The mathematical incorrectness of the integral isoconversional methods in case of variable activation energy and the consequences

Kinetic parameters resulting from the application of isoconversional methods mostly depend on the degree of conversion. This paper shows that the integral isoconversional methods are mathematically incorrect if the activation energy depends on conversion. In this case, the incorrectness resides in i...

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Veröffentlicht in:	Journal of thermal analysis and calorimetry 2014, Vol.115 (1), p.853-859
Hauptverfasser:	Šimon, Peter, Thomas, Paul, Dubaj, Tibor, Cibulková, Zuzana, Peller, András, Veverka, Miroslav
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation energy Analysis Analytical Chemistry Chemistry Chemistry and Materials Science Inorganic Chemistry Measurement Science and Instrumentation Methods Physical Chemistry Polymer Sciences
Online-Zugang:	Volltext
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