Process for the synthesis of 1,3-diols

An improved process for the preparation of cis-1,3-diols is described where a beta hydroxy ketone is treated with a trialkylborane or dialkylalkoxyborane or a mixture of a trialkylborane and a dialkylalkoxyborane followed by recovery and reuse of the alkylborane species to convert additional beta hy...

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Hauptverfasser: THOMAS NORMAN NANNINGA, RICHARD JOSEPH MC CABE, ROBERT LEE BOSCH, ROBERT JOSEPH STAHL
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creator THOMAS NORMAN NANNINGA
RICHARD JOSEPH MC CABE
ROBERT LEE BOSCH
ROBERT JOSEPH STAHL
description An improved process for the preparation of cis-1,3-diols is described where a beta hydroxy ketone is treated with a trialkylborane or dialkylalkoxyborane or a mixture of a trialkylborane and a dialkylalkoxyborane followed by recovery and reuse of the alkylborane species to convert additional beta hydroxy ketone to the cis-1,3-diol.
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
APPARATUS THEREFOR
CHEMISTRY
GENERAL METHODS OF ORGANIC CHEMISTRY
HETEROCYCLIC COMPOUNDS
METALLURGY
ORGANIC CHEMISTRY
title Process for the synthesis of 1,3-diols
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