Carbon dioxide photolysis from 150 to 210 nm: Singlet and triplet channel dynamics, UV-spectrum, and isotope effects

We present a first principles study of the carbon dioxide (CO ₂) photodissociation process in the 150- to 210-nm wavelength range, with emphasis on photolysis below the carbon monoxide + [Formula] singlet channel threshold at ∼167 nm. The calculations reproduce experimental absorption cross-sections...

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