Ion Exchange of H , Na , Mg2 , Ca2 , Mn2 , and Ba2 on Wood Pulp
Ion exchange selectivity coefficients were measured for the partition of metals between solution and pulp fibers. The method accurately models the ion exchange isotherms for all cation pairs evaluated and is accurate up to approximately 0.05 molar concentrations. Selectivity coefficients were determ...
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| Veröffentlicht in: | Journal of wood chemistry and technology 2006-09, Vol.26 (3), p.259-272 |
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| container_title | Journal of wood chemistry and technology |
| container_volume | 26 |
| creator | Rudie, A.W Ball, A Patel, N |
| description | Ion exchange selectivity coefficients were measured for the partition of metals between solution and pulp fibers. The method accurately models the ion exchange isotherms for all cation pairs evaluated and is accurate up to approximately 0.05 molar concentrations. Selectivity coefficients were determined for calcium and magnesium with each other and with hydrogen, sodium, manganese, and barium. Measurements made at 25°, 50°, and 65°C were used to determine the enthalpy and entropy of the reactions. The data follow the expected linear free-energy relationship. These results can be used to estimate the ion exchange selectivity coefficients for any temperature within the experimental range. |
| doi_str_mv | 10.1080/02773810601023503 |
| format | Article |
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The method accurately models the ion exchange isotherms for all cation pairs evaluated and is accurate up to approximately 0.05 molar concentrations. Selectivity coefficients were determined for calcium and magnesium with each other and with hydrogen, sodium, manganese, and barium. Measurements made at 25°, 50°, and 65°C were used to determine the enthalpy and entropy of the reactions. The data follow the expected linear free-energy relationship. These results can be used to estimate the ion exchange selectivity coefficients for any temperature within the experimental range.</description><identifier>ISSN: 0277-3813</identifier><identifier>EISSN: 1532-2319</identifier><identifier>DOI: 10.1080/02773810601023503</identifier><identifier>CODEN: JWCTDJ</identifier><language>eng</language><publisher>Colchester: Taylor & Francis Group</publisher><subject>Applied sciences ; barium ; bleaching ; calcium ; cations ; chemical bonding ; divalent cations ; Exact sciences and technology ; hydrogen ; ion exchange ; ion exchange selectivity coefficients ; ions ; magnesium ; manganese ; metals ; monovalent cations ; Paper, paperboard, non wovens ; pine ; Polymer industry, paints, wood ; processing technology ; pulp and paper technology ; pulp fiber ; Pulp manufacturing ; selectivity coefficients ; sodium ; solutions ; Wood fiber ; wood pulp ; wood technology ; Wood. Paper. Non wovens</subject><ispartof>Journal of wood chemistry and technology, 2006-09, Vol.26 (3), p.259-272</ispartof><rights>Copyright Taylor & Francis Group, LLC 2006</rights><rights>2008 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.tandfonline.com/doi/pdf/10.1080/02773810601023503$$EPDF$$P50$$Ginformaworld$$H</linktopdf><linktohtml>$$Uhttps://www.tandfonline.com/doi/full/10.1080/02773810601023503$$EHTML$$P50$$Ginformaworld$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,59620,60409</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=18346570$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Rudie, A.W</creatorcontrib><creatorcontrib>Ball, A</creatorcontrib><creatorcontrib>Patel, N</creatorcontrib><title>Ion Exchange of H , Na , Mg2 , Ca2 , Mn2 , and Ba2 on Wood Pulp</title><title>Journal of wood chemistry and technology</title><description>Ion exchange selectivity coefficients were measured for the partition of metals between solution and pulp fibers. The method accurately models the ion exchange isotherms for all cation pairs evaluated and is accurate up to approximately 0.05 molar concentrations. Selectivity coefficients were determined for calcium and magnesium with each other and with hydrogen, sodium, manganese, and barium. Measurements made at 25°, 50°, and 65°C were used to determine the enthalpy and entropy of the reactions. The data follow the expected linear free-energy relationship. These results can be used to estimate the ion exchange selectivity coefficients for any temperature within the experimental range.