Hydrogenation, disproportionation, desorption, and recombination in the [Sm.sub.2][Co.sub.17-x][Fe.sub.x]-[H.sub.2] system. x-ray diffraction
Differential thermal analysis and X-ray diffraction are used to study phase transitions in the [Sm.sub.2][Co.sub.17-x][Fe.sub.x]-[H.sub.2] system (x = 3.9 and 5.95) during conventional and solid HDDR at hydrogen pressure 0.57-4.0 MPa and temperature up to 950°C. The ferromagnetic phase with [Th.sub....
Gespeichert in:
| Veröffentlicht in: | Powder metallurgy and metal ceramics 2014-09, Vol.53 (5-6), p.343 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | 5-6 |
| container_start_page | 343 |
| container_title | Powder metallurgy and metal ceramics |
| container_volume | 53 |
| creator | Bulyk, I.I Pilat, M.V Lyutyy, P. Ya |
| description | Differential thermal analysis and X-ray diffraction are used to study phase transitions in the [Sm.sub.2][Co.sub.17-x][Fe.sub.x]-[H.sub.2] system (x = 3.9 and 5.95) during conventional and solid HDDR at hydrogen pressure 0.57-4.0 MPa and temperature up to 950°C. The ferromagnetic phase with [Th.sub.2][Zn.sub.17] structure disproportionates into Sm[H.sub.2 ± ], cobalt, and intermetallic FeCo after one-hour interaction with hydrogen at 1.1 and 0.6MPa and 700°C with x = 3.9 and 5.95. Recombination in vacuum at 770-950°C leads to a two-phase alloy consisting of the [Th.sub.2][Zn.sub.17]-type phase and intermetallic FeCo. Keywords: hydrogenation, disproportionation, desorption, recombination; samarium-cobalt alloys; two-phase ferromagnetic materials. |
| doi_str_mv | 10.1007/s11106-014-9622-2 |
| format | Article |
| fullrecord | <record><control><sourceid>gale</sourceid><recordid>TN_cdi_gale_infotracacademiconefile_A388967926</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A388967926</galeid><sourcerecordid>A388967926</sourcerecordid><originalsourceid>FETCH-gale_infotracacademiconefile_A3889679263</originalsourceid><addsrcrecordid>eNqVjUtOxDAMhrMAieFxAHY5AAlJOupjiUaMuoddVaFM6wxB07iKi9QegjuTeXAA5IX___dnm7FHraRWqngmrbXKhdJrUeXGCHPFVikohc6UuWG3RF9KJXKtV-ynXvqIewh28hieeO9pjDhiPNq_DAjjeNY29DxCh8POn8fcBz59Am_eBknfO2naZoMnpQsxt80WTmZuRVNfAE4LTTBIPotol_TSuWi747F7du3sgeDh0u-Y3L6-b2qxtwf48MHhlMhUPQy-wwDOp_wlK8sqLyqTZ_9e-AWDWmFd</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Hydrogenation, disproportionation, desorption, and recombination in the [Sm.sub.2][Co.sub.17-x][Fe.sub.x]-[H.sub.2] system. x-ray diffraction</title><source>SpringerNature Journals</source><creator>Bulyk, I.I ; Pilat, M.V ; Lyutyy, P. Ya</creator><creatorcontrib>Bulyk, I.I ; Pilat, M.V ; Lyutyy, P. Ya</creatorcontrib><description>Differential thermal analysis and X-ray diffraction are used to study phase transitions in the [Sm.sub.2][Co.sub.17-x][Fe.sub.x]-[H.sub.2] system (x = 3.9 and 5.95) during conventional and solid HDDR at hydrogen pressure 0.57-4.0 MPa and temperature up to 950°C. The ferromagnetic phase with [Th.sub.2][Zn.sub.17] structure disproportionates into Sm[H.sub.2 ± ], cobalt, and intermetallic FeCo after one-hour interaction with hydrogen at 1.1 and 0.6MPa and 700°C with x = 3.9 and 5.95. Recombination in vacuum at 770-950°C leads to a two-phase alloy consisting of the [Th.sub.2][Zn.sub.17]-type phase and intermetallic FeCo. Keywords: hydrogenation, disproportionation, desorption, recombination; samarium-cobalt alloys; two-phase ferromagnetic materials.</description><identifier>ISSN: 1068-1302</identifier><identifier>DOI: 10.1007/s11106-014-9622-2</identifier><language>eng</language><publisher>Springer</publisher><subject>Analysis ; Anisotropy ; Cobalt ; Diffraction ; Ferromagnetism ; Hydrogen ; Hydrogenation ; Intermetallic compounds ; Magnetic alloys ; Magnetization ; X-rays</subject><ispartof>Powder metallurgy and metal ceramics, 2014-09, Vol.53 (5-6), p.343</ispartof><rights>COPYRIGHT 2014 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Bulyk, I.I</creatorcontrib><creatorcontrib>Pilat, M.V</creatorcontrib><creatorcontrib>Lyutyy, P. Ya</creatorcontrib><title>Hydrogenation, disproportionation, desorption, and recombination in the [Sm.sub.2][Co.sub.17-x][Fe.sub.x]-[H.sub.2] system. x-ray diffraction</title><title>Powder metallurgy and metal ceramics</title><description>Differential thermal analysis and X-ray diffraction are used to study phase transitions in the [Sm.sub.2][Co.sub.17-x][Fe.sub.x]-[H.sub.2] system (x = 3.9 and 5.95) during conventional and solid HDDR at hydrogen pressure 0.57-4.0 MPa and temperature up to 950°C. The ferromagnetic phase with [Th.sub.2][Zn.sub.17] structure disproportionates into Sm[H.sub.2 ± ], cobalt, and intermetallic FeCo after one-hour interaction with hydrogen at 1.1 and 0.6MPa and 700°C with x = 3.9 and 5.95. Recombination in vacuum at 770-950°C leads to a two-phase alloy consisting of the [Th.sub.2][Zn.sub.17]-type phase and intermetallic FeCo. Keywords: hydrogenation, disproportionation, desorption, recombination; samarium-cobalt alloys; two-phase ferromagnetic materials.