Methods for the determination of arsenic, cadmium, copper, lead, and tin in sucrose, corn syrup, and high-fructose corn syrups by inductively coupled plasma atomic emission spectrometry
This paper demonstrates the determination of arsenic, cadmium, copper, lead, and tin in sucrose, corn syrups, and high-fructose corn syrups by inductively coupled plasma atomic emission spectrometry (ICP-AES). Sample digestion by both open vessel/hot plate and closed vessel/microwave techniques is r...
Gespeichert in:
| Veröffentlicht in: | Journal of agricultural and food chemistry 1997-01, Vol.45 (1) |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | 1 |
| container_start_page | |
| container_title | Journal of agricultural and food chemistry |
| container_volume | 45 |
| creator | Allen, L.B Siitonen, P.H Thompson, H.C. Jr |
| description | This paper demonstrates the determination of arsenic, cadmium, copper, lead, and tin in sucrose, corn syrups, and high-fructose corn syrups by inductively coupled plasma atomic emission spectrometry (ICP-AES). Sample digestion by both open vessel/hot plate and closed vessel/microwave techniques is reported. Open vessel digestion was suitable for the simultaneous determination of cadmium, copper, and lead. Average recoveries (five different sample types) for the open vessel procedure were 98%, 88%, and 93% for cadmium, copper, and lead, respectively, at 0.10 microgram/g. In contrast, microwave digestion yielded average recoveries (five different sample types) of 92%, 83%, 89%, 85%, and 88%, respectively, for arsenic, cadmium, copper, lead, and tin at 1.0 microgram/g. Method detection limits were lower with open vessel digestion versus microwave digestion because of sample volume reduction. Sample introduction included microporous membrane desolvation, which assisted digestion and matrix normalization |
| format | Article |
| fullrecord | <record><control><sourceid>fao</sourceid><recordid>TN_cdi_fao_agris_US1997062828</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>US1997062828</sourcerecordid><originalsourceid>FETCH-fao_agris_US19970628283</originalsourceid><addsrcrecordid>eNqFzs1KxDAQB_AgCtaPRxDmAVpIKt3tnkXx4kk9L7PJdBtpmjCTCn00384sevAmDMz8-c3AnKnKdK1uOmP6c1Vp3Zqm7zbmUl2JfGit-26rK_X1QnmMTmCIDHkkcJSJg58x-zhDHABZaPa2Bosu-CWUIaZEXMNE6GrA2UH2M5SSxXIUOm1wSSsv6cdHfxybgRebC_9RgcNaDl0B_0nTWmhJEzlIE0pAwByDt0DBi5zekUQ2cwyUeb1RFwNOQre__VrdPT2-PTw3A8Y9HtnL_v3V7HZbvWn7tr__z78BXRphrQ</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Methods for the determination of arsenic, cadmium, copper, lead, and tin in sucrose, corn syrup, and high-fructose corn syrups by inductively coupled plasma atomic emission spectrometry</title><source>ACS Journals: American Chemical Society Web Editions</source><creator>Allen, L.B ; Siitonen, P.H ; Thompson, H.C. Jr</creator><creatorcontrib>Allen, L.B ; Siitonen, P.H ; Thompson, H.C. Jr</creatorcontrib><description>This paper demonstrates the determination of arsenic, cadmium, copper, lead, and tin in sucrose, corn syrups, and high-fructose corn syrups by inductively coupled plasma atomic emission spectrometry (ICP-AES). Sample digestion by both open vessel/hot plate and closed vessel/microwave techniques is reported. Open vessel digestion was suitable for the simultaneous determination of cadmium, copper, and lead. Average recoveries (five different sample types) for the open vessel procedure were 98%, 88%, and 93% for cadmium, copper, and lead, respectively, at 0.10 microgram/g. In contrast, microwave digestion yielded average recoveries (five different sample types) of 92%, 83%, 89%, 85%, and 88%, respectively, for arsenic, cadmium, copper, lead, and tin at 1.0 microgram/g. Method detection limits were lower with open vessel digestion versus microwave digestion because of sample volume reduction. Sample introduction included microporous membrane desolvation, which assisted digestion and matrix normalization</description><identifier>ISSN: 0021-8561</identifier><identifier>EISSN: 1520-5118</identifier><language>eng</language><subject>ALIMENTOS ; ARSENIC ; ARSENICO ; CADMIO ; CADMIUM ; COBRE ; COPPER ; CUIVRE ; EDULCORANT ; EDULCORANTES ; ESPECTROMETRIA ; ESTANO ; ETAIN ; FOOD ANALYSIS ; FOODS ; GLUCOSE SYRUPS ; HIGH FRUCTOSE