ZEOLITE CATALYZED PROCESS FOR THE AMINATION OF PROPYLENE OXIDE

The present invention relates to a process for the conversion of propylene oxide to 1-amino-2- propanol and/or di(2-hydroxypropyl)amine comprising (i) providing a catalyst comprising a zeolitic material comprising YO2 and optionally comprising X2O3 in its framework structure, wherein Y is a tetraval...

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Hauptverfasser: HAYDL, Alexander Michael, MELDER, Johann-Peter, PARVULESCU, Andrei-Nicolae, GORDILLO BOLONIO, Alvaro, MUELLER, Ulrich, KRUG, Thomas
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creator HAYDL, Alexander Michael
MELDER, Johann-Peter
PARVULESCU, Andrei-Nicolae
GORDILLO BOLONIO, Alvaro
MUELLER, Ulrich
KRUG, Thomas
description The present invention relates to a process for the conversion of propylene oxide to 1-amino-2- propanol and/or di(2-hydroxypropyl)amine comprising (i) providing a catalyst comprising a zeolitic material comprising YO2 and optionally comprising X2O3 in its framework structure, wherein Y is a tetravalent element and X is a trivalent element, wherein the zeolitic material has a framework-type structure selected from the group consisting of MFI and/or MEL, including MEL/MFI intergrowths; (ii) providing a mixture in the liquid phase comprising propylene oxide and ammonia; (iii) contacting the catalyst provided in (i) with the mixture in the liquid phase provided in (ii) for converting propylene oxide to 1-amino-2-propanol and/or di(2-hydroxypropyl)amine. La présente invention concerne un procédé de conversion d'oxyde de propylène en 1-amino-2-propanol et/ou de di(2-hydroxypropyle)amine comprenant (i) la fourniture d'un catalyseur comprenant un matériau zéolithique comprenant YO2 et comprenant éventuellement X2O3 dans sa structure de charpente, Y étant un élément tétravalent et X étant un élément trivalent, le matériau zéolithique ayant une structure de type charpente choisie dans le groupe constitué par MFI et/ou MEL, comprenant des enchevêtrements MEL/MFI ; (ii) la fourniture d'un mélange dans la phase liquide comprenant de l'oxyde de propylène et de l'ammoniac ; (iii) la mise en contact du catalyseur fourni dans (i) avec le mélange dans la phase liquide fournie dans (ii) pour convertir l'oxyde de propylène en 1-amino-2-propanol et/ou di(2-hydroxypropyl)amine.
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title ZEOLITE CATALYZED PROCESS FOR THE AMINATION OF PROPYLENE OXIDE
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