FLUORESCENCE REMOVAL FROM RAMAN SPECTRA BY POLARIZATION SUBTRACTION

A method for utilizing polarization as a scheme for fluorescence removal from UV Raman spectra collected in a standoff detection scheme has been invented. In this scheme, a linearly polarized ultraviolet (UV) laser interacts with a material on a surface or in a container. The material generates Rama...

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Hauptverfasser: FORD, ALAN R, HOPKINS, ADAM J
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HOPKINS, ADAM J
description A method for utilizing polarization as a scheme for fluorescence removal from UV Raman spectra collected in a standoff detection scheme has been invented. In this scheme, a linearly polarized ultraviolet (UV) laser interacts with a material on a surface or in a container. The material generates Raman scattering with polarization contributions relative to that of the laser. The material possibly fluoresces as well, but the fluorescence is generally unpolarized. By subtracting a scaled version of the perpendicular component from the parallel component of the returned signal both relative to the laser source polarization - it is possible to generate a spectrum that is fluorescence free and contains the strongest features of the Raman scattered light. La présente invention concerne un procédé pour utiliser la polarisation en tant que mécanisme pour l'élimination de fluorescence de spectres UV Raman collectés dans un schéma de détection à distance. Dans ce schéma, un laser ultraviolet (UV) à polarisation linéaire interagit avec un matériau sur une surface ou dans un récipient. Le matériau génère une diffusion Raman avec des contributions de polarisation relatives à celle du laser. Le matériau peut également émettre une fluorescence, mais la fluorescence est généralement non polarisée. Par soustraction d'une version mise à l'échelle de la composante perpendiculaire à la composante parallèle du signal retourné toutes deux relatives à la polarisation de source laser, il est possible de générer un spectre qui est exempt de fluorescence et contient les composantes les plus intenses de la lumière de diffusion Raman.
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subjects COLORIMETRY
INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIRCHEMICAL OR PHYSICAL PROPERTIES
MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT,POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRA-RED,VISIBLE OR ULTRA-VIOLET LIGHT
MEASURING
PHYSICS
RADIATION PYROMETRY
TESTING
title FLUORESCENCE REMOVAL FROM RAMAN SPECTRA BY POLARIZATION SUBTRACTION
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