CORN SYRUP ; ISOGLUCOSA ; ISOGLUCOSE ; JARABE DE GLUCOSA ; LEAD ; MICROWAVE TREATMENT ; PLASMA EMISSION SPECTROSCOPY ; PLOMB ; PLOMO ; PRODUIT ALIMENTAIRE ; SACCHAROSE ; SIROP DE GLUCOSE ; SPECTROMETRIE ; SPECTROMETRY ; SUCROSA ; SUCROSE ; SWEETENERS ; TIN ; TRAITEMENT AUX MICROONDES ; TRATAMIENTO POR MICROONDAS</subject><ispartof>Journal of agricultural and food chemistry, 1997-01, Vol.45 (1)</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780</link.rule.ids></links><search><creatorcontrib>Allen, L.B</creatorcontrib><creatorcontrib>Siitonen, P.H</creatorcontrib><creatorcontrib>Thompson, H.C. Jr</creatorcontrib><title>Methods for the determination of arsenic, cadmium, copper, lead, and tin in sucrose, corn syrup, and high-fructose corn syrups by inductively coupled plasma atomic emission spectrometry</title><title>Journal of agricultural and food chemistry</title><description>This paper demonstrates the determination of arsenic, cadmium, copper, lead, and tin in sucrose, corn syrups, and high-fructose corn syrups by inductively coupled plasma atomic emission spectrometry (ICP-AES). Sample digestion by both open vessel/hot plate and closed vessel/microwave techniques is reported. Open vessel digestion was suitable for the simultaneous determination of cadmium, copper, and lead. Average recoveries (five different sample types) for the open vessel procedure were 98%, 88%, and 93% for cadmium, copper, and lead, respectively, at 0.10 microgram/g. In contrast, microwave digestion yielded average recoveries (five different sample types) of 92%, 83%, 89%, 85%, and 88%, respectively, for arsenic, cadmium, copper, lead, and tin at 1.0 microgram/g. Method detection limits were lower with open vessel digestion versus microwave digestion because of sample volume reduction. Sample introduction included microporous membrane desolvation, which assisted digestion and matrix normalization</description><subject>ALIMENTOS</subject><subject>ARSENIC</subject><subject>ARSENICO</subject><subject>CADMIO</subject><subject>CADMIUM</subject><subject>COBRE</subject><subject>COPPER</subject><subject>CUIVRE</subject><subject>EDULCORANT</subject><subject>EDULCORANTES</subject><subject>ESPECTROMETRIA</subject><subject>ESTANO</subject><subject>ETAIN</subject><subject>FOOD ANALYSIS</subject><subject>FOODS</subject><subject>GLUCOSE SYRUPS</subject><subject>HIGH FRUCTOSE CORN SYRUP</subject><subject>ISOGLUCOSA</subject><subject>ISOGLUCOSE</subject><subject>JARABE DE GLUCOSA</subject><subject>LEAD</subject><subject>MICROWAVE TREATMENT</subject><subject>PLASMA EMISSION SPECTROSCOPY</subject><subject>PLOMB</subject><subject>PLOMO</subject><subject>PRODUIT ALIMENTAIRE</subject><subject>SACCHAROSE</subject><subject>SIROP DE GLUCOSE</subject><subject>SPECTROMETRIE</subject><subject>SPECTROMETRY</subject><subject>SUCROSA</subject><subject>SUCROSE</subject><subject>SWEETENERS</subject><subject>TIN</subject><subject>TRAITEMENT AUX MICROONDES</subject><subject>TRATAMIENTO POR MICROONDAS</subject><issn>0021-8561</issn><issn>1520-5118</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1997</creationdate><recordtype>article</recordtype><recordid>eNqFzs1KxDAQB_AgCtaPRxDmAVpIKt3tnkXx4kk9L7PJdBtpmjCTCn00384sevAmDMz8-c3AnKnKdK1uOmP6c1Vp3Zqm7zbmUl2JfGit-26rK_X1QnmMTmCIDHkkcJSJg58x-zhDHABZaPa2Bosu-CWUIaZEXMNE6GrA2UH2M5SSxXIUOm1wSSsv6cdHfxybgRebC_9RgcNaDl0B_0nTWmhJEzlIE0pAwByDt0DBi5zekUQ2cwyUeb1RFwNOQre__VrdPT2-PTw3A8Y9HtnL_v3V7HZbvWn7tr__z78BXRphrQ</recordid><startdate>199701</startdate><enddate>199701</enddate><creator>Allen, L.B</creator><creator>Siitonen, P.H</creator><creator>Thompson, H.C. Jr</creator><scope>FBQ</scope></search><sort><creationdate>199701</creationdate><title>Methods for the determination of arsenic, cadmium, copper, lead, and tin in sucrose, corn syrup, and high-fructose corn syrups by inductively coupled plasma atomic emission spectrometry</title><author>Allen, L.B ; Siitonen, P.H ; Thompson, H.C. Jr</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-fao_agris_US19970628283</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1997</creationdate><topic>ALIMENTOS</topic><topic>ARSENIC</topic><topic>ARSENICO</topic><topic>CADMIO</topic><topic>CADMIUM</topic><topic>COBRE</topic><topic>COPPER</topic><topic>CUIVRE</topic><topic>EDULCORANT</topic><topic>EDULCORANTES</topic><topic>ESPECTROMETRIA</topic><topic>ESTANO</topic><topic>ETAIN</topic><topic>FOOD