METAL COMPLEX, AND ADSORBENT, STORAGE MATERIAL, AND SEPARATION MATERIAL COMPRISING SAME

[Problem] To provide a metal complex having excellent gas adsorption performance, and excellent gas storage performance and gas separation performance. [Solution] The abovementioned problem is solved by a metal complex obtained by reacting a carboxylic acid compound such as terephthalic acid which i...

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OKADA, YUKI
description [Problem] To provide a metal complex having excellent gas adsorption performance, and excellent gas storage performance and gas separation performance. [Solution] The abovementioned problem is solved by a metal complex obtained by reacting a carboxylic acid compound such as terephthalic acid which is represented by general formula (I) and is capable of at least bidentate coordination, zirconium ions, and an organic ligand capable of bidentate coordination at a nitrogen site with the zirconium ions. Le problème de l'invention concerne un complexe métallique présentant d'excellentes performances d'adsorption de gaz, d'excellentes performances de stockage de gaz et d'excellentes performances de séparation de gaz. Le problème susmentionné est résolu selon l'invention par un complexe métallique obtenu par la réaction d'un composé d'acide carboxylique, tel que l'acide téréphtalique, qui est représenté par la formule générale (I) et qui est apte à une coordination au moins bidentate, d'ions de zirconium et d'un ligand organique apte à une coordination bidentate au niveau d'un site d'azote avec les ions de zirconium. 【課題】優れたガス吸着性能、優れたガス吸蔵性能及びガス分離性能を有する金属錯体を提供すること。 【解決手段】テレフタル酸に代表される下記一般式(I)で表される二座以上で配位可能なカルボン酸化合物と、ジルコニウムイオンと、該ジルコニウムイオンに窒素部位で二座配位可能な有機配位子とを反応させてなる金属錯体によって上記課題を解決する。
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
HETEROCYCLIC COMPOUNDS
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title METAL COMPLEX, AND ADSORBENT, STORAGE MATERIAL, AND SEPARATION MATERIAL COMPRISING SAME
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