Activity and Selectivity of an Amphoteric ZrO.sub.2-TiO.sub.2 Catalyst in the Conversion of Dihydroxyacetone into Ethyl Lactate and Lactic Acid
A 96% conversion of dihydroxyacetone dissolved in aqueous ethanol mixtures was achieved on an amphoteric ZnO.sub.2-TiO.sub.2 catalyst in a flow reactor at 140 °C and 1.0 MPa with identical selectivity relative to the two reaction products, lactic acid and ethyl lactate. Variation of the ethanol : wa...
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Veröffentlicht in: | Theoretical and experimental chemistry 2015-01, Vol.50 (6), p.384 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | A 96% conversion of dihydroxyacetone dissolved in aqueous ethanol mixtures was achieved on an amphoteric ZnO.sub.2-TiO.sub.2 catalyst in a flow reactor at 140 °C and 1.0 MPa with identical selectivity relative to the two reaction products, lactic acid and ethyl lactate. Variation of the ethanol : water ratio significantly affects the activity and selectivity of the catalyst. The maximum catalyst efficiency was achieved using an aqueous solution containing 65 mass % ethanol. |
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ISSN: | 0040-5760 |
DOI: | 10.1007/s11237-015-9392-z |