CHROMIUM PHOSPHONATE METAL-ORGANIC FRAMEWORKS, PROCESS FOR PREPARING THE SAME AND USES THEREOF

The present application relates to metal-organic frameworks (MOFs). More specifically, the present application relates to process for their preparation and uses thereof. The present application includes a process for preparing a chromium(III) phosphonate metal-organic framework (MOF) comprising: a)...

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Hauptverfasser: EVANS, David, ZHANG, Jinfeng, SHIMIZU, George K. H, GABERT, Evan, HUYNH, Racheal, PADEANU, Daniel, TAYLOR, Jared, GLAVINOVIC, Martin, PERRAS, Justin
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creator EVANS, David
ZHANG, Jinfeng
SHIMIZU, George K. H
GABERT, Evan
HUYNH, Racheal
PADEANU, Daniel
TAYLOR, Jared
GLAVINOVIC, Martin
PERRAS, Justin
description The present application relates to metal-organic frameworks (MOFs). More specifically, the present application relates to process for their preparation and uses thereof. The present application includes a process for preparing a chromium(III) phosphonate metal-organic framework (MOF) comprising: a) dehydrating a hydrogen-bonded metal-organic framework (HMOF) comprising chromium (III) hydrogen bonded to one or more organic polyphosphonate molecule by heating the HMOF at a controlled rate; b) cooling the dehydrated HMOF from a) to provide the MOF. La présente invention concerne des structures organométalliques (MOF). Plus particulièrement, la présente demande porte sur un procédé pour leur préparation et leurs utilisations. La présente invention comprend un procédé de préparation d'une structure organométallique au phosphonate de chrome (III) (MOF) comprenant : a) la déshydratation d'une structure organométallique liée à l'hydrogène (HMOF)) comprenant de l'hydrogène chrome (III) lié à une ou plusieurs molécules de polyphosphonate organique par chauffage du HMOF à un débit contrôlé ; b) le refroidissement du HMOF déshydraté à partir de a) pour fournir le MOF.
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subjects ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
title CHROMIUM PHOSPHONATE METAL-ORGANIC FRAMEWORKS, PROCESS FOR PREPARING THE SAME AND USES THEREOF
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