Generation of Hydrocarbons Having Adamantine Structure from Bacterial Biomass
The chloroform-insoluble part of chemoorganoheterotrophic aerobic bacteria Arthrobacter sp. RV and Pseudomonas aeruginosa RM is subjected to thermolysis and catalytic thermolysis (aluminosilicate as catalyst). The thermolysis and catalytic thermolysis products are analyzed by chromatomass spectrosco...
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| Veröffentlicht in: | Chemistry and technology of fuels and oils 2014-09, Vol.50 (4), p.290-298 |
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| container_title | Chemistry and technology of fuels and oils |
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| creator | Giruts, M. V. Gordadze, G. N. Stroeva, A. R. Stokolos, O. A. Bogatyrev, S. O. Koshelev, V. N. |
| description | The chloroform-insoluble part of chemoorganoheterotrophic aerobic bacteria Arthrobacter sp. RV and Pseudomonas aeruginosa RM is subjected to thermolysis and catalytic thermolysis (aluminosilicate as catalyst). The thermolysis and catalytic thermolysis products are analyzed by chromatomass spectroscopy. It is noticed for the first time that the products of thermolysis of the insoluble part contain hydrocarbons with typical ions of adamantanes (m/z 135, 136, 149, 163) and diamantanes (m/z 187, 188, 201). It is shown by isomerization over aluminum bromide that these hydrocarbons are protoadamantanes and protodiamantanes, respectively. Unlike thermolysis, catalytic thermolysis of the insoluble part of the bacteria generates simultaneously protoadamantanes and adamantanes of the C
10
–C
13
composition and protodiamantanes and diamantanes of the C
14
–C
16
composition. It is suggested that one of the routes of formation of hydrocarbons having diamond-like (adamantine) structure in oils could be catalytic transformation of the bacterial biomass. |
| doi_str_mv | 10.1007/s10553-014-0526-0 |
| format | Article |
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10
–C
13
composition and protodiamantanes and diamantanes of the C
14
–C
16
composition. It is suggested that one of the routes of formation of hydrocarbons having diamond-like (adamantine) structure in oils could be catalytic transformation of the bacterial biomass.</description><identifier>ISSN: 0009-3092</identifier><identifier>EISSN: 1573-8310</identifier><identifier>DOI: 10.1007/s10553-014-0526-0</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Bacteria ; Chemistry ; Chemistry and Materials Science ; Geotechnical Engineering & Applied Earth Sciences ; Industrial Chemistry/Chemical Engineering ; Isomerization ; Mineral Resources ; Pyrolysis</subject><ispartof>Chemistry and technology of fuels and oils, 2014-09, Vol.50 (4), p.290-298</ispartof><rights>Springer Science+Business Media New York 2014</rights><rights>COPYRIGHT 2014 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c434t-5f84db8cee857b9946ec08f6292e17cfa2abe2d7b7bad708dfc064d3bad68a423</citedby><cites>FETCH-LOGICAL-c434t-5f84db8cee857b9946ec08f6292e17cfa2abe2d7b7bad708dfc064d3bad68a423</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10553-014-0526-0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10553-014-0526-0$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Giruts, M. V.</creatorcontrib><creatorcontrib>Gordadze, G. N.</creatorcontrib><creatorcontrib>Stroeva, A. R.</creatorcontrib><creatorcontrib>Stokolos, O. A.</creatorcontrib><creatorcontrib>Bogatyrev, S. O.</creatorcontrib><creatorcontrib>Koshelev, V. N.</creatorcontrib><title>Generation of Hydrocarbons Having Adamantine Structure from Bacterial Biomass</title><title>Chemistry and technology of fuels and oils</title><addtitle>Chem Technol Fuels Oils</addtitle><description>The chloroform-insoluble part of chemoorganoheterotrophic aerobic bacteria Arthrobacter sp. RV and Pseudomonas aeruginosa RM is subjected to thermolysis and catalytic thermolysis (aluminosilicate as catalyst). The thermolysis and catalytic thermolysis products are analyzed by chromatomass spectroscopy. It is noticed for the first time that the products of thermolysis of the insoluble part contain hydrocarbons with typical ions of adamantanes (m/z 135, 136, 149, 163) and diamantanes (m/z 187, 188, 201). It is shown by isomerization over aluminum bromide that these hydrocarbons are protoadamantanes and protodiamantanes, respectively. Unlike thermolysis, catalytic thermolysis of the insoluble part of the bacteria generates simultaneously protoadamantanes and adamantanes of the C
10
–C
13
composition and protodiamantanes and diamantanes of the C
