CATALYST PRECURSOR COMPOSITION, AND METHOD OF MAKING THE SAME

A catalyst precursor composition comprises the reaction product of a cation exchange resin containing trityl carbonium ions contacted with a metallocene. The process of producing the reaction product of a cation exchange resin containing trityl carbonium ions contacted with a metallocene comprises:...

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Hauptverfasser: FURTEK, ALLAN, BRENT, KRAUSE, MICHAEL, JOSEPH
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KRAUSE, MICHAEL, JOSEPH
description A catalyst precursor composition comprises the reaction product of a cation exchange resin containing trityl carbonium ions contacted with a metallocene. The process of producing the reaction product of a cation exchange resin containing trityl carbonium ions contacted with a metallocene comprises: (1) providing a cation exchange resin which has cations, (2) contacting the cation exchange resin with a solution comprising a trityl halide complex and solvent therefor to form an intermediate; and (3) contacting the intermediate with a metallocene, preferably a zirconocene salt. The resulting composition can be used to form ethylene resins in an alumoxane free system. Une composition de précurseur de catalyseur comprend le produit de réaction d'une résine échangeuse de cations contenant des ions trityle carbonium en contact avec un métallocène. Le procédé d'obtention de ce produit de la réaction d'une résine échangeuse de cations contenant des ions trityle carbonium avec un métallocène consiste à: (1) fournir une résine échangeuse de cations ayant des cations, (2) mettre en contact la résine échangeuse de cations avec une solution contenant un complexe d'halogénure de trityle et un solvant pour former un intermédiaire; et (3) mettre en contact l'intermédiaire avec un métallocène, de préférence un sel de zirconocène. La composition résultante peut être utilisée pour produire les résines éthyléniques dans un système exempt d'alumoxane.
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The process of producing the reaction product of a cation exchange resin containing trityl carbonium ions contacted with a metallocene comprises: (1) providing a cation exchange resin which has cations, (2) contacting the cation exchange resin with a solution comprising a trityl halide complex and solvent therefor to form an intermediate; and (3) contacting the intermediate with a metallocene, preferably a zirconocene salt. The resulting composition can be used to form ethylene resins in an alumoxane free system. Une composition de précurseur de catalyseur comprend le produit de réaction d'une résine échangeuse de cations contenant des ions trityle carbonium en contact avec un métallocène. Le procédé d'obtention de ce produit de la réaction d'une résine échangeuse de cations contenant des ions trityle carbonium avec un métallocène consiste à: (1) fournir une résine échangeuse de cations ayant des cations, (2) mettre en contact la résine échangeuse de cations avec une solution contenant un complexe d'halogénure de trityle et un solvant pour former un intermédiaire; et (3) mettre en contact l'intermédiaire avec un métallocène, de préférence un sel de zirconocène. La composition résultante peut être utilisée pour produire les résines éthyléniques dans un système exempt d'alumoxane.</abstract><edition>6</edition><oa>free_for_read</oa></addata></record>
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subjects CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
COMPOSITIONS BASED THEREON
GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
TECHNICAL SUBJECTS COVERED BY FORMER USPC
TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ARTCOLLECTIONS [XRACs] AND DIGESTS
THEIR PREPARATION OR CHEMICAL WORKING-UP
THEIR RELEVANT APPARATUS
TRANSPORTING
title CATALYST PRECURSOR COMPOSITION, AND METHOD OF MAKING THE SAME
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