</description><subject>Applied sciences</subject><subject>barium</subject><subject>bleaching</subject><subject>calcium</subject><subject>cations</subject><subject>chemical bonding</subject><subject>divalent cations</subject><subject>Exact sciences and technology</subject><subject>hydrogen</subject><subject>ion exchange</subject><subject>ion exchange selectivity coefficients</subject><subject>ions</subject><subject>magnesium</subject><subject>manganese</subject><subject>metals</subject><subject>monovalent cations</subject><subject>Paper, paperboard, non wovens</subject><subject>pine</subject><subject>Polymer industry, paints, wood</subject><subject>processing technology</subject><subject>pulp and paper technology</subject><subject>pulp fiber</subject><subject>Pulp manufacturing</subject><subject>selectivity coefficients</subject><subject>sodium</subject><subject>solutions</subject><subject>Wood fiber</subject><subject>wood pulp</subject><subject>wood technology</subject><subject>Wood. Paper. Non wovens</subject><issn>0277-3813</issn><issn>1532-2319</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNqFkVFLwzAQx4MoOKcfwCf7Ir5YveTapgFBdEwnbCro8DGkTTorXTObDrdvb8rm0x58-R9Hfr_jyBFySuGKQgrXwDjHlEICFBjGgHukR2NkIUMq9kmvew89gIfkyLkvACo4xR65fbJ1MFzln6qemcAWwSi4DJ6Vj8mM-RyoLid1l6rWwb3vvfFhrQ5el9XimBwUqnLmZFv7ZPowfB-MwvHL49PgbhwWjLM2zBMdxTphQudCCUhZokwUC66F8MtmmUHkicl4HjG_WOJrZBhqI2gGaVQw7JOLzdxFY7-XxrVyXrrcVJWqjV06yeOYIqKIPHm-JZXLVVU0qs5LJxdNOVfNWtIUoyTm4Dm-4cq6sM1c_dim0rJV68o2f9LOr8p21Xrz5l8TKcjuMLsjvH620QtlpZo1np6-MaAIwNMIEfAX4QOBdQ</recordid><startdate>20060901</startdate><enddate>20060901</enddate><creator>Rudie, A.W</creator><creator>Ball, A</creator><creator>Patel, N</creator><general>Taylor & Francis Group</general><general>Taylor & Francis</general><scope>FBQ</scope><scope>IQODW</scope><scope>7QP</scope><scope>7QR</scope><scope>8FD</scope><scope>FR3</scope><scope>P64</scope></search><sort><creationdate>20060901</creationdate><title>Ion Exchange of H , Na , Mg2 , Ca2 , Mn2 , and Ba2 on Wood Pulp</title><author>Rudie, A.W ; Ball, A ; Patel, N</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-f272t-c6d45d629dc9a90826ae4597d99350bbe3376eb7c4219767c44e23de91b084f23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Applied sciences</topic><topic>barium</topic><topic>bleaching</topic><topic>calcium</topic><topic>cations</topic><topic>chemical bonding</topic><topic>divalent cations</topic><topic>Exact sciences and technology</topic><topic>hydrogen</topic><topic>ion exchange</topic><topic>ion exchange selectivity coefficients</topic><topic>ions</topic><topic>magnesium</topic><topic>manganese</topic><topic>metals</topic><topic>monovalent cations</topic><topic>Paper, paperboard, non wovens</topic><topic>pine</topic><topic>Polymer industry, paints, wood</topic><topic>processing technology</topic><topic>pulp and paper technology</topic><topic>pulp fiber</topic><topic>Pulp manufacturing</topic><topic>selectivity coefficients</topic><topic>sodium</topic><topic>solutions</topic><topic>Wood fiber</topic><topic>wood pulp</topic><topic>wood technology</topic><topic>Wood. Paper. Non wovens</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rudie, A.W</creatorcontrib><creatorcontrib>Ball, A</creatorcontrib><creatorcontrib>Patel, N</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>Calcium & Calcified Tissue Abstracts</collection><collection>Chemoreception Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Journal of wood chemistry and technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rudie, A.W</au><au>Ball, A</au><au>Patel, N</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ion Exchange of H , Na , Mg2 , Ca2 , Mn2 , and Ba2 on Wood Pulp</atitle><jtitle>Journal of wood chemistry and technology</jtitle><date>2006-09-01</date><risdate>2006</risdate><volume>26</volume><issue>3</issue><spage>259</spage><epage>272</epage><pages>259-272</pages><issn>0277-3813</issn><eissn>1532-2319</eissn><coden>JWCTDJ</coden><abstract>Ion exchange selectivity coefficients were measured for the partition of metals between solution and pulp fibers. The method accurately models the ion exchange isotherms for all cation pairs evaluated and is accurate up to approximately 0.05 molar concentrations. Selectivity coefficients were determined for calcium and magnesium with each other and with hydrogen, sodium, manganese, and barium. Measurements made at 25°, 50°, and 65°C were used to determine the enthalpy and entropy of the reactions. The data follow the expected linear free-energy relationship. These results can be used to estimate the ion exchange selectivity coefficients for any temperature within the experimental range.</abstract><cop>Colchester</cop><pub>Taylor & Francis Group</pub><doi>10.1080/02773810601023503</doi><tpages>14</tpages></addata></record> |
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| identifier | ISSN: 0277-3813 |
| ispartof | Journal of wood chemistry and technology, 2006-09, Vol.26 (3), p.259-272 |
| issn | 0277-3813 1532-2319 |
| language | eng |
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| source | Taylor & Francis Journals Complete |
| subjects | Applied sciences barium bleaching calcium cations chemical bonding divalent cations Exact sciences and technology hydrogen ion exchange ion exchange selectivity coefficients ions magnesium manganese metals monovalent cations Paper, paperboard, non wovens pine Polymer industry, paints, wood processing technology pulp and paper technology pulp fiber Pulp manufacturing selectivity coefficients sodium solutions Wood fiber wood pulp wood technology Wood. Paper. Non wovens |
| title | Ion Exchange of H , Na , Mg2 , Ca2 , Mn2 , and Ba2 on Wood Pulp |
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