14
–C
16
composition. It is suggested that one of the routes of formation of hydrocarbons having diamond-like (adamantine) structure in oils could be catalytic transformation of the bacterial biomass.</description><subject>Bacteria</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Geotechnical Engineering & Applied Earth Sciences</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Isomerization</subject><subject>Mineral Resources</subject><subject>Pyrolysis</subject><issn>0009-3092</issn><issn>1573-8310</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp9kM9KAzEQh4MoWKsP4C0vsHWS7G6SY1u0FSoe1HPI5k9J6SaSbIW-vVvWs8xh-A3zDcyH0COBBQHgT4VA07AKSF1BQ9sKrtCMNJxVghG4RjMAkBUDSW_RXSmHS-SUzdDbxkWX9RBSxMnj7dnmZHTuUix4q39C3OOl1b2OQ4gOfwz5ZIZTdtjn1OOVNoPLQR_xKqRel3KPbrw-Fvfw1-fo6-X5c72tdu-b1_VyV5ma1UPVeFHbThjnRMM7KevWGRC-pZI6wo3XVHeOWt7xTlsOwnoDbW3ZmFqha8rmaDHd3eujUyH6NGRtxrKuDyZF58M4XzLRSClbdgHIBJicSsnOq-8cep3PioC6CFSTQDUKVBeBCkaGTkwZd-PeZXVIpxzHv_6BfgF5tXR8</recordid><startdate>20140901</startdate><enddate>20140901</enddate><creator>Giruts, M. V.</creator><creator>Gordadze, G. N.</creator><creator>Stroeva, A. R.</creator><creator>Stokolos, O. A.</creator><creator>Bogatyrev, S. O.</creator><creator>Koshelev, V. N.</creator><general>Springer US</general><general>Springer</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20140901</creationdate><title>Generation of Hydrocarbons Having Adamantine Structure from Bacterial Biomass</title><author>Giruts, M. V. ; Gordadze, G. N. ; Stroeva, A. R. ; Stokolos, O. A. ; Bogatyrev, S. O. ; Koshelev, V. N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c434t-5f84db8cee857b9946ec08f6292e17cfa2abe2d7b7bad708dfc064d3bad68a423</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Bacteria</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Geotechnical Engineering & Applied Earth Sciences</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Isomerization</topic><topic>Mineral Resources</topic><topic>Pyrolysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Giruts, M. V.</creatorcontrib><creatorcontrib>Gordadze, G. N.</creatorcontrib><creatorcontrib>Stroeva, A. R.</creatorcontrib><creatorcontrib>Stokolos, O. A.</creatorcontrib><creatorcontrib>Bogatyrev, S. O.</creatorcontrib><creatorcontrib>Koshelev, V. N.</creatorcontrib><collection>CrossRef</collection><jtitle>Chemistry and technology of fuels and oils</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Giruts, M. V.</au><au>Gordadze, G. N.</au><au>Stroeva, A. R.</au><au>Stokolos, O. A.</au><au>Bogatyrev, S. O.</au><au>Koshelev, V. N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Generation of Hydrocarbons Having Adamantine Structure from Bacterial Biomass</atitle><jtitle>Chemistry and technology of fuels and oils</jtitle><stitle>Chem Technol Fuels Oils</stitle><date>2014-09-01</date><risdate>2014</risdate><volume>50</volume><issue>4</issue><spage>290</spage><epage>298</epage><pages>290-298</pages><issn>0009-3092</issn><eissn>1573-8310</eissn><abstract>The chloroform-insoluble part of chemoorganoheterotrophic aerobic bacteria Arthrobacter sp. RV and Pseudomonas aeruginosa RM is subjected to thermolysis and catalytic thermolysis (aluminosilicate as catalyst). The thermolysis and catalytic thermolysis products are analyzed by chromatomass spectroscopy. It is noticed for the first time that the products of thermolysis of the insoluble part contain hydrocarbons with typical ions of adamantanes (m/z 135, 136, 149, 163) and diamantanes (m/z 187, 188, 201). It is shown by isomerization over aluminum bromide that these hydrocarbons are protoadamantanes and protodiamantanes, respectively. Unlike thermolysis, catalytic thermolysis of the insoluble part of the bacteria generates simultaneously protoadamantanes and adamantanes of the C
10
–C
13
composition and protodiamantanes and diamantanes of the C
14
–C
16
composition. It is suggested that one of the routes of formation of hydrocarbons having diamond-like (adamantine) structure in oils could be catalytic transformation of the bacterial biomass.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s10553-014-0526-0</doi><tpages>9</tpages></addata></record> |
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| subjects | Bacteria Chemistry Chemistry and Materials Science Geotechnical Engineering & Applied Earth Sciences Industrial Chemistry/Chemical Engineering Isomerization Mineral Resources Pyrolysis |
| title | Generation of Hydrocarbons Having Adamantine Structure from Bacterial Biomass |
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