Modification of the Benoit model for beta 1-4 glucans

The Benoit model for beta 1-4 glucans is considered taking into account intrachain hydrogen bonds. This model is basis for calculation of equilibrium rigidity of chains with completely free rotation. Analysis of the experimental value of equilibrium rigidity is carried out and the fraction of hinge...

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Veröffentlicht in:Carbohydrate polymers 1998-12, Vol.37 (4), p.415-418
1. Verfasser: Pavlov, G.M
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container_title Carbohydrate polymers
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creator Pavlov, G.M
description The Benoit model for beta 1-4 glucans is considered taking into account intrachain hydrogen bonds. This model is basis for calculation of equilibrium rigidity of chains with completely free rotation. Analysis of the experimental value of equilibrium rigidity is carried out and the fraction of hinge C(1)OC(4) bonds about which rotation is free is evaluated.
doi_str_mv 10.1016/S0144-8617(98)00043-5
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language eng
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source Elsevier ScienceDirect Journals Complete
subjects beta-glucans
equilibrium
hydrogen bonding
molecular conformation
molecular rotation
rigid chain polymers
title Modification of the Benoit model for beta 1-4 glucans
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