0.2, 0.5) system has been investigated using X-ray photoelectron and Mossbauer spectroscopy. It has been shown that, in this system, there are [Fe.sup.2+] and [Fe.sup.3+] ions. The relative [Fe.sup.3+]/[Fe.sup.2+] contents have been determined by fitting the experimental Fe 2p photoelectron spectra by a superposition of theoretical spectra of the [Fe.sup.2+] and [Fe.sup.3+] ions, as well as using Mossbauer spectroscopy. |
| doi_str_mv | 10.1134/S1063783416010170 |
| format | Article |
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It has been shown that, in this system, there are [Fe.sup.2+] and [Fe.sup.3+] ions. The relative [Fe.sup.3+]/[Fe.sup.2+] contents have been determined by fitting the experimental Fe 2p photoelectron spectra by a superposition of theoretical spectra of the [Fe.sup.2+] and [Fe.sup.3+] ions, as well as using Mossbauer spectroscopy.</description><identifier>ISSN: 1063-7834</identifier><identifier>EISSN: 1090-6460</identifier><identifier>DOI: 10.1134/S1063783416010170</identifier><language>eng</language><publisher>Springer</publisher><subject>Ceramic materials ; Ceramics ; Cobalt ; Spectrum analysis ; Spinel group ; Transition metal compounds</subject><ispartof>Physics of the solid state, 2016-01, Vol.58 (1), p.108</ispartof><rights>COPYRIGHT 2016 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Kochur, A.G</creatorcontrib><creatorcontrib>Guglev, K.A</creatorcontrib><creatorcontrib>Kozakov, A.T</creatorcontrib><creatorcontrib>Kubrin, S.P</creatorcontrib><creatorcontrib>Nikolskii, A.V</creatorcontrib><creatorcontrib>Torgashev, V.I</creatorcontrib><title>X-ray photoelectron and mossbauer spectroscopy studies of the valence state of transition metal ions in [Co.sub.1-x][Fe.sub.x][Cr.sub.2][O.sub.4] ceramics</title><title>Physics of the solid state</title><description>The valence state of transition metal ions in the [Co.sub.1-x][Fe.sub.x][Cr.sub.2][O.sub.4] (x = 0.1, 0.2, 0.5) system has been investigated using X-ray photoelectron and Mossbauer spectroscopy. It has been shown that, in this system, there are [Fe.sup.2+] and [Fe.sup.3+] ions. The relative [Fe.sup.3+]/[Fe.sup.2+] contents have been determined by fitting the experimental Fe 2p photoelectron spectra by a superposition of theoretical spectra of the [Fe.sup.2+] and [Fe.sup.3+] ions, as well as using Mossbauer spectroscopy.</description><subject>Ceramic materials</subject><subject>Ceramics</subject><subject>Cobalt</subject><subject>Spectrum analysis</subject><subject>Spinel group</subject><subject>Transition metal compounds</subject><issn>1063-7834</issn><issn>1090-6460</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNpVj09Lw0AQxRdRsFY_gLe9ekid_ZNNeizBaqFQsD0IpZRNMttG0mzJbsR-FT-t2-hBT_PjzXvDPELuGYwYE_JxyUCJJBWSKWDAErggAwZjiJRUcHlmJaLz_prcOPcOwBiLxwPy9Ra1-kSPe-st1lj41jZUNyU9WOdy3WFL3bGXXWGPJ-p8V1boqDXU75F-6BqbAoOsPfZiqxtX-SpcOaDXNQ3kaNXQdWZHrstHLPrcrKfYc6Cs7Ylv1ose5IYW2OpDVbhbcmV07fDudw7Javq0yl6i-eJ5lk3m0S4RccRKo00J3PA8LgESnkpQiShB5EmajiVwXuhCMJAiTrAUwAxyo2KVa8hTVoghGf2c3YUu26oxNnQIEV1i-MI2aKqgT6SUiUi5jEPg4V8geDx--p3unNvOlq9_vd9fdHy4</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Kochur, A.G</creator><creator>Guglev, K.A</creator><creator>Kozakov, A.T</creator><creator>Kubrin, S.P</creator><creator>Nikolskii, A.V</creator><creator>Torgashev, V.I</creator><general>Springer</general><scope>ISR</scope></search><sort><creationdate>20160101</creationdate><title>X-ray photoelectron and mossbauer spectroscopy studies of the valence state of transition metal ions in [Co.sub.1-x][Fe.sub.x][Cr.sub.2][O.sub.4] ceramics</title><author>Kochur, A.G ; Guglev, K.A ; Kozakov, A.T ; Kubrin, S.P ; Nikolskii, A.V ; Torgashev, V.I</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-g735-1dfafd02f2b5d0072840673d03b78894022cac3104357ed301fe2f656ba0b81c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Ceramic materials</topic><topic>Ceramics</topic><topic>Cobalt</topic><topic>Spectrum analysis</topic><topic>Spinel group</topic><topic>Transition metal compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kochur, A.G</creatorcontrib><creatorcontrib>Guglev, K.A</creatorcontrib><creatorcontrib>Kozakov, A.T</creatorcontrib><creatorcontrib>Kubrin, S.P</creatorcontrib><creatorcontrib>Nikolskii, A.V</creatorcontrib><creatorcontrib>Torgashev, V.I</creatorcontrib><collection>Gale In Context: Science</collection><jtitle>Physics of the solid state</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kochur, A.G</au><au>Guglev, K.A</au><au>Kozakov, A.T</au><au>Kubrin, S.P</au><au>Nikolskii, A.V</au><au>Torgashev, V.I</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>X-ray photoelectron and mossbauer spectroscopy studies of the valence state of transition metal ions in [Co.sub.1-x][Fe.sub.x][Cr.sub.2][O.sub.4] ceramics</atitle><jtitle>Physics of the solid state</jtitle><date>2016-01-01</date><risdate>2016</risdate><volume>58</volume><issue>1</issue><spage>108</spage><pages>108-</pages><issn>1063-7834</issn><eissn>1090-6460</eissn><abstract>The valence state of transition metal ions in the [Co.sub.1-x][Fe.sub.x][Cr.sub.2][O.sub.4] (x = 0.1, 0.2, 0.5) system has been investigated using X-ray photoelectron and Mossbauer spectroscopy. It has been shown that, in this system, there are [Fe.sup.2+] and [Fe.sup.3+] ions. The relative [Fe.sup.3+]/[Fe.sup.2+] contents have been determined by fitting the experimental Fe 2p photoelectron spectra by a superposition of theoretical spectra of the [Fe.sup.2+] and [Fe.sup.3+] ions, as well as using Mossbauer spectroscopy.</abstract><pub>Springer</pub><doi>10.1134/S1063783416010170</doi><tpages>7</tpages></addata></record> |
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| subjects | Ceramic materials Ceramics Cobalt Spectrum analysis Spinel group Transition metal compounds |
| title | X-ray photoelectron and mossbauer spectroscopy studies of the valence state of transition metal ions in [Co.sub.1-x][Fe.sub.x][Cr.sub.2][O.sub.4] ceramics |
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