DISPERSION LIQUID

The present invention addresses the problem of providing a sheet which has excellent transparency, while being suppressed in curling. The present invention relates to a dispersion liquid which contains a fibrous cellulose that has a fiber width of 1,000 nm or less, while having an ionic substituent,...

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Hauptverfasser: TSUTSUMI Yoshiyuki, MATSUBARA Yusuke, NOGUCHI Mayo, YAMANE Kazuo, SHIRAO Takeshi, OHBUCHI Takayuki
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creator TSUTSUMI Yoshiyuki
MATSUBARA Yusuke
NOGUCHI Mayo
YAMANE Kazuo
SHIRAO Takeshi
OHBUCHI Takayuki
description The present invention addresses the problem of providing a sheet which has excellent transparency, while being suppressed in curling. The present invention relates to a dispersion liquid which contains a fibrous cellulose that has a fiber width of 1,000 nm or less, while having an ionic substituent, wherein: the content of the fibrous cellulose is 3.0% by mass or more relative to the total mass of the dispersion liquid; and the TI value of the dispersion liquid as calculated under the conditions (a) described below is from 1 to 80,000. Conditions (a): The viscosity (η1) of the dispersion liquid at a shear rate of 1 sec-1 and the viscosity (η2) of the dispersion liquid at a shear rate of 1,000 sec-1 are measured with use of a rheometer, and the TI value is calculated by the formula described below. TI value = η1/η2 La présente invention aborde le problème de la fourniture d'une feuille qui a une excellente transparence, tout en étant supprimée lors du roulage. La présente invention concerne un liquide de dispersion qui contient une cellulose fibreuse qui a une largeur de fibre de 1 000 nm ou moins, tout en ayant un substituant ionique, la teneur de la cellulose fibreuse étant de 3,0 % en masse ou plus par rapport à la masse totale du liquide de dispersion ; et la valeur TI du liquide de dispersion telle que calculée dans les conditions (a) décrites ci-dessous est de 1 à 80 000. Condition (a) : la viscosité (η1) du liquide de dispersion à une vitesse de cisaillement de 1 sec-1 et la viscosité (η2) du liquide de dispersion à une vitesse de cisaillement de 1 000 sec-1 sont mesurées à l'aide d'un rhéomètre, et la valeur TI est calculée par la formule décrite ci-dessous. Valeur TI = η1/η2 本発明は、透明性に優れ、かつカールが抑制されたシートを提供することを課題とする。本発明は、繊維幅が1000nm以下であり、イオン性置換基を有する繊維状セルロースを含む分散液であって、繊維状セルロースの含有量が分散液の全質量に対して3.0質量%以上であり、下記条件(a)により算出した前記分散液のTI値が1以上80000以下である、分散液に関する。 条件(a):レオメーターを用い、前記分散液のせん断速度1sec-1の条件における粘度(η1)と、前記分散液のせん断速度1000sec-1の条件における粘度(η2)を測定し、下記式によりTI値を算出する。 TI値=η1/η2
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The present invention relates to a dispersion liquid which contains a fibrous cellulose that has a fiber width of 1,000 nm or less, while having an ionic substituent, wherein: the content of the fibrous cellulose is 3.0% by mass or more relative to the total mass of the dispersion liquid; and the TI value of the dispersion liquid as calculated under the conditions (a) described below is from 1 to 80,000. Conditions (a): The viscosity (η1) of the dispersion liquid at a shear rate of 1 sec-1 and the viscosity (η2) of the dispersion liquid at a shear rate of 1,000 sec-1 are measured with use of a rheometer, and the TI value is calculated by the formula described below. TI value = η1/η2 La présente invention aborde le problème de la fourniture d'une feuille qui a une excellente transparence, tout en étant supprimée lors du roulage. La présente invention concerne un liquide de dispersion qui contient une cellulose fibreuse qui a une largeur de fibre de 1 000 nm ou moins, tout en ayant un substituant ionique, la teneur de la cellulose fibreuse étant de 3,0 % en masse ou plus par rapport à la masse totale du liquide de dispersion ; et la valeur TI du liquide de dispersion telle que calculée dans les conditions (a) décrites ci-dessous est de 1 à 80 000. Condition (a) : la viscosité (η1) du liquide de dispersion à une vitesse de cisaillement de 1 sec-1 et la viscosité (η2) du liquide de dispersion à une vitesse de cisaillement de 1 000 sec-1 sont mesurées à l'aide d'un rhéomètre, et la valeur TI est calculée par la formule décrite ci-dessous. 