SELF-HEALING OLIGOMERS AND THE USE THEREOF

Disclosed herein are self-healing oligomers according to the structure [UPy - (Dm - U -Dm)(2+q)] - [A(G)(n-1) - Dm]k - Z; wherein UPy, D, m, U, q, A, G, n, k, and Z are defined and described further herein, and wherein the oligomer possesses at least 3 urethane linking groups and comprises a backbon...

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Hauptverfasser: LIN, Jim, HE, Meng, HSIEH, Sam
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HE, Meng
HSIEH, Sam
description Disclosed herein are self-healing oligomers according to the structure [UPy - (Dm - U -Dm)(2+q)] - [A(G)(n-1) - Dm]k - Z; wherein UPy, D, m, U, q, A, G, n, k, and Z are defined and described further herein, and wherein the oligomer possesses at least 3 urethane linking groups and comprises a backbone derived from a polyether polyol, a polyester polyol, a poly(dimethylsiloxane), a disulfide polyol, or combinations thereof. Also described and claimed are various compositions containing such oligomers as part of a self-healing component, wherein such compositions also include an optional reactive monomer and/or oligomer component and a photoinitiator component. Yet further described and claimed are articles cured from the compositions elsewhere described using the oligomers elsewhere described. L'invention concerne des oligomères autocicatrisants selon la structure [UPy - (Dm - U -Dm)(2+q)] - [A(G)(n-1) - Dm]k - Z ; dans laquelle UPy, D, m, U, q, a, G, n, k et Z sont définis et décrits davantage dans la description et l'oligomère possédant au moins 3 groupes de liaison uréthane et comprenant un squelette dérivé d'un polyéther-polyol, d'un polyester-polyol, d'un poly(diméthylsiloxane), d'un disulfure de polyol ou des combinaisons correspondantes. L'invention concerne également diverses compositions contenant de tels oligomères en tant que partie d'un constituant auto-cicatrisant, de telles compositions comprenant également un constituant monomère et/ou oligomère réactif facultatif et un constituant photo-initiateur. L'invention concerne en outre des articles durcis à partir des compositions décrites ailleurs à l'aide des oligomères décrits ailleurs.
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Also described and claimed are various compositions containing such oligomers as part of a self-healing component, wherein such compositions also include an optional reactive monomer and/or oligomer component and a photoinitiator component. Yet further described and claimed are articles cured from the compositions elsewhere described using the oligomers elsewhere described. L'invention concerne des oligomères autocicatrisants selon la structure [UPy - (Dm - U -Dm)(2+q)] - [A(G)(n-1) - Dm]k - Z ; dans laquelle UPy, D, m, U, q, a, G, n, k et Z sont définis et décrits davantage dans la description et l'oligomère possédant au moins 3 groupes de liaison uréthane et comprenant un squelette dérivé d'un polyéther-polyol, d'un polyester-polyol, d'un poly(diméthylsiloxane), d'un disulfure de polyol ou des combinaisons correspondantes. L'invention concerne également diverses compositions contenant de tels oligomères en tant que partie d'un constituant auto-cicatrisant, de telles compositions comprenant également un constituant monomère et/ou oligomère réactif facultatif et un constituant photo-initiateur. 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Also described and claimed are various compositions containing such oligomers as part of a self-healing component, wherein such compositions also include an optional reactive monomer and/or oligomer component and a photoinitiator component. Yet further described and claimed are articles cured from the compositions elsewhere described using the oligomers elsewhere described. L'invention concerne des oligomères autocicatrisants selon la structure [UPy - (Dm - U -Dm)(2+q)] - [A(G)(n-1) - Dm]k - Z ; dans laquelle UPy, D, m, U, q, a, G, n, k et Z sont définis et décrits davantage dans la description et l'oligomère possédant au moins 3 groupes de liaison uréthane et comprenant un squelette dérivé d'un polyéther-polyol, d'un polyester-polyol, d'un poly(diméthylsiloxane), d'un disulfure de polyol ou des combinaisons correspondantes. 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Also described and claimed are various compositions containing such oligomers as part of a self-healing component, wherein such compositions also include an optional reactive monomer and/or oligomer component and a photoinitiator component. Yet further described and claimed are articles cured from the compositions elsewhere described using the oligomers elsewhere described. L'invention concerne des oligomères autocicatrisants selon la structure [UPy - (Dm - U -Dm)(2+q)] - [A(G)(n-1) - Dm]k - Z ; dans laquelle UPy, D, m, U, q, a, G, n, k et Z sont définis et décrits davantage dans la description et l'oligomère possédant au moins 3 groupes de liaison uréthane et comprenant un squelette dérivé d'un polyéther-polyol, d'un polyester-polyol, d'un poly(diméthylsiloxane), d'un disulfure de polyol ou des combinaisons correspondantes. L'invention concerne également diverses compositions contenant de tels oligomères en tant que partie d'un constituant auto-cicatrisant, de telles compositions comprenant également un constituant monomère et/ou oligomère réactif facultatif et un constituant photo-initiateur. L'invention concerne en outre des articles durcis à partir des compositions décrites ailleurs à l'aide des oligomères décrits ailleurs.</abstract><oa>free_for_read</oa></addata></record>
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subjects ADHESIVES
AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G
CHEMICAL PAINT OR INK REMOVERS
CHEMISTRY
COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS
COMPOSITIONS BASED THEREON
CORRECTING FLUIDS
DYES
FILLING PASTES
GENERAL PROCESSES OF COMPOUNDING
INKS
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
METALLURGY
MISCELLANEOUS APPLICATIONS OF MATERIALS
MISCELLANEOUS COMPOSITIONS
NATURAL RESINS
ORGANIC MACROMOLECULAR COMPOUNDS
PAINTS
PASTES OR SOLIDS FOR COLOURING OR PRINTING
POLISHES
THEIR PREPARATION OR CHEMICAL WORKING-UP
USE OF MATERIALS THEREFOR
WOODSTAINS
WORKING-UP
title SELF-HEALING OLIGOMERS AND THE USE THEREOF
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