Protonation/reduction dynamics at the [4Fe–4S] cluster of the hydrogen-forming cofactor in [FeFe]-hydrogenases

The [FeFe]-hydrogenases of bacteria and algae are the most efficient hydrogen conversion catalysts in nature. Their active-site cofactor (H-cluster) comprises a [4Fe–4S] cluster linked to a unique diiron site that binds three carbon monoxide (CO) and two cyanide (CN−) ligands. Understanding microbia...

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Hauptverfasser:	Senger, M, Mebs, S, Duan, J, Shulenina, O, Laun, K, Kertess, L, Wittkamp, F, Apfel, U.-P, Happe, T, Winkler, M, Haumann, M, Stripp, S.T
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Sprache:	eng
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