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La présente invention concerne un liquide de dispersion qui contient une cellulose fibreuse qui a une largeur de fibre de 1 000 nm ou moins, tout en ayant un substituant ionique, la teneur de la cellulose fibreuse étant de 3,0 % en masse ou plus par rapport à la masse totale du liquide de dispersion ; et la valeur TI du liquide de dispersion telle que calculée dans les conditions (a) décrites ci-dessous est de 1 à 80 000. Condition (a) : la viscosité (η1) du liquide de dispersion à une vitesse de cisaillement de 1 sec-1 et la viscosité (η2) du liquide de dispersion à une vitesse de cisaillement de 1 000 sec-1 sont mesurées à l'aide d'un rhéomètre, et la valeur TI est calculée par la formule décrite ci-dessous. 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The present invention relates to a dispersion liquid which contains a fibrous cellulose that has a fiber width of 1,000 nm or less, while having an ionic substituent, wherein: the content of the fibrous cellulose is 3.0% by mass or more relative to the total mass of the dispersion liquid; and the TI value of the dispersion liquid as calculated under the conditions (a) described below is from 1 to 80,000. Conditions (a): The viscosity (η1) of the dispersion liquid at a shear rate of 1 sec-1 and the viscosity (η2) of the dispersion liquid at a shear rate of 1,000 sec-1 are measured with use of a rheometer, and the TI value is calculated by the formula described below. TI value = η1/η2 La présente invention aborde le problème de la fourniture d'une feuille qui a une excellente transparence, tout en étant supprimée lors du roulage. La présente invention concerne un liquide de dispersion qui contient une cellulose fibreuse qui a une largeur de fibre de 1 000 nm ou moins, tout en ayant un substituant ionique, la teneur de la cellulose fibreuse étant de 3,0 % en masse ou plus par rapport à la masse totale du liquide de dispersion ; et la valeur TI du liquide de dispersion telle que calculée dans les conditions (a) décrites ci-dessous est de 1 à 80 000. Condition (a) : la viscosité (η1) du liquide de dispersion à une vitesse de cisaillement de 1 sec-1 et la viscosité (η2) du liquide de dispersion à une vitesse de cisaillement de 1 000 sec-1 sont mesurées à l'aide d'un rhéomètre, et la valeur TI est calculée par la formule décrite ci-dessous. Valeur TI = η1/η2 本発明は、透明性に優れ、かつカールが抑制されたシートを提供することを課題とする。本発明は、繊維幅が1000nm以下であり、イオン性置換基を有する繊維状セルロースを含む分散液であって、繊維状セルロースの含有量が分散液の全質量に対して3.0質量%以上であり、下記条件(a)により算出した前記分散液のTI値が1以上80000以下である、分散液に関する。 条件(a):レオメーターを用い、前記分散液のせん断速度1sec-1の条件における粘度(η1)と、前記分散液のせん断速度1000sec-1の条件における粘度(η2)を測定し、下記式によりTI値を算出する。 TI値=η1/η2</abstract><oa>free_for_read</oa></addata></record>
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subjects AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G
CHEMISTRY
COMPOSITIONS BASED THEREON
COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
DERIVATIVES THEREOF
GENERAL PROCESSES OF COMPOUNDING
IMPREGNATING OR COATING OF PAPER
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
PAPER NOT OTHERWISE PROVIDED FOR
PAPER-MAKING
POLYSACCHARIDES
PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D
PRODUCTION OF CELLULOSE
PULP COMPOSITIONS
TEXTILES
THEIR PREPARATION OR CHEMICAL WORKING-UP
TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G
WORKING-UP
title DISPERSION LIQUID
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