ANALYSIS</topic><topic>FOODS</topic><topic>GLUCOSE SYRUPS</topic><topic>HIGH FRUCTOSE CORN SYRUP</topic><topic>ISOGLUCOSA</topic><topic>ISOGLUCOSE</topic><topic>JARABE DE GLUCOSA</topic><topic>LEAD</topic><topic>MICROWAVE TREATMENT</topic><topic>PLASMA EMISSION SPECTROSCOPY</topic><topic>PLOMB</topic><topic>PLOMO</topic><topic>PRODUIT ALIMENTAIRE</topic><topic>SACCHAROSE</topic><topic>SIROP DE GLUCOSE</topic><topic>SPECTROMETRIE</topic><topic>SPECTROMETRY</topic><topic>SUCROSA</topic><topic>SUCROSE</topic><topic>SWEETENERS</topic><topic>TIN</topic><topic>TRAITEMENT AUX MICROONDES</topic><topic>TRATAMIENTO POR MICROONDAS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Allen, L.B</creatorcontrib><creatorcontrib>Siitonen, P.H</creatorcontrib><creatorcontrib>Thompson, H.C. Jr</creatorcontrib><collection>AGRIS</collection><jtitle>Journal of agricultural and food chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Allen, L.B</au><au>Siitonen, P.H</au><au>Thompson, H.C. Jr</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Methods for the determination of arsenic, cadmium, copper, lead, and tin in sucrose, corn syrup, and high-fructose corn syrups by inductively coupled plasma atomic emission spectrometry</atitle><jtitle>Journal of agricultural and food chemistry</jtitle><date>1997-01</date><risdate>1997</risdate><volume>45</volume><issue>1</issue><issn>0021-8561</issn><eissn>1520-5118</eissn><abstract>This paper demonstrates the determination of arsenic, cadmium, copper, lead, and tin in sucrose, corn syrups, and high-fructose corn syrups by inductively coupled plasma atomic emission spectrometry (ICP-AES). Sample digestion by both open vessel/hot plate and closed vessel/microwave techniques is reported. Open vessel digestion was suitable for the simultaneous determination of cadmium, copper, and lead. Average recoveries (five different sample types) for the open vessel procedure were 98%, 88%, and 93% for cadmium, copper, and lead, respectively, at 0.10 microgram/g. In contrast, microwave digestion yielded average recoveries (five different sample types) of 92%, 83%, 89%, 85%, and 88%, respectively, for arsenic, cadmium, copper, lead, and tin at 1.0 microgram/g. Method detection limits were lower with open vessel digestion versus microwave digestion because of sample volume reduction. Sample introduction included microporous membrane desolvation, which assisted digestion and matrix normalization</abstract></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-8561 |
| ispartof | Journal of agricultural and food chemistry, 1997-01, Vol.45 (1) |
| issn | 0021-8561 1520-5118 |
| language | eng |
| recordid | cdi_fao_agris_US1997062828 |
| source | ACS Journals: American Chemical Society Web Editions |
| subjects | ALIMENTOS ARSENIC ARSENICO CADMIO CADMIUM COBRE COPPER CUIVRE EDULCORANT EDULCORANTES ESPECTROMETRIA ESTANO ETAIN FOOD ANALYSIS FOODS GLUCOSE SYRUPS HIGH FRUCTOSE CORN SYRUP ISOGLUCOSA ISOGLUCOSE JARABE DE GLUCOSA LEAD MICROWAVE TREATMENT PLASMA EMISSION SPECTROSCOPY PLOMB PLOMO PRODUIT ALIMENTAIRE SACCHAROSE SIROP DE GLUCOSE SPECTROMETRIE SPECTROMETRY SUCROSA SUCROSE SWEETENERS TIN TRAITEMENT AUX MICROONDES TRATAMIENTO POR MICROONDAS |
| title | Methods for the determination of arsenic, cadmium, copper, lead, and tin in sucrose, corn syrup, and high-fructose corn syrups by inductively coupled plasma atomic emission spectrometry |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-01T11%3A36%3A11IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-fao&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Methods%20for%20the%20determination%20of%20arsenic,%20cadmium,%20copper,%20lead,%20and%20tin%20in%20sucrose,%20corn%20syrup,%20and%20high-fructose%20corn%20syrups%20by%20inductively%20coupled%20plasma%20atomic%20emission%20spectrometry&rft.jtitle=Journal%20of%20agricultural%20and%20food%20chemistry&rft.au=Allen,%20L.B&rft.date=1997-01&rft.volume=45&rft.issue=1&rft.issn=0021-8561&rft.eissn=1520-5118&rft_id=info:doi/&rft_dat=%3Cfao%3EUS1997062828%3C/fao%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |