NEAR-INFRARED (NIR) TRANSPARENT NEUTRAL BLACK PERYLENE SOLID SOLUTIONS
The present invention relates to a solid solution comprising (a) at least one compound according to formula (I) and (b) at least one compound according to formula (II), or at least one compound according to formula (III), or a mixture of at least one compound according to formula (II) and at least o...
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creator | BROWN, Paul GARCIA ESPINO, Andres Carlos VINOKUROV, Nikolay VOGEL, Till ROQUETTE, Paul Pascal |
description | The present invention relates to a solid solution comprising (a) at least one compound according to formula (I) and (b) at least one compound according to formula (II), or at least one compound according to formula (III), or a mixture of at least one compound according to formula (II) and at least one compound according to formula (III) wherein R1 and R2 may, independently of one another, stand for -(CH2)n-X, wherein X stands for hydrogen, methyl, a C1-C5 alkoxyl, hydroxy, phenyl, C1-C5 alkylphenyl, C1-C5 alkoxyphenyl, hydroxyphenyl, halogenated phenyl, pyridyl, C1-C5 alkylpyridyl, C1-C5 alkoxypyridyl, halogenated pyridyl, pyridylvinyl or naphthyl; wherein n stands for 0, 1, 2, 3, 4 or 5; R3 and R4 may, independently of one another, stand for phenylene, C1-C5 alkylphenylene, C1-C5 alkoxyphenylene, hydroxyphenylene, halogenated phenylene, pyridinediyl, C1-C5 alkylpyridinediyl, C1-C5 alkoxy- pyridinediyl, halogenated pyridinediyl, anthraquinonediyl or naphthalenediyl, wherein the 2 nitrogen atoms bound to R4 according to formula (II) and (III) form a 5-membered or a 6- membered heterocycle with 2 atoms of an aromatic ring of R3; wherein the 2 nitrogen atoms bound to R4 according to formula (II) and (III) form a 5-membered or a 6-membered heterocycle with 2 atoms of an aromatic ring of R4; X1 to X8 may, independently from one another, stand for hydrogen, C1-C5 alkyl, C1-C5 alkoxy, hydroxy, phenyl or halide. The present invention further relates to a process for producing the solid solution. Furthermore, the present invention relates to a solid solution obtainable or obtained according to said process and to the use of the inventive solid solution, in particular as a NIR transparent black colorant in a NIR non-absorbing component.
La présente invention concerne une solution solide comprenant (a) au moins un composé selon la formule (I) et (b) au moins un composé selon la formule (II), ou au moins un composé selon la formule (III), ou un mélange d'au moins un composé selon la formule (II) et d'au moins un composé selon la formule (III), R1 et R2 pouvant, indépendamment l'un de l'autre, représenter -(CH2)n-X, X représentant un hydrogène, un méthyle, un alcoxyle en C1-C5, un hydroxy, un phényle, un alkylphényle en C1-C5, un alcoxyphényle en C1-C5, un hydroxyphényle, un phényle halogéné, un pyridyle, un alkylpyridyle en C1-C5, un alcoxypyridyle en C1-C5, un pyridyle halogéné, un pyridylvinyle ou un naphtyle ; n représentant 0, 1, 2, 3, 4 ou 5 ; R3 et R4 pouvant, i |
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fullrecord | <record><control><sourceid>epo_EVB</sourceid><recordid>TN_cdi_epo_espacenet_WO2022136310A1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>WO2022136310A1</sourcerecordid><originalsourceid>FETCH-epo_espacenet_WO2022136310A13</originalsourceid><addsrcrecordid>eNrjZHDzc3UM0vX0cwtyDHJ1UdDw8wzSVAgJcvQLDgAK-IUo-LmGArk-Ck4-js7eCgGuQZE-rn6uCsH-Pp4uIDI0xNPfL5iHgTUtMac4lRdKczMou7mGOHvophbkx6cWFyQmp-allsSH-xsZGBkZGpsZGxo4GhoTpwoAXIUtNg</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>patent</recordtype></control><display><type>patent</type><title>NEAR-INFRARED (NIR) TRANSPARENT NEUTRAL BLACK PERYLENE SOLID SOLUTIONS</title><source>esp@cenet</source><creator>BROWN, Paul ; GARCIA ESPINO, Andres Carlos ; VINOKUROV, Nikolay ; VOGEL, Till ; ROQUETTE, Paul Pascal</creator><creatorcontrib>BROWN, Paul ; GARCIA ESPINO, Andres Carlos ; VINOKUROV, Nikolay ; VOGEL, Till ; ROQUETTE, Paul Pascal</creatorcontrib><description>The present invention relates to a solid solution comprising (a) at least one compound according to formula (I) and (b) at least one compound according to formula (II), or at least one compound according to formula (III), or a mixture of at least one compound according to formula (II) and at least one compound according to formula (III) wherein R1 and R2 may, independently of one another, stand for -(CH2)n-X, wherein X stands for hydrogen, methyl, a C1-C5 alkoxyl, hydroxy, phenyl, C1-C5 alkylphenyl, C1-C5 alkoxyphenyl, hydroxyphenyl, halogenated phenyl, pyridyl, C1-C5 alkylpyridyl, C1-C5 alkoxypyridyl, halogenated pyridyl, pyridylvinyl or naphthyl; wherein n stands for 0, 1, 2, 3, 4 or 5; R3 and R4 may, independently of one another, stand for phenylene, C1-C5 alkylphenylene, C1-C5 alkoxyphenylene, hydroxyphenylene, halogenated phenylene, pyridinediyl, C1-C5 alkylpyridinediyl, C1-C5 alkoxy- pyridinediyl, halogenated pyridinediyl, anthraquinonediyl or naphthalenediyl, wherein the 2 nitrogen atoms bound to R4 according to formula (II) and (III) form a 5-membered or a 6- membered heterocycle with 2 atoms of an aromatic ring of R3; wherein the 2 nitrogen atoms bound to R4 according to formula (II) and (III) form a 5-membered or a 6-membered heterocycle with 2 atoms of an aromatic ring of R4; X1 to X8 may, independently from one another, stand for hydrogen, C1-C5 alkyl, C1-C5 alkoxy, hydroxy, phenyl or halide. The present invention further relates to a process for producing the solid solution. Furthermore, the present invention relates to a solid solution obtainable or obtained according to said process and to the use of the inventive solid solution, in particular as a NIR transparent black colorant in a NIR non-absorbing component.
La présente invention concerne une solution solide comprenant (a) au moins un composé selon la formule (I) et (b) au moins un composé selon la formule (II), ou au moins un composé selon la formule (III), ou un mélange d'au moins un composé selon la formule (II) et d'au moins un composé selon la formule (III), R1 et R2 pouvant, indépendamment l'un de l'autre, représenter -(CH2)n-X, X représentant un hydrogène, un méthyle, un alcoxyle en C1-C5, un hydroxy, un phényle, un alkylphényle en C1-C5, un alcoxyphényle en C1-C5, un hydroxyphényle, un phényle halogéné, un pyridyle, un alkylpyridyle en C1-C5, un alcoxypyridyle en C1-C5, un pyridyle halogéné, un pyridylvinyle ou un naphtyle ; n représentant 0, 1, 2, 3, 4 ou 5 ; R3 et R4 pouvant, indépendamment l'un de l'autre, représenter un phénylène, un alkylphénylène en C1-C5, un alcoxyphénylène en C1-C5, un hydroxyphénylène, un phénylène halogéné, un pyridinediyle, un alkylpyridinediyle en C1-C5, un alcoxy-pyridinediyle en C1-C5, un pyridinediyle halogéné, un anthraquinonediyle ou un naphtalènediyle, les 2 atomes d'azote liés à R4 selon les formules (II) et (III) formant un hétérocycle à 5 chaînons ou à 6 chaînons avec 2 atomes d'un cycle aromatique de R3 ; les 2 atomes d'azote liés à R4 selon les formules (II) et (III) formant un hétérocycle à 5 chaînons ou à 6 chaînons avec 2 atomes d'un cycle aromatique de R4 ; X1 à X8 pouvant, indépendamment les uns des autres, représenter un hydrogène, un alkyle en C1-C5, un alcoxy en C1-C5, un hydroxy, un phényle ou un halogénure. La présente invention concerne en outre un procédé de production de la solution solide. En outre, la présente invention concerne une solution solide pouvant être obtenue ou obtenue selon ledit procédé et l'utilisation de la solution solide de l'invention, en particulier en tant que colorant noir transparent NIR dans un composant non absorbant NIR.</description><language>eng ; fre</language><subject>ADHESIVES ; APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL ; CHEMISTRY ; DYES ; LAKES ; METALLURGY ; MISCELLANEOUS APPLICATIONS OF MATERIALS ; MISCELLANEOUS COMPOSITIONS ; MORDANTS ; NATURAL RESINS ; ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES ; PAINTS ; PERFORMING OPERATIONS ; POLISHES ; PREPARATION OF CARBON BLACK ; PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TOSURFACES, IN GENERAL ; SPRAYING OR ATOMISING IN GENERAL ; TRANSPORTING ; TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS,TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES</subject><creationdate>2022</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20220630&DB=EPODOC&CC=WO&NR=2022136310A1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76419</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20220630&DB=EPODOC&CC=WO&NR=2022136310A1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>BROWN, Paul</creatorcontrib><creatorcontrib>GARCIA ESPINO, Andres Carlos</creatorcontrib><creatorcontrib>VINOKUROV, Nikolay</creatorcontrib><creatorcontrib>VOGEL, Till</creatorcontrib><creatorcontrib>ROQUETTE, Paul Pascal</creatorcontrib><title>NEAR-INFRARED (NIR) TRANSPARENT NEUTRAL BLACK PERYLENE SOLID SOLUTIONS</title><description>The present invention relates to a solid solution comprising (a) at least one compound according to formula (I) and (b) at least one compound according to formula (II), or at least one compound according to formula (III), or a mixture of at least one compound according to formula (II) and at least one compound according to formula (III) wherein R1 and R2 may, independently of one another, stand for -(CH2)n-X, wherein X stands for hydrogen, methyl, a C1-C5 alkoxyl, hydroxy, phenyl, C1-C5 alkylphenyl, C1-C5 alkoxyphenyl, hydroxyphenyl, halogenated phenyl, pyridyl, C1-C5 alkylpyridyl, C1-C5 alkoxypyridyl, halogenated pyridyl, pyridylvinyl or naphthyl; wherein n stands for 0, 1, 2, 3, 4 or 5; R3 and R4 may, independently of one another, stand for phenylene, C1-C5 alkylphenylene, C1-C5 alkoxyphenylene, hydroxyphenylene, halogenated phenylene, pyridinediyl, C1-C5 alkylpyridinediyl, C1-C5 alkoxy- pyridinediyl, halogenated pyridinediyl, anthraquinonediyl or naphthalenediyl, wherein the 2 nitrogen atoms bound to R4 according to formula (II) and (III) form a 5-membered or a 6- membered heterocycle with 2 atoms of an aromatic ring of R3; wherein the 2 nitrogen atoms bound to R4 according to formula (II) and (III) form a 5-membered or a 6-membered heterocycle with 2 atoms of an aromatic ring of R4; X1 to X8 may, independently from one another, stand for hydrogen, C1-C5 alkyl, C1-C5 alkoxy, hydroxy, phenyl or halide. The present invention further relates to a process for producing the solid solution. Furthermore, the present invention relates to a solid solution obtainable or obtained according to said process and to the use of the inventive solid solution, in particular as a NIR transparent black colorant in a NIR non-absorbing component.
La présente invention concerne une solution solide comprenant (a) au moins un composé selon la formule (I) et (b) au moins un composé selon la formule (II), ou au moins un composé selon la formule (III), ou un mélange d'au moins un composé selon la formule (II) et d'au moins un composé selon la formule (III), R1 et R2 pouvant, indépendamment l'un de l'autre, représenter -(CH2)n-X, X représentant un hydrogène, un méthyle, un alcoxyle en C1-C5, un hydroxy, un phényle, un alkylphényle en C1-C5, un alcoxyphényle en C1-C5, un hydroxyphényle, un phényle halogéné, un pyridyle, un alkylpyridyle en C1-C5, un alcoxypyridyle en C1-C5, un pyridyle halogéné, un pyridylvinyle ou un naphtyle ; n représentant 0, 1, 2, 3, 4 ou 5 ; R3 et R4 pouvant, indépendamment l'un de l'autre, représenter un phénylène, un alkylphénylène en C1-C5, un alcoxyphénylène en C1-C5, un hydroxyphénylène, un phénylène halogéné, un pyridinediyle, un alkylpyridinediyle en C1-C5, un alcoxy-pyridinediyle en C1-C5, un pyridinediyle halogéné, un anthraquinonediyle ou un naphtalènediyle, les 2 atomes d'azote liés à R4 selon les formules (II) et (III) formant un hétérocycle à 5 chaînons ou à 6 chaînons avec 2 atomes d'un cycle aromatique de R3 ; les 2 atomes d'azote liés à R4 selon les formules (II) et (III) formant un hétérocycle à 5 chaînons ou à 6 chaînons avec 2 atomes d'un cycle aromatique de R4 ; X1 à X8 pouvant, indépendamment les uns des autres, représenter un hydrogène, un alkyle en C1-C5, un alcoxy en C1-C5, un hydroxy, un phényle ou un halogénure. La présente invention concerne en outre un procédé de production de la solution solide. En outre, la présente invention concerne une solution solide pouvant être obtenue ou obtenue selon ledit procédé et l'utilisation de la solution solide de l'invention, en particulier en tant que colorant noir transparent NIR dans un composant non absorbant NIR.</description><subject>ADHESIVES</subject><subject>APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL</subject><subject>CHEMISTRY</subject><subject>DYES</subject><subject>LAKES</subject><subject>METALLURGY</subject><subject>MISCELLANEOUS APPLICATIONS OF MATERIALS</subject><subject>MISCELLANEOUS COMPOSITIONS</subject><subject>MORDANTS</subject><subject>NATURAL RESINS</subject><subject>ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES</subject><subject>PAINTS</subject><subject>PERFORMING OPERATIONS</subject><subject>POLISHES</subject><subject>PREPARATION OF CARBON BLACK</subject><subject>PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TOSURFACES, IN GENERAL</subject><subject>SPRAYING OR ATOMISING IN GENERAL</subject><subject>TRANSPORTING</subject><subject>TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS,TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2022</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZHDzc3UM0vX0cwtyDHJ1UdDw8wzSVAgJcvQLDgAK-IUo-LmGArk-Ck4-js7eCgGuQZE-rn6uCsH-Pp4uIDI0xNPfL5iHgTUtMac4lRdKczMou7mGOHvophbkx6cWFyQmp-allsSH-xsZGBkZGpsZGxo4GhoTpwoAXIUtNg</recordid><startdate>20220630</startdate><enddate>20220630</enddate><creator>BROWN, Paul</creator><creator>GARCIA ESPINO, Andres Carlos</creator><creator>VINOKUROV, Nikolay</creator><creator>VOGEL, Till</creator><creator>ROQUETTE, Paul Pascal</creator><scope>EVB</scope></search><sort><creationdate>20220630</creationdate><title>NEAR-INFRARED (NIR) TRANSPARENT NEUTRAL BLACK PERYLENE SOLID SOLUTIONS</title><author>BROWN, Paul ; GARCIA ESPINO, Andres Carlos ; VINOKUROV, Nikolay ; VOGEL, Till ; ROQUETTE, Paul Pascal</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_WO2022136310A13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng ; fre</language><creationdate>2022</creationdate><topic>ADHESIVES</topic><topic>APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL</topic><topic>CHEMISTRY</topic><topic>DYES</topic><topic>LAKES</topic><topic>METALLURGY</topic><topic>MISCELLANEOUS APPLICATIONS OF MATERIALS</topic><topic>MISCELLANEOUS COMPOSITIONS</topic><topic>MORDANTS</topic><topic>NATURAL RESINS</topic><topic>ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES</topic><topic>PAINTS</topic><topic>PERFORMING OPERATIONS</topic><topic>POLISHES</topic><topic>PREPARATION OF CARBON BLACK</topic><topic>PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TOSURFACES, IN GENERAL</topic><topic>SPRAYING OR ATOMISING IN GENERAL</topic><topic>TRANSPORTING</topic><topic>TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS,TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES</topic><toplevel>online_resources</toplevel><creatorcontrib>BROWN, Paul</creatorcontrib><creatorcontrib>GARCIA ESPINO, Andres Carlos</creatorcontrib><creatorcontrib>VINOKUROV, Nikolay</creatorcontrib><creatorcontrib>VOGEL, Till</creatorcontrib><creatorcontrib>ROQUETTE, Paul Pascal</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>BROWN, Paul</au><au>GARCIA ESPINO, Andres Carlos</au><au>VINOKUROV, Nikolay</au><au>VOGEL, Till</au><au>ROQUETTE, Paul Pascal</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>NEAR-INFRARED (NIR) TRANSPARENT NEUTRAL BLACK PERYLENE SOLID SOLUTIONS</title><date>2022-06-30</date><risdate>2022</risdate><abstract>The present invention relates to a solid solution comprising (a) at least one compound according to formula (I) and (b) at least one compound according to formula (II), or at least one compound according to formula (III), or a mixture of at least one compound according to formula (II) and at least one compound according to formula (III) wherein R1 and R2 may, independently of one another, stand for -(CH2)n-X, wherein X stands for hydrogen, methyl, a C1-C5 alkoxyl, hydroxy, phenyl, C1-C5 alkylphenyl, C1-C5 alkoxyphenyl, hydroxyphenyl, halogenated phenyl, pyridyl, C1-C5 alkylpyridyl, C1-C5 alkoxypyridyl, halogenated pyridyl, pyridylvinyl or naphthyl; wherein n stands for 0, 1, 2, 3, 4 or 5; R3 and R4 may, independently of one another, stand for phenylene, C1-C5 alkylphenylene, C1-C5 alkoxyphenylene, hydroxyphenylene, halogenated phenylene, pyridinediyl, C1-C5 alkylpyridinediyl, C1-C5 alkoxy- pyridinediyl, halogenated pyridinediyl, anthraquinonediyl or naphthalenediyl, wherein the 2 nitrogen atoms bound to R4 according to formula (II) and (III) form a 5-membered or a 6- membered heterocycle with 2 atoms of an aromatic ring of R3; wherein the 2 nitrogen atoms bound to R4 according to formula (II) and (III) form a 5-membered or a 6-membered heterocycle with 2 atoms of an aromatic ring of R4; X1 to X8 may, independently from one another, stand for hydrogen, C1-C5 alkyl, C1-C5 alkoxy, hydroxy, phenyl or halide. The present invention further relates to a process for producing the solid solution. Furthermore, the present invention relates to a solid solution obtainable or obtained according to said process and to the use of the inventive solid solution, in particular as a NIR transparent black colorant in a NIR non-absorbing component.
La présente invention concerne une solution solide comprenant (a) au moins un composé selon la formule (I) et (b) au moins un composé selon la formule (II), ou au moins un composé selon la formule (III), ou un mélange d'au moins un composé selon la formule (II) et d'au moins un composé selon la formule (III), R1 et R2 pouvant, indépendamment l'un de l'autre, représenter -(CH2)n-X, X représentant un hydrogène, un méthyle, un alcoxyle en C1-C5, un hydroxy, un phényle, un alkylphényle en C1-C5, un alcoxyphényle en C1-C5, un hydroxyphényle, un phényle halogéné, un pyridyle, un alkylpyridyle en C1-C5, un alcoxypyridyle en C1-C5, un pyridyle halogéné, un pyridylvinyle ou un naphtyle ; n représentant 0, 1, 2, 3, 4 ou 5 ; R3 et R4 pouvant, indépendamment l'un de l'autre, représenter un phénylène, un alkylphénylène en C1-C5, un alcoxyphénylène en C1-C5, un hydroxyphénylène, un phénylène halogéné, un pyridinediyle, un alkylpyridinediyle en C1-C5, un alcoxy-pyridinediyle en C1-C5, un pyridinediyle halogéné, un anthraquinonediyle ou un naphtalènediyle, les 2 atomes d'azote liés à R4 selon les formules (II) et (III) formant un hétérocycle à 5 chaînons ou à 6 chaînons avec 2 atomes d'un cycle aromatique de R3 ; les 2 atomes d'azote liés à R4 selon les formules (II) et (III) formant un hétérocycle à 5 chaînons ou à 6 chaînons avec 2 atomes d'un cycle aromatique de R4 ; X1 à X8 pouvant, indépendamment les uns des autres, représenter un hydrogène, un alkyle en C1-C5, un alcoxy en C1-C5, un hydroxy, un phényle ou un halogénure. La présente invention concerne en outre un procédé de production de la solution solide. En outre, la présente invention concerne une solution solide pouvant être obtenue ou obtenue selon ledit procédé et l'utilisation de la solution solide de l'invention, en particulier en tant que colorant noir transparent NIR dans un composant non absorbant NIR.</abstract><oa>free_for_read</oa></addata></record> |
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subjects | ADHESIVES APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL CHEMISTRY DYES LAKES METALLURGY MISCELLANEOUS APPLICATIONS OF MATERIALS MISCELLANEOUS COMPOSITIONS MORDANTS NATURAL RESINS ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES PAINTS PERFORMING OPERATIONS POLISHES PREPARATION OF CARBON BLACK PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TOSURFACES, IN GENERAL SPRAYING OR ATOMISING IN GENERAL TRANSPORTING TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS,TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES |
title | NEAR-INFRARED (NIR) TRANSPARENT NEUTRAL BLACK PERYLENE SOLID SOLUTIONS |
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