</description><subject>Analysis</subject><subject>Anisotropy</subject><subject>Cobalt</subject><subject>Diffraction</subject><subject>Ferromagnetism</subject><subject>Hydrogen</subject><subject>Hydrogenation</subject><subject>Intermetallic compounds</subject><subject>Magnetic alloys</subject><subject>Magnetization</subject><subject>X-rays</subject><issn>1068-1302</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqVjUtOxDAMhrMAieFxAHY5AAlJOupjiUaMuoddVaFM6wxB07iKi9QegjuTeXAA5IX___dnm7FHraRWqngmrbXKhdJrUeXGCHPFVikohc6UuWG3RF9KJXKtV-ynXvqIewh28hieeO9pjDhiPNq_DAjjeNY29DxCh8POn8fcBz59Am_eBknfO2naZoMnpQsxt80WTmZuRVNfAE4LTTBIPotol_TSuWi747F7du3sgeDh0u-Y3L6-b2qxtwf48MHhlMhUPQy-wwDOp_wlK8sqLyqTZ_9e-AWDWmFd</recordid><startdate>20140901</startdate><enddate>20140901</enddate><creator>Bulyk, I.I</creator><creator>Pilat, M.V</creator><creator>Lyutyy, P. Ya</creator><general>Springer</general><scope/></search><sort><creationdate>20140901</creationdate><title>Hydrogenation, disproportionation, desorption, and recombination in the [Sm.sub.2][Co.sub.17-x][Fe.sub.x]-[H.sub.2] system. x-ray diffraction</title><author>Bulyk, I.I ; Pilat, M.V ; Lyutyy, P. Ya</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-gale_infotracacademiconefile_A3889679263</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Analysis</topic><topic>Anisotropy</topic><topic>Cobalt</topic><topic>Diffraction</topic><topic>Ferromagnetism</topic><topic>Hydrogen</topic><topic>Hydrogenation</topic><topic>Intermetallic compounds</topic><topic>Magnetic alloys</topic><topic>Magnetization</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bulyk, I.I</creatorcontrib><creatorcontrib>Pilat, M.V</creatorcontrib><creatorcontrib>Lyutyy, P. Ya</creatorcontrib><jtitle>Powder metallurgy and metal ceramics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bulyk, I.I</au><au>Pilat, M.V</au><au>Lyutyy, P. Ya</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hydrogenation, disproportionation, desorption, and recombination in the [Sm.sub.2][Co.sub.17-x][Fe.sub.x]-[H.sub.2] system. x-ray diffraction</atitle><jtitle>Powder metallurgy and metal ceramics</jtitle><date>2014-09-01</date><risdate>2014</risdate><volume>53</volume><issue>5-6</issue><spage>343</spage><pages>343-</pages><issn>1068-1302</issn><abstract>Differential thermal analysis and X-ray diffraction are used to study phase transitions in the [Sm.sub.2][Co.sub.17-x][Fe.sub.x]-[H.sub.2] system (x = 3.9 and 5.95) during conventional and solid HDDR at hydrogen pressure 0.57-4.0 MPa and temperature up to 950°C. The ferromagnetic phase with [Th.sub.2][Zn.sub.17] structure disproportionates into Sm[H.sub.2 ± ], cobalt, and intermetallic FeCo after one-hour interaction with hydrogen at 1.1 and 0.6MPa and 700°C with x = 3.9 and 5.95. Recombination in vacuum at 770-950°C leads to a two-phase alloy consisting of the [Th.sub.2][Zn.sub.17]-type phase and intermetallic FeCo. Keywords: hydrogenation, disproportionation, desorption, recombination; samarium-cobalt alloys; two-phase ferromagnetic materials.</abstract><pub>Springer</pub><doi>10.1007/s11106-014-9622-2</doi></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1068-1302 |
| ispartof | Powder metallurgy and metal ceramics, 2014-09, Vol.53 (5-6), p.343 |
| issn | 1068-1302 |
| language | eng |
| recordid | cdi_gale_infotracacademiconefile_A388967926 |
| source | SpringerNature Journals |
| subjects | Analysis Anisotropy Cobalt Diffraction Ferromagnetism Hydrogen Hydrogenation Intermetallic compounds Magnetic alloys Magnetization X-rays |
| title | Hydrogenation, disproportionation, desorption, and recombination in the [Sm.sub.2][Co.sub.17-x][Fe.sub.x]-[H.sub.2] system. x-ray diffraction |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-04T05%3A18%3A57IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Hydrogenation,%20disproportionation,%20desorption,%20and%20recombination%20in%20the%20%5BSm.sub.2%5D%5BCo.sub.17-x%5D%5BFe.sub.x%5D-%5BH.sub.2%5D%20system.%20x-ray%20diffraction&rft.jtitle=Powder%20metallurgy%20and%20metal%20ceramics&rft.au=Bulyk,%20I.I&rft.date=2014-09-01&rft.volume=53&rft.issue=5-6&rft.spage=343&rft.pages=343-&rft.issn=1068-1302&rft_id=info:doi/10.1007/s11106-014-9622-2&rft_dat=%3Cgale%3EA388967926%3C/gale%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rft_galeid=A388967926&rfr_iscdi=true |